"From the first I was much struck with the exceedingly fine state of division in which the gold existed in the ore. After roasting and very carefully grinding down in an agate mortar, I have never been able to get any pieces of gold exceeding one-thousandth of an inch in diameter, and the greater quantity is very much finer than this. Careful dissolving of the pyrites and gangue so as to leave the gold intact failed to find it in any larger diameter. As this was a very unusual experience in investigations on many other kinds of pyrites, I was led further into the matter.

"Ultimately, after a number of experiments, there was nothing left but to test for gold existing as a natural sulphide. Taking 200 gr. of ore from a sample assaying 17 oz. fine gold per ton, grinding it finely and heating for some hours with yellow sodium sulphide—on decomposing the filtrate and treating for gold I got a result at the rate of 12 oz. per ton. This was repeated several times with the same result.

"This sample came from the lode at the 140 ft. level, whilst samples from the higher levels where the ore is more oxidised, although carrying the gold in exactly the same degree of fineness, do not give as high a percentage of auric sulphide.

"It would appear that all the gold in the pyrites (and I have never found any gold existing apart from the pyrites) has originally taken its place there as a sulphide."

Professor Newbery, who made many valuable suggestions on the subject, says, speaking of gold in pyritous lodes:

"As it (the gold salt) may have been in the same solution that deposited the pyrites, which probably contained its iron in the form of proto-carbonate with sulphates, it was not easy at first to imagine any ordinary salt of gold; but this I find can be accomplished with very dilute solutions in the presence of an alkaline carbonate and a large excess of