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It is essential to understand the meaning of this equation. It expresses the maximum effect of the given cause, viz., that if all the heat were converted into power, or all the power were converted into heat, 1 thermal unit would produce 772 foot-pounds, or 772 foot-pounds would raise 1 lb. of water 1 deg. Fahr. But there is never a complete conversion of any form of energy. Common solid coal may be partly converted into gases in a retort; but some of the carbon remains unchanged, and more is dissipated but not lost. In the same way, if I take five sovereigns to Paris and convert them into francs, and return to London and convert the francs into shillings, I shall not have 100 shillings, but only perhaps 95 shillings. But the five shillings have not been lost; three of them remain in the French change de monnaies, and two of them in the English exchange office. I may have forfeited something, but the world has forfeited nothing. There remains in it exactly the same number of sovereigns, francs, and shillings as there was before I set out on my travels. Nothing has been lost, but some of my money has been "dissipated;" and the analogous case, "the dissipation of energy," has formed the subject of more than one learned essay.
Before the invention of the steam-engine, the only powers employed in mechanics were those of wind and water mills, and animal power. In the first two, no conversion of one force into another took place; they were mere kinematic devices for employing the mechanical force already existing in the gale of wind and the head of water. With regard to the power developed by man and other animals, we had in them examples of most efficient heat-engines, converting into power a large percentage of the fuel burnt in the lungs. But animal power is small in amount, and it is expensive for two reasons—first, because the agents require long intervals of rest, during which they still burn fuel; and next, because the fuel they require is very expensive. A pound of bread or beef, or oats or beans, costs a great deal more than a pound of coal; while it does not, by its combustion, generate nearly so much heat. The steam-engine, therefore, took the place of animal power, and for a long time stood alone; and nearly all the motive power derived from heat is still produced by the mechanism which Watt brought to such great efficiency in so short a time.
Now the practical question for all designers and employers of heat-engines is to determine how the greatest quantity of motive force can be developed from the heat evolved from a given kind of fuel; and coal being the cheapest of all, we will see what are the results obtainable from it by the steam-engine. In this we have three efficiencies to consider—those of the furnace, the boiler, and the cylinder.
First, with respect to the furnace. The object is to combine the carbon and the hydrogen of the coal with a sufficient quantity of the oxygen of the air to effect complete combustion into carbonic acid and water. In order to do this, we have to use a quantity of air much larger than is theoretically necessary, and also to heat an amount of inert nitrogen five times greater than the necessary oxygen; and we are therefore obliged to create a draught which carries away to the chimney a considerable portion of the heat developed. The combustion, moreover, is never perfect; and some heat is lost by conduction and radiation. The principal loss is by hot gases escaping from the flues to the chimney. Even with well-set boilers, the temperature in the chimney varies from 400 deg. to 600 deg. Fahr. Taking the mean of 500 deg., this would represent a large proportion of the total heat, even if the combustion were perfect; for, as a general rule, the supply of air to a furnace is double that which is theoretically necessary. For our present purpose, it will be sufficient to see how much the whole loss is, without dividing it under the several heads of "imperfect combustion," "radiation," and "convection," by the heated gases passing to the chimney.
With a very good boiler and furnace each pound of coal evaporates 10 pounds of water from 62 deg. Fahr., changing it into steam of 65 lb. pressure at a temperature of 312 deg., or 250 deg. above that of the water from which it is generated. Besides these 250 deg., each pound of steam contains 894 units of latent heat, or 1,144 units in all. A very good condensing engine will work with 2.2 lb. of coal and 22 lb. of steam per horse power per hour. Now. 1 lb. of good coal will, by its combustion, produce 14,000 heat-units; and the 2.2 lb. of coal multiplied by 14,000 represent 30,800[theta]. Of these we find in the boiler 22 x 1,144, or 25,168 units, or about 811/2 per cent., of the whole heat of combustion; so that the difference (5,632 units, or 181/2 per cent.) has been lost by imperfect combustion, radiation, or convection. The water required for condensing this quantity of steam is 550 lb.; and, taking the temperature in the hot well as 102 deg., 550 lb. have been raised 40 deg. from 62 deg.. Thus we account for 550 x 40 = 22,000, or (say) 711/2 per cent. still remaining as heat. If we add this 711/2 per cent. to 181/2 per cent. we have 90 per cent., and there remain only 10 per cent. of the heat that can possibly have been converted into power. But some of this has been lost by radiation from steam-pipes, cylinder, etc. Allowing but 1 per cent. for this, we have only 9 per cent. as the efficiency of a really good condensing engine. This estimate agrees very closely with the actual result; for the 2.2 lb. of coal would develop 30,800[theta]; and this, multiplied by Joule's equivalent, amounts to nearly 24 millions of foot-pounds. As 1 horse power is a little less than 2 million foot-pounds per hour, only one-twelfth, or a little more than 8 per cent. of the total heat is converted; so that whether we look at the total quantity of heat which we show unconverted, or the total heat converted, we find that each supplements and corroborates the other. If we take the efficiency of the engine alone, without considering the loss caused by the boiler, we find that the 25,168[theta] which entered the boiler should have given 19,429,696 foot-pounds; so that the 2 millions given by the engine represent about 10 per cent. of the heat which has left the boiler. The foregoing figures refer to large stationary or marine engines, with first-rate boilers. When, however, we come to high-pressure engines of the best type, the consumption of coal is twice as much; and for those of any ordinary type it is usual to calculate 1 cubic foot, or 621/2 lb., of water evaporated per horse power. This would reduce the efficiency to about 6 per cent. for the best, and 3 per cent. for the ordinary non-condensing engines; and if to this we add the inefficiency of some boilers, it is certain that many small engines do not convert into power more than 2 per cent. of the potential energy contained in the coal.
At one time the steam-engine was threatened with serious rivalry by the hot-air engine. About the year 1816 the Rev. Mr. Stirling, a Scotch clergyman, invented one which a member of this Institute (Mr. George Anderson) remembers to have seen still at work at Dundee. The principle of it was that a quantity of air under pressure was moved by a mass, called a "displacer," from the cold to the hot end of a large vessel which was heated by a fire beneath and cooled by a current of water above. The same air was alternately heated and cooled, expanded and contracted; and by the difference of pressure moved the piston in a working cylinder. In this arrangement the furnace was inefficient. As only a small portion of heat reached the compressed air, the loss by radiation was very great, and the wear and tear exceedingly heavy. This system, with some modifications, was revived by Rankine, Ericsson, Laubereau, Ryder, Buckett, and Bailey. Siemens employed a similar system, only substituting steam for air. Another system, originally proposed by Sir George Cayley, consisted in compressing by a pump cold air which was subsequently passed partly through a furnace, and, expanding, moved a larger piston at the same pressure; and the difference of the areas of the pistons multiplied by the pressure common to both represented the indicated power. This principle was subsequently developed by a very able mechanic, Mr. Wenham; but his engine never came much into favor. The only hot-air engines at present in use are Ryder's, Buckett's, and Bailey's, employed to a limited extent for small powers. I have not said anything of the thermal principles involved in the construction of these engines, as they are precisely the same as those affecting the subject of the present paper.
Before explaining the principle upon which the gas-engine and every other hot-air engine depends, I shall remind you of a few data with which most of you are already familiar. The volume of every gas increases with the temperature; and this increase was the basis of the air thermometer—the first ever used. It is to be regretted that it was not the foundation of all others; for it is based on a physical principle universally applicable. Although the volume increases with the temperature, it does not increase in proportion to the degrees of any ordinary scale, but much more slowly. Now, if to each of the terms of an arithmetical series we add the same number, the new series so formed increases or decreases more slowly than the original; and it was discovered that, by adding 461 to the degrees of Fahrenheit's scale, the new scale so formed represented exactly the increment of volume caused by increase of temperature. This scale, proposed by Sir W. Thomson in 1848, is called the "scale of absolute temperature." Its zero, called the "absolute zero," is 461 deg. below the zero of Fahrenheit, or 493 deg. below the freezing point of water; and the degree of heat measured by it is termed the "absolute temperature." It is often convenient to refer to 39 deg. Fahr. (which happens to be the point at which water attains its maximum density), as this is the same as 500 deg. absolute; for, counting from this datum level, a volume of air expands exactly 1 per cent. for 5 deg., and would be doubled at 1,000 deg. absolute, or 539 deg. Fahr.
Whenever any body is compressed, its specific heat is diminished; and the surplus portion is, as it were, pushed out of the body—appearing as sensible heat. And whenever any body is expanded, its specific heat is increased; and the additional quantity of heat requisite is, as it were, sucked in from surrounding bodies—so producing cold. This action may be compared to that of a wet sponge from which, when compressed, a portion of the water is forced out, and when the sponge is allowed to expand, the water is drawn back. This effect is manifested by the increase of temperature in air-compressing machines, and the cold produced by allowing or forcing air to expand in air-cooling machines. At 39 deg. Fahr., 1 lb. of air measures 121/2 cubic feet. Let us suppose that 1 lb. of air at 39 deg. Fahr. = 500 deg. absolute, is contained in a non-conducting cylinder of 1 foot area and 121/2 feet deep under a counterpoised piston. The pressure of the atmosphere on the piston = 144 square inches x 14.7 lb., or 2,116 lb. If the air be now heated up to 539 deg. Fahr. = 1,000 deg. absolute, and at the same time the piston is not allowed to move, the pressure is doubled; and when the piston is released, it would rise 121/2 feet, provided that the temperature remained constant, and the indicator would describe a hyperbolic curve (called an "isothermal") because the temperature would have remained equal throughout. But, in fact, the temperature is lowered, because expansion has taken place, and the indicator curve which would then be described is called an "adiabatic curve," which is more inclined to the horizontal line when the volumes are represented by horizontal and the pressures by vertical co-ordinates. In this case it is supposed that there is no conduction or transmission (diabasis) of heat through the sides of the containing vessel. If, however, an additional quantity of heat be communicated to the air, so as to maintain the temperature at 1,000 deg. absolute, the piston will rise until it is 121/2 feet above its original position, and the indicator will describe an isothermal curve. Now mark the difference. When the piston was fixed, only a heating effect resulted; but when the piston moved up 121/2 feet, not only a heating but a mechanical, in fact, a thermodynamic, effect was produced, for the weight of the atmosphere (2,116 lb.) was lifted 121/2 feet = 26,450 foot-pounds.
The specific heat of air at constant pressure has been proved by the experiments of Regnault to be 0.2378, or something less than one-fourth of that of water—a result arrived at by Rankine from totally different data. In the case we have taken, there have been expended 500 x 0.2378, or (say) 118.9[theta] to produce 26,450 f.p. Each unit has therefore produced (26,450 / 118.0) = 222.5 f.p., instead of 772 f.p., which would have been rendered if every unit had been converted into power. We therefore conclude that (222.5 / 772) = 29 per cent. of the total heat has been converted. The residue, or 71 per cent., remains unchanged as heat, and may be partly saved by a regenerator, or applied to other purposes for which a moderate heat is required.
The quantity of heat necessary to raise the heat of air at a constant volume is only 71 per cent. of that required to raise to the same temperature the same weight of air under constant pressure. This is exactly the result which Laplace arrived at from observations on the velocity of sound, and may be stated thus—
Specific Foot- Per heat. pounds. cent.
Kp = 1 lb. of air at constant pressure 0.2378 x 772 = 183.5 = 100 Kv = 1 lb. of air at constant volume 0.1688 x 772 = 130.3 = 71 ——— —- ——- —- Difference, being heat converted into power 0.0690 x 772 = 53.2 = 29
Or, in a hot-air engine without regeneration, the maximum effect of 1 lb. of air heated 1 deg. Fahr. would be 53.2 f.p. The quantity of heat Ky necessary to heat air under constant volume is to Kv, or that necessary to heat it under constant pressure, as 71:100, or as 1:1.408, or very nearly as 1:SQRT(2)—a result which was arrived at by Masson from theoretical considerations. The 71 per cent. escaping as heat may be utilized in place of other fuel; and with the first hot-air engine I ever saw, it was employed for drying blocks of wood. In the same way, the unconverted heat of the exhaust steam from a high-pressure engine, or the heated gases and water passing away from a gas-engine, may be employed.
We are now in a position to judge what is the practical efficiency of the gas-engine. Some years since, in a letter which I addressed to Engineering, and which also appeared in the Journal of Gas Lighting,[2] I showed (I believe for the first time) that, in the Otto-Crossley engine, 18 per cent. of the total heat was converted into power, as against the 8 per cent. given by a very good steam-engine. About the end of 1883 a very elaborate essay, by M. Witz, appeared in the Annales de Chimie et de Physique, reporting experiments on a similar engine, which gave an efficiency somewhat lower. Early in 1884 there appeared in Van Nostrand's Engineering Magazine a most valuable paper, by Messrs. Brooks and Steward, with a preface by Professor Thurston,[3] in which the efficiency was estimated at 17 to 18 per cent. of the total heat of combustion. Both these papers show what I had no opportunity of ascertaining, that is, what becomes of the 82 per cent. of heat which is not utilized—information of the greatest importance, as it indicates in what direction improvement may be sought for, and how loss may be avoided. But, short as is the time that has elapsed since the appearance of these papers, you will find that progress has been made, and that a still higher efficiency is now claimed.
[Footnote 2: See Journal, vol. xxxv, pp. 91, 133.]
[Footnote 3: Ibid., vol. xliii., pp. 703, 744.]
When I first wrote on this subject, I relied upon some data which led me to suppose that the heating power of ordinary coal gas was higher than it really is. At our last meeting, Mr. Hartley proved, by experiments with his calorimeter, that gas of 16 or 17 candles gave only about 630 units of heat per cubic foot. Now, if all this heat could be converted into power, it would yield 630 x 772, or 486,360 f.p.; and it would require only 1,980,000 / 486,360 = 4.07 cubic feet to produce 1 indicated horse power. Some recent tests have shown that, with gas of similar heating power, 18 cubic feet have given 1 indicated horse power, and therefore 4.07 / 18 = 22.6 of the whole heat has been converted—a truly wonderful proportion when compared with steam-engines of a similar power, showing only an efficiency of 2 to 4 per cent.
The first gas-engine which came into practical use was Lenoir's, invented about 1866, in which the mixture of gas and air drawn in for part of the stroke at atmospheric pressure was inflamed by the spark from an induction coil. This required a couple of cells of a strong Bunsen battery, was apt to miss fire, and used about 90 cubic feet of gas per horse power. This was succeeded by Hugon's engine, in which the ignition was caused by a small gas flame, and the consumption was reduced to 80 cubic feet. In 1864 Otto's atmospheric engine was invented, in which a heavily-loaded piston was forced upward by an explosion of gas and air drawn in at atmospheric pressure. In its upward stroke the piston was free to move; but in its downward stroke it was connected with a ratchet, and the partial vacuum formed after the explosion beneath the piston, together with its own weight in falling, operated through a rack, and caused rotation of the flywheel. This engine (which, in an improved form, uses only about 20 cubic feet of gas) is still largely employed, some 1,600 having been constructed. The great objection to it was the noise it produced, and the wear and tear of the ratchet and rack arrangements. In 1876 the Otto-Crossley silent engine was introduced. As you are aware, it is a single-acting engine, in which the gas and air are drawn in by the first outward, and compressed by the first inward stroke. The compressed mixture is then ignited; and, being expanded by heat, drives the piston outward by the second outward stroke. Near the end of this stroke the exhaust-valve is opened, the products of combustion partly escape, and are partly driven out by the second inward stroke. I say partly, for a considerable clearance space, equal to 38 per cent. of the whole cylinder volume, remains unexhausted at the inner end of the cylinder. When working to full power, only one stroke out of every four is effective; but this engine works with only 18 to 22 cubic feet of gas per horse power. Up to the present time I am informed that about 18,000 of these engines have been manufactured. Several other compression engines have been introduced, of which the best known is Mr. Dugald Clerk's, using about 20 feet of Glasgow cannel gas. It gives one effective stroke for every revolution; the mixture being compressed in a separate air-pump. But this arrangement leads to additional friction; and the power measured by the brake is a smaller percentage of the indicated horse power than in the Otto-Crossley engine. A number of gas engines—such as Bisschop's (much used for very small powers), Robson's (at present undergoing transformation in the able hands of Messrs. Tangye), Korting's, and others—are in use; but, so far as I can learn, all require a larger quantity of gas than those previously referred to.
I have all along spoken of efficiency as a percentage of the total quantity of heat evolved by the fuel; and this is, in the eyes of a manufacturer, the essential question. Other things being equal, that engine is the most economical which requires the smallest quantity of coal or of gas. But men of science often employ the term efficiency in another sense, which I will explain. If I wind a clock, I have spent a certain amount of energy lifting the weight. This is called "energy of position;" and it is returned by the fall of the weight to its original level. In the same way if I heat air or water, I communicate to it energy of heat, which remains potential as long as the temperature does not fall, but which can be spent again by a decrease of temperature. In every heat-engine, therefore, there must be a fall from a higher to a lower temperature; otherwise no work would be done. If the water in the condenser of a steam-engine were as hot as that in the boiler, there would be equal pressure on both sides of the piston, and consequently the engine would remain at rest. Now, the greater the fall, the greater the power developed; for a smaller proportion of the heat remains as heat. If we call the higher temperature T and the lower T' on the absolute scale, T - T' is the difference; and the ratio of this to the higher temperature is called the "efficiency." This is the foundation of the formula we meet so often: E = (T - T')/T. A perfect heat-engine would, therefore, be one in which the temperature of the absolute zero would be attained, for (T - O)/T = 1. This low temperature, however, has never been reached, and in all practical cases we are confined within much narrower limits. Taking the case of the condensing engine, the limits were 312 deg. to 102 deg., or 773 deg. and 563 deg. absolute, respectively. The equation then becomes (773 - 563)/773 = 210/773 or (say) 27 per cent. With non-condensing engines, the temperatures may be taken as 312 deg. and 212 deg., or 773 deg. and 673 deg. absolute respectively. The equation then becomes (773 - 673)/773 = 100/773, or nearly 13 per cent. The practical efficiencies are not nearly this, but they are in about the same ratio—27/13. If, then, we multiply the theoretical efficiencies by 0.37, we get the practical efficiencies, say 10 per cent. and 5 per cent.; and it is in the former sense that M. Witz calculated the efficiency of the steam-engine at 35 per cent.—a statement which, I own, puzzled me a little when I first met it. These efficiencies do not take any account of loss of heat before the boiler. In the case of the gas-engine, the question is much more complicated on account of the large clearance space and the early opening of the exhaust. The highest temperature has been calculated by the American observers at 3,443 deg. absolute, and the observed temperature of the exhaust gases was 1,229 deg.. The fraction then becomes (3443 - 1229)/3443 = 64 per cent. If we multiply this by 0.37, as we did in the case of the steam-engine, we get 23.7 per cent., or approximately the same as that arrived at by direct experience. Indeed, if the consumption is, as sometimes stated, less than 18 feet, the two percentages would be exactly the same. I do not put this forward as scientifically true; but the coincidence is at least striking.
I have spoken of the illuminating power of the gas as of importance; for the richer gases have also more calorific power, and an engine would, of course, require a smaller quantity of them. The heat-giving power does not, however, vary as the illuminating power, but at a much slower rate; and, adopting the same contrivance as that on which the absolute scale of temperature is formed, I would suggest a formula of the following type: H = C (I + K), in which H represents the number of heat-units given out by the combustion of 1 cubic foot of gas, I is the illuminating power in candles, and C and K two constants to be determined by experiment. If we take the value for motive power of the different qualities of gas as given in Mr. Charles Hunt's interesting paper in our Transactions for 1882, C might without any great error be taken as 22 and K as 7.5. With Pintsch's oil gas, however, as compared with coal gas, this formula does not hold; and C should be taken much lower, and K much higher than the figures given above. That is to say, the heating power increases in a slower progression. The data available, however, are few; but I trust that Mr. Hartley will on this, as he has done on so many other scientific subjects, come to our aid.
I will now refer to the valuable experiments of Messrs. Brooks and Steward, which were most carefully made. Everything was measured—the gas by a 60 light, and the air by a 300 light meter; the indicated horse power, by a steam-engine indicator; the useful work, by a Prony brake; the temperature of the water, by a standard thermometer; and that of the escaping gases, by a pyrometer. The gas itself was analyzed; and its heating power calculated, from its composition, as 617.5[theta]. Its specific gravity was .464; and the volume of air was about seven times that of the gas used (or one-eighth of the mixture), and was only 111/2 per cent. by weight more than was needed for perfect combustion. The results arrived at were as follows:
Per cent. Converted into indicated horse power, including friction, etc. 17.0 Escaped with the exhaust gas. 15.5 Escaped in radiation. 15.5 Communicated to water in the jacket. 52.0
It will thus be seen that more than half of the heat is communicated to the water in the jacket. Now, this is the opposite of the steam-engine, where the jacket is used to transmit heat to the cylinder, and not from it. This cooling is rendered necessary, because without it the oil would be carbonized, and lubrication of the cylinder rendered impossible. Indeed, a similar difficulty has occurred with all hot-air engines, and is, I think, the reason they have not been more generally adopted. I felt this so strongly that, for some time after the introduction of the gas-engine, I was very cautious in recommending those who consulted me to adopt it. I was afraid that the wear and tear would be excessive. I have, however, for some time past been thoroughly satisfied that this fear was needless; as I am satisfied that a well-made gas-engine is as durable as a steam-engine, and the parts subject to wear can be replaced at moderate cost. We have no boiler, no feed pump, no stuffing-boxes to attend to—no water-gauges, pressure-gauges, safety-valve, or throttle-valve to be looked after; the governor is of a very simple construction; and the slide-valves may be removed and replaced in a few minutes. An occasional cleaning out of the cylinder at considerable intervals is all the supervision that the engine requires.
The very large percentage of heat absorbed by the water-jacket should point out to the ingenuity of inventors the first problem to be attacked, viz., how to save this heat without wasting the lubricant or making it inoperative; and in the solution of this problem, I look for the most important improvement to be expected in the engine. The most obvious contrivance would be some sort of intercepting shield, which would save the walls of the cylinder and the rings of the piston from the heat of the ignited gases. I have just learned that something of the kind is under trial. Another solution may possibly be found in the employment of a fluid piston; but here we are placed in a dilemma between the liquids that are decomposed and the metals that are oxidized at high temperatures. Next, the loss by radiation—15 per cent.—seems large; but this is to be attributed to the fact that the inside surface of the cylinder is at each inward stroke exposed to the atmosphere—an influence which contributes to the cooling necessary for lubrication. The remaining 15 per cent., which is carried away by the exhaust, is small compared with the proportion passing away with the exhaust steam of a high-pressure or the water of a condensing engine. As the water in the jacket can be safely raised to 212 deg. Fahr., the whole of the jacket heat can be utilized where hot water is required for other purposes; and this, with the exhaust gases, has been used for drying and heating purposes.
With such advantages, it may be asked: Why does not the gas-engine everywhere supersede the steam-engine? My answer is a simple one: The gas we manufacture is a dear fuel compared with coal. Ordinary coal gas measures 30 cubic feet to the pound; and 1,000 cubic feet, therefore, weigh 33 lb. Taking the price at 2s. 9d. per 1,000 cubic feet, it costs 1d. per lb. The 30 cubic feet at 630[theta] give 19,000[theta] all available heat. Although good coal may yield 14,000 units by its combustion, only about 11,000 of these reach the boiler; so that the ratio of the useful heat is 11/19. The thermal efficiency of the best non-condensing engine to that of the gas-engine is in the ratio 4/22. Multiplying together these two ratios, we get
11 4 44 — x ———- = —— 19 22_{1/2} 4.28
That is, speaking roughly, 1 lb. of gas gives about ten times as much power as 1 lb. of coal does in a good non-condensing engine. But at 18s. 8d. a ton we get 10 lb. of coal for 1d.; so that with these figures the cheapness of the coal would just compensate for the efficiency of the gas. As to the waste heat passing away from the engine being utilized, here the gas-engine has no advantage; and, so far as this is concerned, the gas is about eight times dearer than coal. The prices of gas and coal vary so much in different places that it is hard to determine in what cases gas or coal will be the dearer fuel, considering this point alone.
But there are other kinds of non-illuminating gases—such as Wilson's, Strong's, and Dowson's—which are now coming into use; and at Messrs. Crossley's works you will have an opportunity of seeing a large engineering factory employing several hundred mechanics, and without a chimney, in which every shaft and tool is driven by gas-engines supplied by Dowson's gas, and in which the consumption of coal is only 1.2 lb. per indicated horse power. The greatest economy ever claimed for the steam-engine was a consumption of 1.6 lb.; and this with steam of very high pressure, expanded in three cylinders successively. Thus in a quarter of a century the gas-engine has beaten in the race the steam-engine; although from Watt's first idea of improvement, nearly a century and a quarter have elapsed.
As regards the steam-engine, it is the opinion of competent authorities that the limits of temperature between which it works are so restricted, and so much of the heat is expended in producing a change of state from liquid to vapor, that little further improvement can be made. With respect to gas-engines, the limits of temperature are much further apart. A change of state is not required, and so very great improvement may still be looked for. It is not impossible even that some of the younger members of our body may live to see that period foretold by one of the greatest of our civil engineers—that happy time when boiler explosions will only be matters of history; that period, not a millennium removed by a thousand years, but an era deferred perhaps by only half a dozen decades, when the use of the gas-engine will be universal, and "a steam-engine can be found only in a cabinet of antiquities."
Discussion.
The President said this was a very delightful paper; and nothing could be finer than Mr. Lane's description of the conversion of heat into power, and the gradual growth of theory into practical work.
Mr. W. Foulis (Glasgow) agreed that it was admirable; but it required to be read to be thoroughly appreciated. When members were able to read it, they would find Mr. Lane had given a very clear description of the elementary principles of thermo-dynamics in their relation to the gas-engine and the steam-engine. There was very little in the paper to raise discussion; but Mr. Lane had made exceedingly clear how the present loss in a gas-engine was occasioned, and had also shown how, in the future development of the engine, the loss might be saved, and the engine rendered more efficient.
Mr. H.P. Holt (of Messrs. Crossley Bros., Limited) said he could indorse everything Mr. Lane had said. He had found the paper most interesting and instructive even to himself, though he had some little practical experience of gas-engines, and was supposed to know a little about them. He did not pretend to be able to teach other people; but if he could say anything as to indicator cards, or answer any questions, he should be happy to do so. (He then described the indicator diagram of the atmospheric gas-engine.) In this engine the proportion of the charging stroke to the whole sweep of the piston was about 10 per cent.; and as the charge drawn in consisted of about 10 per cent. of gas, about 1-100 of the total sweep of the piston was composed of the gas.
Mr. Foulis asked what proportion the power indicated on the diagram bore to the power indicated on the brake in the atmospheric engine.
Mr. Holt said unfortunately he had not any figures with him which would give this information; and it was so long since he had anything practically to do with this form of engine, that he should not like to speak from memory. He might add that the largest size of gas-engine made (of about 100 horse power indicated) was at work at Messrs. Edwin Butterworth and Co.'s, of Manchester. It was now driven by ordinary coal gas; but Dowson plant was to be put up very shortly in order to reduce the cost of working, which, though not excessive, would be still more economical with the Dowson gas—probably only about 30s. per week. The present cost was about L4 per week, though it was not working always at full power.
Mr. T. Holgate (Batley) said he thought it was generally understood, by those who had studied the subject, that the adoption of compression of the gaseous mixture before ignition had, so far, more than anything else, contributed to the improved working of gas-engines. This fact had not been sufficiently brought out in the paper, although Mr. Lane had clearly indicated some of the directions in which further improvements were likely to obtain. Gas engineers were largely indebted to Mr. Dugald Clerk for the statement he had made of the theory of the gas-engine.[4] Mr. Lane had given some figures, arrived at by Messrs. Brooks and Steward, from experiments made in America; but, prior to these Mr. Clerk had given others which were in the main in accordance with them. Professor Kennedy had also made experiments, the results of which agreed with them.[5] The extent of the loss by the cooling water was thus well ascertained; and it was no doubt by a reduction of this loss that further improvement in the working of gas-engines would eventually be obtained.
[Footnote 4: See Journal, vol. xxxix., p. 648.]
[Footnote 5: Ibid., vol. xl., p. 955.]
Mr. J. Paterson (Warrington) expressed his appreciation of the paper, as one of exceptional interest and value. He said he did not rise with a view to make any observations thereon. The analysis of first principles required more matured consideration and thought than could be given to it here. The opinion, however, he had formed of the paper placed it beyond the reach of criticism. It was now many years since his attention had been drawn to the name of Denny Lane; and everything that had come from his facile pen conveyed sound scientific conclusions. The paper to which they had just listened was no exception. It was invested with great interest, and would be regarded as a valuable contribution to the Transactions of the Institute.
Mr. Lane, in reply, thanked the members for the kind expressions used with respect to his paper. His object in writing it was that any one who had not paid any attention to the subject before should be able to understand thoroughly the principles on which gas and hot-air engines operated; and he believed any one who read it with moderate care would perfectly understand all the essential conditions of the gas-engine. He might mention that not long after the thermo-dynamic theory was so far developed as to determine the amount of heat converted into power, a very eminent French Engineer—M. Hirn—conducted some experiments on steam-engines at a large factory, and thought he could account for the whole heat of combustion in the condensed water and the heat which passed away; so much so that he actually doubted altogether the theory of thermo-dynamics. However, being open to conviction, he made further experiments, and discovered that he had been in error, and ultimately became one of the most energetic supporters of the theory. This showed how necessary it was to be careful before arriving at a conclusion on such a subject. He had endeavored, as far as the nature of the case allowed, to avoid any scientific abstractions, because he knew that when practical men came to theory—x's and y's, differentials, integrals, and other mathematical formulae—they were apt to be terrified.
The President said it was like coming down to every day life to say that it was important that gas managers should be familiar with the appliances used in the consumption of gas, and should be able, when called upon, to give an intelligent description of their method of working. A study of Mr. Lane's paper would reveal many matters of interest with regard to this wonderful motor, which was coming daily more and more into use, not only to the advantage of gas manufacturers, but of those who employed them.
* * * * *
M. MEIZEL'S RECIPROCATING EXHAUSTER.
At the recent Congress of the Societe Technique de l'Industrie du Gaz en France, M. Meizel, Chief Engineer of the St. Etienne Gas Works, described a new exhauster devised by him on the reciprocating principle, and for which he claims certain advantages over the appliances now in general use. Exhausters constructed on the above-named principle have hitherto, M. Meizel says, been costly to fit up, owing to the necessity for providing machinery and special mechanism for the transmission of motion. This has prevented the employment of cylinders of large dimensions; and, consequently, when the quantity of gas to be dealt with has been considerable, the number of exhausters has had to be increased. The result of this has been inconvenience, which has led to a preference being shown for other kinds of exhausters, notwithstanding the manifest advantages which, in M. Meizel's opinion, those of the reciprocating type possess. The improvement which he has effected in these appliances consists in the application to them of cylinders working automatically; and the general features of the arrangement are shown in the accompanying illustrations.
The principal advantages to be gained by the use of this exhauster are stated by M. Meizel to be the following: Considerably less motive force is necessary than is the case with other exhausters, which require steam engines and all the auxiliary mechanism for the transmission of power. By its quiet and regular action, it prevents oscillation and unsteadiness in the flow of gas in the hydraulic main, as well as in the pipes leading therefrom—a defect which has been found to exist with other exhausters. The bells, being of large area, serve the purpose of a condenser; and as, owing to its density, the tar falls to the bottom of the lower vessels, which are filled with water, contact between the gas and tar is avoided. Although the appliance is of substantial construction, its action is so sensitive that it readily adapts itself to the requirements of production. It may be placed in the open air; and therefore its establishment is attended with less outlay than is the case with other exhausters, which have to be placed under cover, and provided with driving machinery and, of course, a supply of steam.
The total superficial area of the exhauster above described, including the governor, is 150 square feet; and its capacity per 24 hours is 230,000 cubic feet. It works silently, with an almost entire absence of friction; and consequently there are few parts which require lubrication. Exhausters of this type (which, M. Meizel says, could be made available for ventilation purposes, in case of necessity) may be constructed of all sizes, from 500 cubic feet per hour upward.
* * * * *
AUTOMATIC SIPHON FOR IRRIGATION.
When, at an elevated point in a meadow, there exists a spring or vein of water that cannot be utilized at a distance, either because the supply is not sufficient, or because of the permeability of the soil, it becomes very advantageous to accumulate the water in a reservoir, which may be emptied from time to time through an aperture large enough to allow the water to flow in abundance over all parts of the field.
The storing up of the water permits of irrigating a much greater area of land, and has the advantage of allowing the watering to be effected intermittingly, this being better than if it were done continuously. But this mode of irrigating requires assiduous attention. It is necessary, in fact, when the reservoir is full, to go and raise the plug, wait till the water has flowed out, and then put in the plug again as accurately as possible—a thing that it is not always easy to do. The work is a continuous piece of drudgery, and takes just as much the longer to do in proportion as the reservoir is more distant from one's dwelling. In order to do away with this inconvenience, Mr. Giral, of Langogne (Lozere), has invented a sort of movable siphon that primes itself automatically, however small be the spring that feeds the reservoir in which it is placed. The apparatus (see figure) consists of an elbowed pipe, C A B D E, of galvanized iron, whose extremity, C, communicates with the outlet, R, where it is fixed by means of a piece of rubber of peculiar form that allows the other extremity, B D E, to revolve around the axis, K, while at the same time keeping the outlet pipe hermetically closed. This rubber, whose lower extremity is bent back like the bell of a trumpet, forms a washer against which there is applied a galvanized iron ring that is fixed to the mouth of the outlet pipe by means of six small screws. This ring is provided with two studs which engage with two flexible thimbles, K and L, that are affixed to the siphon by four rivets. These studs and thimbles, as well as the screws, are likewise galvanized. Between the branches, A B D E, of the pipe there is soldered a sheet of galvanized iron, which forms isolatedly a receptacle or air-chamber, F, that contains at its upper part a small aperture, b, that remains always open, and, at its lower part, a copper screw-plug, d, and a galvanized hook, H.
In the interior of this chamber there is arranged a small leaden siphon, a b c, whose longer leg, a, passes through the bottom, where it is soldered, and whose shorter one, c, ends in close proximity to the bottom. Finally, a galvanized iron chain, G H, fixed at G to the bottom of the reservoir, and provided with a weight, P, of galvanized iron, is hooked at H to the siphon and allows it to rise more or less, according as it is given a greater or less length.
From what precedes, it will be seen that the outlet is entirely closed, so that, in order that the water may escape, it must pass into the pipe in the direction, E D B A C.
This granted, let us see how the apparatus works: In measure as the water rises in the reservoir, the siphon gradually loses weight, and its extremity, B D H, is finally lifted by the thrust, so that the entire affair revolves upon the studs, K, until the chain becomes taut. The apparatus then ceases to rise; but the water, ever continuing to rise, finally reaches the apex, b, of the smaller siphon, and, through it, enters the air chamber and fills it. The equilibrium being thus broken, the siphon descends to the bottom, becomes primed, and empties the reservoir. When the level of the water, in descending, is at the height of the small siphon, a b c, this latter, which is also primed, empties the chamber, F, in turn, so that, at the moment the large siphon loses its priming, the entire apparatus is in the same state that it was at first.
In short, when the water enters the reservoir, the siphon, movable upon its base, rises to the height at which it is desired that the flow shall take place. Being arrested at this point by the chain, it becomes primed, and sinks, and the water escapes. When the water is exhausted, the siphon rises anew in order to again sink; and this goes on as long as the period of irrigation lasts.
This apparatus, which is simple in its operation, and not very costly, is being employed with success for irrigating several meadows in the upper basin of the Allier.—Le Genie Civil.
* * * * *
ASSAY OF EARTHENWARE GLAZE.
Lead oxide melted or incompletely vitrified is still in common use in the manufacture of inferior earthenware, and sometimes leads to serious results. To detect lead in a glaze, M. Herbelin moistens a slip of white linen or cotton, free from starch, with nitric acid at 10 per cent. and rubs it for ten to fifteen seconds on the side of the utensil under examination, and then deposits a drop of a solution of potassium iodide, at 5 per cent. on the part which has been in contact. A lead glaze simply fused gives a very highly colored yellow spot of potassium iodide; a lead glaze incompletely vitrified gives spots the more decided, the less perfect the vitrification; and a glaze of good quality gives no sensible color at all.—M. Herbelin.
* * * * *
ON THE ELECTRICAL FURNACE AND THE REDUCTION OF THE OXIDES OF BORON, SILICON, ALUMINUM, AND OTHER METALS BY CARBON.[1]
[Footnote 1: Read at the recent meeting of the American Association, Ann Arbor, Mich.]
By EUGENE H. COWLES, ALFRED H. COWLES, AND CHARLES F. MABERY.
The application of electricity to metallurgical processes has hitherto been confined to the reduction of metals from solutions, and few attempts have been made to effect dry reductions by means of an electric current. Sir W. Siemens attempted to utilize the intense heat of an electric arc for this purpose, but accomplished little beyond fusing several pounds of steel. A short time since, Eugene H. Cowles and Alfred H. Cowles of Cleveland conceived the idea of obtaining a continuous high temperature on an extended scale by introducing into the path of an electric current some material that would afford the requisite resistance, thereby producing a corresponding increase in the temperature. After numerous experiments that need not be described in detail, coarsely pulverized carbon was selected as the best means for maintaining a variable resistance and at the same time as the most available substance for the reduction of oxides. When this material, mixed with the oxide to be reduced, was made a part of the electric circuit in a fire clay retort, and submitted to the action of a current from a powerful dynamo machine, not only was the oxide reduced, but the temperature increased to such an extent that the whole interior of the retort fused completely. In other experiments lumps of lime, sand, and corundum were fused, with indications of a reduction of the corresponding metal; on cooling, the lime formed large, well-defined crystals, the corundum beautiful red, green, and blue hexagonal crystals.
Following up these results with the assistance of Charles F. Mabery, professor of chemistry in the Case School of Applied Science, who became interested at this stage of the experiments, it was soon found that the intense heat thus produced could be utilized for the reduction of oxides in large quantities, and experiments were next tried on a large scale with a current from two dynamos driven by an equivalent of fifty horse power. For the protection of the walls of the furnace, which were made of fire brick, a mixture of the ore and coarsely pulverized gas carbon was made a central core, and it was surrounded on the sides and bottom by fine charcoal, the current following the lesser resistance of the central core from carbon electrodes which were inserted at the ends of the furnace in contact with the core. In order to protect the machines from the variable resistance within the furnace, a resistance box consisting of a coil of German silver wire placed in a large tank of water was introduced into the main circuit, and a Brush ammeter was also attached by means of a shunt circuit, to indicate the quantity of current that was being absorbed in the furnace. The latter was charged by first filling it with charcoal, making a trough in the center, and filling this central space with the ore mixture, which was covered with a layer of coarse charcoal. The furnace was closed at the top with fire brick slabs containing two or three holes for the escape of the gaseous products of the reduction, and the entire furnace made air-tight by luting with fire clay. Within a few minutes after starting the dynamo, a stream of carbonic oxide issued through the openings, burning usually with a flame eighteen inches in height. The time required for complete reduction was ordinarily about an hour.
The furnace at present in use is charged in substantially the same manner, and the current is supplied by a Brush machine of variable electromotive force driven by an equivalent of forty horse power. A Brush machine capable of utilizing 125 horse power, or two and one-half times as large as any hitherto constructed by the Brush Electric Company, is being made for the Cowles Electric Smelting and Aluminum Company, and this machine will soon be in operation. Experiments already made so that aluminum, silicon, boron, manganese, magnesium, sodium and potassium can be reduced from their oxides with ease. In fact, there is no oxide that can withstand temperatures attainable in this electrical furnace. Charcoal is changed to graphite. Does this indicate fusion or solution of carbon? As to what can be accomplished by converting enormous electrical energy into heat within a limited space, it can only be said that it opens the way into an extensive field for both pure and applied chemistry. It is not difficult to conceive of temperatures limited only by the capability of carbon to resist fusion. The results to be obtained with the large Brush machine above mentioned will be of some importance in this direction.
Since the cost of the motive power is the chief expense in accomplishing reductions by this method, its commercial success is closely connected with the cheapest form of power to be obtained. Realizing the importance of this point, the Cowles Electric Smelting and Aluminum Company has purchased an extensive and reliable water power, and works are soon to be erected for the utilization of 1,200 horse power. An important feature in the use of these furnaces, from a commercial standpoint, is the slight technical skill required in their manipulation. The four furnaces in operation in the experimental laboratory at Cleveland are in charge of two young men twenty years of age, who, six months ago, knew absolutely nothing of electricity. The products at present manufactured are the various grades of aluminum bronze made from a rich furnace product that is obtained by adding copper to the charge of ore, silicon bronze prepared in the same manner, and aluminum silver, an alloy of aluminum with several other metals. A boron bronze may be prepared by the reduction of boracic acid in contact with copper.
As commercial results may be mentioned the production in the experimental laboratory, which averages fifty pounds of 10 per cent. aluminum bronze daily, and it can be supplied to the trade in large quantities at prices based on $5 per pound for the aluminum contained, the lowest market quotation of this metal being at present $15 per pound. Silicon bronze can be furnished at prices far below those of the French manufacturers.
The alloys which the metals obtained by the methods above described form with copper have been made the subject of careful study. An alloy containing 10 per cent. of aluminum and 90 per cent. of copper forms the so-called aluminum bronze with a fine golden color, which it retains for a long time. The tensile strength of this alloy is usually given as 100,000 pounds to the square inch; but castings of our ten per cent. bronze have stood a strain of 109,000 pounds. It is a very hard, tough alloy, with a capacity to withstand wear far in excess of any other alloy in use. All grades of aluminum bronze make fine castings, taking very exact impressions, and there is no loss in remelting, as in the case of alloys containing zinc. The 5 per cent. aluminum alloy is a close approximation in color to 18 carat gold, and does not tarnish readily. Its tensile strength in the form of castings is equivalent to a strain of 68,000 pounds to the square inch. An alloy containing 2 or 3 per cent. aluminum is stronger than brass, possesses greater permanency of color, and would make an excellent substitute for that metal. When the percentage of aluminum reaches 13, an exceedingly hard, brittle alloy of a reddish color is obtained, and higher percentages increase the brittleness, and the color becomes grayish-black. Above 25 per cent. the strength again increases.
The effect of silicon in small proportions upon copper is to greatly increase its tensile strength. When more than 5 per cent. is present, the product is exceedingly brittle and grayish-black in color. It is probable that silicon acts to a certain extent as a fluxing material upon the oxides present in the copper, thereby making the metal more homogeneous. On account of its superior strength and high conductivity for electrical currents, silicon bronze is the best material known for telegraph and telephone wire.
The element boron seems to have almost as marked an effect upon copper as carbon does upon iron. A small percentage in copper increases its strength to 50,000 or 60,000 pounds per square inch without diminishing to any large extent its conductivity.
Aluminum increases very considerably the strength of all metals with which it is alloyed. An alloy of copper and nickel containing a small percentage of aluminum, called Hercules metal, withstood a strain of 105,000 pounds, and broke without elongation. Another grade of this metal broke under a strain of 111,000 pounds, with an elongation equivalent to 33 per cent. It must be remembered that these tests were all made upon castings of the alloys. The strength of common brass is doubled by the addition of 2 or 3 per cent. of aluminum. Alloys of aluminum and iron are obtained without difficulty; one product was analyzed, containing 40 per cent. of aluminum. In the furnace iron does not seem to be absorbed readily by the reduced aluminum when copper is present; but in one experiment a mixture composed of old files, 60 per cent.; nickel, 5 per cent.; and of 10 per cent. aluminum bronze 35 per cent., was melted together, and it gave a malleable product that stood a strain of 69,000 pounds.
When the reduction of aluminic oxide by carbon is conducted without the addition of copper, a brittle product is obtained that behaves in many respects like pig iron as it comes from the blast furnace. The same product is formed in considerable quantities, even when copper is present, and frequently the copper alloy is found embedded in it. Graphite is always found associated with it, even when charcoal is the reducing material, and analysis invariably shows a very high percentage of metallic aluminum. This extremely interesting substance is at present under examination.
* * * * *
THE COWLES ELECTRIC SMELTING PROCESS.
The use of electricity in the reduction of metals from their ores is extending so rapidly, and the methods of its generation and application have been so greatly improved within a few years, that the possibility of its becoming the chief agent in the metallurgy of the future may now be admitted, even in cases where the present cost of treatment is too high to be commercially advantageous.
The refining of copper and the separation of copper, gold, and silver by electrolysis have thus far attracted the greatest amount of attention, but a commercial success has also been achieved in the dry reduction by electricity of some of the more valuable metals by the Cowles Electric Smelting and Aluminum Company, of Cleveland, Ohio. Both this method of manufacture and the qualities of the products are so interesting and important that it is with pleasure we call attention to them as steps toward that large and cheap production of aluminum that the abundance of its ores and the importance of its physical properties have for several years made the unattained goal of many skillful metallurgists.
The Messrs. Cowles have succeeded in greatly reducing the market value of aluminum and its alloys, and thereby vastly extending its uses, and they are now by far the largest producers in the world of these important products. As described in their patents, the Cowles process consists essentially in the use for metallurgical purposes of a body of granular material of high resistance or low conductivity interposed within the circuit in such a manner as to form a continuous and unbroken part of the same, which granular body, by reason of its resistance, is made incandescent, and generates all the heat required. The ore or light material to be reduced—as, for example, the hydrated oxide of aluminum, alum, chloride of sodium, oxide of calcium, or sulphate of strontium—is usually mixed with the body of granular resistance material, and is thus brought directly in contact with the heat at the points of generation, at the same time the heat is distributed through the mass of granular material, being generated by the resistance of all the granules, and is not localized at one point or along a single line. The material best adapted for this purpose is electric light carbon, as it possesses the necessary amount of electrical resistance, and is capable of enduring any known degree of heat when protected from oxygen without disintegrating or fusing; but crystalline silicon or other equivalent of carbon can be employed for the same purpose. This is pulverized or granulated, the degree of granulation depending upon the size of the furnace. Coarse granulated carbon works better than finely pulverized carbon, and gives more even results. The electrical energy is more evenly distributed, and the current can not so readily form a path of highest temperature, and consequently of least resistance through the mass along which the entire current or the bulk of the current can pass. The operation must necessarily be conducted within an air-tight chamber or in a non-oxidizing atmosphere, as otherwise the carbon will be consumed and act as fuel. The carbon acts as a deoxidizing agent for the ore or metalliferous material treated, and to this extent it is consumed, but otherwise than from this cause, it remains unimpaired.
Fig. I. of the accompanying drawings is a vertical longitudinal section through a retort designed for the reduction of zinc ore, according to this process, and Fig. II. is a front elevation of the same. Fig. III. is a perspective view of a furnace adapted to withstand a very high temperature, and Figs. IV. and V. are respectively longitudinal and transverse sections of the same.
This retort consists of a cylinder, A, made of silica or other non-conducting material, suitably embedded in a body, B, of powdered charcoal, mineral wool, or of some other material which is not a good conductor of heat. The rear end of the retort-cylinder is closed by means of a carbon plate, C, which plate forms the positive electrode, and with this plate the positive wire of the electric circuit is connected. The outer end of the retort is closed by means of an inverted graphite crucible, D, to which the negative wire of the electric circuit is attached. The graphite crucible serves as a plug for closing the end of the retort. It also forms a condensing chamber for the zinc fumes, and it also constitutes the negative electrode. The term "electrode" is used in this case as designating the terminals of the circuit proper, or that portion of it which acts simply as an electrical conductor, and not with the intention of indicating the ends of a line between which there is no circuit connection. The circuit between the "electrodes," so called, is continuous, being established by means of and through the body of broken carbon contained in the retort, A. There is no deposit made on either plate of the decomposed constituents of the material reduced. The mouth of the crucible is closed with a luting of clay, or otherwise, and the opening, d, made in the upper side of the crucible, near its extremity, comes entirely within the retort, and forms a passage for the zinc fumes from the retort chamber into the condensing chamber. The pipe, E, serves as a vent for the condensing chamber. The zinc ore is mixed with pulverized or granular carbon, and the retort charged nearly full through the front end with the mixture, the plug, D, being removed for this purpose.
A small space is left at the top, as shown. After the plug has been inserted and the joint properly luted, the electric circuit is closed and the current allowed to pass through the retort, traversing its entire length through the body of mixed ore and carbon. The carbon constituents of the mass become incandescent, generating a very high degree of heat, and being in direct contact with the ore, the latter is rapidly and effectually reduced and distilled. The heat evolved reduces the ore and distills the zinc, and the zinc fumes are condensed in the condensing chamber, precisely as in the present method of zinc making, with this important exception that, aside from the reaction produced by heating carbon in the presence of zinc oxide, the electric current, in passing through the zinc oxide, has a decomposing and disintegrating action upon it, not unlike the effect produced by an electric current in a solution. This action accelerates the reduction, and promotes economy in the process.
Another form of furnace is illustrated by Fig. III., which is a perspective view of a furnace adapted for the reduction of ores and salts of non-volatile metals and similar chemical compounds. Figs. IV. and V. are longitudinal and transverse sections, respectively, through the same, illustrating the manner of packing and charging the furnace.
The walls and floors L L', of the furnace are made of fire bricks, and do not necessarily have to be very thick or strong, the heat to which they are subjected not being excessive. The carbon plates are smaller than the cross section of the box, as shown, and the spaces between them and the end walls are packed with fine charcoal.
The furnace is covered with a removable slab of fireclay, N, which is provided with one or more vents, n, for the escaping gases.
The space between the carbon plates constitutes the working part of the furnace. This is lined on the bottom and sides with a packing of fine charcoal, O, or such other material as is both a poor conductor of heat and electricity—as, for example, in some cases, silica or pulverized corundum or well-burned lime—and the charge, P, of ore and broken, granular, or pulverized carbon occupies the center of the box, extending between the carbon plates. A layer of granular charcoal, O', also covers the charge on top. The protection afforded by the charcoal jacket, as regards the heat, is so complete, that with the covering-slab removed, the hand can be held within a few inches of the exposed charcoal jacket; but with the top covering of charcoal also removed and the core exposed, the hand cannot be held within several feet. The charcoal packing behind the carbon plates is required to confine the heat and to protect them from combustion.
With this furnace, aluminum can be reduced directly from its ores; and chemical compounds from corundum, cryolite, clay, etc., and silicon, boron, calcium, manganese, magnesium, and other metals are in like manner obtained from their ores and compounds. The reduction of ores according to this process can be practiced, if circumstances require it, without any built furnace.
At present, the Cowles company is engaged mostly in the producing of aluminum bronze and aluminum silver and silicon bronze. The plant, were it run to its full capacity, is capable of turning out eighty pounds of aluminum bronze, containing 10 per cent. of aluminum daily; or, were it to run upon silicon bronze, could turn out one hundred and twenty pounds of that per day, or, we believe, more aluminum bronze daily than can be produced by all other plants in the world combined. This production, however, is but that of the experimental laboratory, and arrangements are making to turn out a ton of bronze daily, and the works have an ultimate capacity of from eight to ten thousand horse power. The energy consumed by the reduction of the ore is almost entirely electrical, only enough carbon being used to unite with the oxygen of the ore to carry it out of the furnace in the form of the carbon monoxide, the aluminum remaining behind. Consequently, the plant necessary to produce aluminum on a large scale involves a large number of the most powerful dynamos. These are to be driven by water-power or natural gas and marine engines of great capacity.
The retail price of standard 10 per cent. aluminum bronze is $1 per pound avoirdupois, which means less than $9 per pound for aluminum, the lowest price at which it has ever been sold, yet the Cowles company has laid a proposition before the Government to furnish this same bronze in large quantities at very much lower prices than this. The Hercules alloy, castings of which will stand over 100,000 pounds to the square inch tensile strain, sells at 75 c. a pound, and is also offered the Government or other large consumers at a heavy discount. The alloys are guaranteed to contain exactly what is advertised; they are standardized into 10 per cent., 7.5 per cent., 5 per cent. and 2.5 per cent. aluminum bronze before shipment.
The current available at the Cowles company's works was, until recently, 330 amperes, driven by an electromotive force of 110 volts and supplied by two Edison dynamos; but the company has now added a large Brush machine that has a current of 560 amperes and 52 volts electromotive force. We shall, on another occasion, give some particulars of experiments in the reduction of refractory ores by the process.—Eng. and Mining Jour.
* * * * *
OPTICAL TELEGRAPHY.[1]
[Footnote 1: Continued from page 8094.]
CRYPTOGRAPHY.—PRESERVATION OF TELEGRAMS.
Optical telegraphy, by reason of its very principle, presents both the advantage and inconvenience of leaving no automatic trace of the correspondence that it transmits. The advantage is very evident in cases in which an optical station falls into the hands of the enemy; on the other hand, the inconvenience is shown in cases where a badly transmitted or badly collated telegram allows an ambiguity to stand subject to dispute. Moreover, in case of warfare between civilized nations that have all the resources of science at their disposal, there may be reason to fear lest one of the enemy's optical stations substitute itself for the corresponding station, and take advantage of the situation to throw confusion into the orders transmitted. The remedy for this appears to reside in the use of cryptography and in the exchange, at various intervals, of certain words that have been agreed upon beforehand, and that the enemy is ignorant of.
As for the automatic preservation of telegrams, the problem has not been satisfactorily solved. It has been proposed to connect the key of the manipulator of the optical apparatus with the manipulator of an ordinary Morse apparatus, thus permitting the telegram to be preserved upon a band of paper. It is unnecessary to say that the space occupied by a dispatch thus transmitted would be considerable; but this is not what has stopped innovators. The principal objection resides in the increase in muscular work imposed by this arrangement upon the telegrapher. Obliged to keep his eye fixed intently at the receiving telescope, while at the same time maneuvering the manipulator and spelling aloud the words that he is receiving, the operator should have a very sensitive manipulator at his disposal, and not be submitted to mental or physical overtaxation. So the apparatus that have been devised have not met with much success.
Two French officers, working independently, have hit upon the same idea of receiving the indications transmitted by the vibration of the luminous fascicle directly upon their travel. The method consists in the use of that peculiar property of selenium of becoming a good conductor under the action of a luminous ray, while in darkness it totally prevents the passage of the electric current. Such modification of the physical properties of selenium, moreover, occurs without the perceptible development of any mechanical work. If, then, in the line of travel of the luminous fascicle emitted by the optical apparatus, or in a portion of such fascicle, we interpose a fragment of selenium connected with the two poles of a local pile, it is easy to see that the current from the latter will be opened or closed according as the luminous ray from the apparatus will or will not strike the selenium, and that the length of time during which the current passes will depend upon the length of the luminous attacks. A Morse apparatus interposed in this annexed circuit will therefore give an automatic inscription of the correspondence exchanged. Such is the principle. But, practically, very great difficulties present themselves, these being connected with the rapid weakening of the electric properties of the selenium, and with the necessity of having recourse to infinitely small mechanical actions only. The problem is nevertheless before us, and it is to be hoped that the perseverance of the scientists who are at work upon it will some day succeed in solving it.
Finally, we may call attention to the attempts made to receive the luminous impression upon a band prepared with gelatino-bromide of silver. In practice this band would unwind uniformly at the focus of the receiving telescope, which would be placed in a box, forming a camera obscura. The velocity of this band prepared for photographing the signals would be regulated by clockwork. The experiments that have been made have not given results that are absolutely satisfactory, by reason of the length of the signals received and the mechanical complication of the device.
OPTICAL TELEGRAPHY BY MEANS OF PROJECTORS.
The projectors employed for lighting to a distance the surroundings of a stronghold or of a ship have likewise been applied in optical telegraphy. For this purpose Messrs. Sautter, Lemonnier & Co. have added to their usual projecting apparatus some peculiar arrangements that permit of occultations of the luminous focus at proper intervals. Figs. 21 and 22 show the arrangement of the apparatus, the principle of which is as follows: When the axis of the projector points toward the clouds, and in the direction occupied by a corresponding station, the occultations of the luminous source placed in the focus of the apparatus produce upon the clouds, which act as a screen, an alternate series of flashes and extinctions. It is therefore possible with this arrangement, and by the use of the Morse alphabet, to establish an optical communication at a distance. The use of this projector (the principal inconvenience of which is that it requires a clouded sky) even permits two observers who are hidden from each other by the nature of the ground to easily communicate at a distance of 36 or 48 miles.
USE OF THE PROJECTOR IN OPTICAL TELEGRAPHY.
The apparatus shown in Figs. 21 and 22 permits of signaling in three ways:
1. Upon the Clouds.—In this case the mirror, A, is removed, and the projector inclined above the horizon in such a way as to illuminate the clouds to as great a distance as possible. A maneuver of the occultator, E, between the lamp and the mirror arrests the luminous rays of the source, or allows them to pass, and thus produces upon the clouds the dots and dashes of the conventional alphabet.
2. Isolated Communication by Luminous Fascicles.—When it is desired to correspond to a short distance of 2 or 3 miles, and establish a communication between two isolated posts, the mirror, A, is put in place upon its support, B. The luminous fascicle emanating from the source reflected by the mirror is thrown vertically. By revolving the mirror 90 deg. around its horizontal axis the fascicle becomes horizontal, and may thus be thrown in a given direction at unequal intervals and during irregular times, and furnish conventional signs.
3. Night Communication upon the Entire Horizon.—When we wish to correspond at a short distance, say two miles, and make signals visible from the entire horizon, the mirror, A, is put in place, so that it shall reflect the luminous fascicle vertically. The fascicle, at a distance of about fifty feet, meets a white balloon which it renders visible from every point in the horizon. The maneuver of the occultator brings the balloon out of darkness or plunges it thereinto again, and thus produces the signs necessary for aerial communication.
These ingenious arrangements, which depend upon the state of the atmosphere, do not appear to have been imitated outside of the navy.
CAPT. GAUMET'S OPTICAL TELEGRAPH.
The system of optical communication proposed by Capt. Gaumet, and which he names the Telelogue, is based upon the visibility of colored or luminous objects, and upon the possibility of piercing the opaque curtain formed by the atmosphere between the observer's eye and a signal, by utilizing the difference in brightness that exists between such objects and the atmosphere. It is a question, then, of giving such difference in intensity its maximum of brightness. To do this, Capt. Gaumet proposes to employ silvered signals upon a black background. He uses the simple letters of the alphabet, but changes their value. His apparatus has the form of a large album glued at the back to a sloping desk. Each silvered letter, glued to a piece of black cloth, is seen in relief upon the open register. A sort of index along the side, as in commercial blank-books, permits of quickly finding any letter at will. Such is the manipulator of the apparatus.
The receiver consists of a spy-glass affixed to the board that carries the register. For a range of two and a half miles, the complete apparatus, with a 12x16 inch manipulator and telescope, weighs but four and a half pounds. For double this range, with a 20x28 inch manipulator and telescope, the total weight is thirteen pounds. The larger apparatus, according to the inventor, have a range of seven miles.
For night work the manipulator is lighted either by one lamp, or by two lamps with reflector, placed laterally against it.
This apparatus, although well known, and having been publicly experimented with, has not, to our knowledge, been applied practically. From a military standpoint, its short range will evidently not permit it to compete with optical telegraphic apparatus, properly so called. Perhaps it might rather be of service for private communications between localities not very far apart, since it costs but little and is easily operated.
OPTICAL SIGNALING BETWEEN BODIES OF TROOPS.
Optical communications by signals, during day and night, with experienced men, may, in the absence of telephones, telegraphs, and messengers, render important service when the distance involved is greater than two thousand feet.
This mode of correspondence is based upon the use of the Morse alphabet. The signals are divided into night and day ones. The day signals are made with small flags. When these are wanting, sheets of white cardboard may be used. The night signals are made with a lantern provided with a support, which may be fixed to a wall or upon a bayonet.
In day signaling, the dashes of the Morse alphabet are formed by means of two flags (Fig. 23) held simultaneously at arm's length by the signaler. The dots are formed with a single flag held in the right hand (Fig. 24). In this way it is possible, by extremely simple combinations, to establish a correspondence, and produce any conventional signal. By means of relay stations, the signals may be transmitted from one to another to a great distance.
In signaling with the lantern, long and short interruptions of the luminous source are produced by means of a screen.
OPTICAL TELEGRAPHY BY LUMINOUS BALLOONS.
Various interesting experiments have been made with a view to utilizing luminous captive balloons for optical communications. As we have already seen, this maybe effected by using opaque balloons, and throwing upon them at unequal intervals a luminous fascicle by means of a projector. As for using a luminous source placed in the car of a balloon, that cannot be thought of in the present state of aeronautic science; the continual rotation of the balloon around its axis would render the projection and reception of the signals in a given direction impossible.
OPTICAL TELEGRAPHY IN THE MARINE.
For communicating optically from ship to ship during the day, the marine uses flags of different forms and colors, and flames. Between ships and the land there are used what are called semaphore signals, which are made by means of a mast provided with three arms and a disk placed at the upper part. The combinations of signs thus obtained, which are analogous in principle to those of the Chappe telegraph, permit of satisfactorily communicating to a distance.
On board ship, hand signals are used like those employed by the army for communicating between bodies of troops. For night communications the marine employs lights corresponding to the day flags, as well as rockets, and luminous rays projected by means of reflectors and intercepted by screens.
In conclusion, it may be said that optical telegraphy, which has only within a few years emerged from the domain of theory to enter that of practice, has taken a remarkable stride in the military art and in science. It is due to its processes that Col. Perrier has in recent years been enabled to carry out certain geodesic work that would have formerly been regarded as impracticable, notably the prolongation of the arc of the meridian between France and Spain. Very recently, an optical communication established between Mauritius and Reunion islands, to a distance of 129 miles, with 24 inch apparatus, proved that, in certain cases, the costly laying of a submarine cable may be replaced by the direct emission of a luminous ray.
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A NEW STYLE OF SUBMARINE TELEGRAPH.
Mr. F. Von Faund-Szyll has devised an original system of submarine telegraph, which is based upon the well known property that selenium exhibits of modifying its resistance under the influence of luminous rays, and which he styles the Selen-Differenzialrecorder.
Contrary to what is found in the other systems hitherto employed, the Faund-Szyll system utilizes the cable current merely for starting the receiving apparatus, which are operated by means of strong local batteries. The result is that the mechanical work that devolves upon the line current, which is, as well known, very weak, is exceedingly reduced.
The system consists of two essential parts: (1) The receiver, properly so called. (2) The relay as well as the registering apparatus or differenzialrecorder. The receiver consists of a closed box, K, in the interior of which there is a very intense source of light whose rays escape by passing through apertures, a a', in the front part (Fig. 1).
As a source of light, there may be conveniently employed an incandescent lamp, g, capable of giving an intense light, and arranged (as shown in Fig. 2) behind the side that contains the slits, a a'.
The starting apparatus consists of a small galvanometric helix, r, analogous to Thomson's siphon recorder, which is suspended from a cocoon fiber and capable of moving in an extremely powerful magnetic field, N S. This helix carries, as may be seen in Figs. 1, 3 and 4, a prolongation, v, at its lower end whose form is that of a prism, and which is arranged in front of the partition of the box, K, in such a way that it exactly covers the two slits, a and a when the bobbin is at rest, and in this case prevents the luminous rays of the lamp, g, from escaping from the box. But, as soon as the current sent through the cable reaches the spirals of the bobbin, through the conductors, y y', the sum of the elementary electrodynamic actions that arise causes the helix to revolve to the right or left, according to the polarity of the current, while at the same time the helix slightly approaches one or the other of the poles of the magnet. The prolongation, v, of the helix, being firmly united with the latter, follows it in its motion, and has the effect of permitting the luminous rays to escape through one or the other of the slits, a a', so that the freeing of the luminous fascicle, if such an expression is allowable, is effected.
In order to prevent oscillations, which could not fail to occur after each emission of a current (so that the helix, instead of returning to a position of equilibrium and stopping there, would go beyond it and alternately uncover the slits, a a'), the apparatus is provided with a liquid deadener. To this end, the prolongation, v, carries a piece, o, which dips into a cup containing a mixture of glycerine and water.
We shall now describe the differenzialrecorder. Opposite the two slits, a and a', there are two powerful converging lenses, l and l', whose foci coincide with two sorts of selenium plate rheostat, z and z'. The result of this arrangement is that as soon as one of the slits, as a consequence of the displacement of the helix, r, allows a luminous fascicle to escape, this latter falls upon the corresponding lens, which concentrates it and sends it to the selenium plates just mentioned. Under the influence of the luminous rays, the resistance that the selenium offers to the passage of an electric current instantly changes. At M and M' are placed two horseshoe magnets whose poles are provided with pieces of soft iron that serve as cores to exceedingly fine wire bobbins, d. These polarized pieces are arranged in the shape of a St. Andrew's cross, and in such a way that the poles of the same name occupy the two extremities of the same arm of the cross, an arrangement very clearly shown in Fig. 2.
Between the poles of the magnets, M and M', there is a permanent magnet, A, movable around a vertical axis, i. Four spiral springs, f, whose tension may be regulated, permit of centering this latter piece in such a way that when the current is traversing the spirals of the polar bobbins it is equally distant from the four poles, n, s, s', and n'. Under such circumstances it is evident that a difference in the power of attraction of these four poles, however feeble it be, will result in moving the magnet, A, in one direction or the other around its axis. The energy and extent of such motion may, moreover, be magnified by properly acting upon the four regulating springs.
The bobbins of the magnet, M, are mounted in series with the selenium plates, z, the local battery, B, and a resistance box, W. Those of the magnet, M', are in series with z', B', and W'. The local batteries, B and B', are composed of quite a large number of elements. The current from the battery, B, traverses the selenium plates and the bobbins of the magnet, M, and returns to B through the rheostat, W; and the same occurs with the current from B'. The two currents, then, are absolutely independent of one another.
From this description it is very easy to see how the system works. Let us suppose, in fact, that the current which is traversing the spirals of the helix, r, has a direction such that the helix in its movement approaches the pole, S; then the prolongation, v, will uncover the slit, a, which, along with a', had up to this moment been closed, and a luminous fascicle escaping through a will strike the lens, l', and from thence converge upon the selenium plates, z'. This is all the duty that the line current has to perform.
The luminous rays, in falling upon the selenium plates, z', modify the resistance that these offered to the passage of the current produced by the battery, B'. As this resistance diminishes, the intensity of the current in the circuit supplied by the battery, B', increases, the attractive action of the polar pieces of the magnet, M', diminishes, the equilibrium is destroyed, and the piece, A, revolves around the axis, i. If the polarity of the line current were different, the same succession of phenomena would occur, save that the direction of A's rotation would be contrary. As for the rheostats, W W', their object is to correct variations in the selenium's resistance and to balance the resistances of the two corresponding circuits. The magnet, A, will be combined with a registering apparatus so as to directly or indirectly actuate the printing lever. The entire first part of this apparatus, which is very sensitive, may be easily protected from all external influence by placing it in a box, and, if need be, in a room distant from the one in which the employes work.
The differenzialrecorder alone has to be in the work room.
As may be seen, the system is not wanting in originality. Experience alone will permit of pronouncing upon the question as to whether it is as practical as ingenious.—La Lumiere Electrique.
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A NEW CIRCUIT CUTTER.
Messrs. Thomson & Bottomley have recently invented a peculiar circuit cutter based upon the use of a metal whose melting point is exceedingly low. Recourse is had to this process for breaking the current within as short a time as possible. In this new device the ends of the conductors are soldered together with the metal in question at one or several points of the circuit. The metal employed is silver or copper of very great conductivity, seeing that the increase of temperature in a conductor, due to a sudden increase of the current, is inversely proportional to the product of the electric resistance by the specific heat of the conductor; that these metals are best adapted for giving constant and definite results; and that the contacts are better than with lead or the other metals of low melting point which are frequently employed in circuit cutters. |
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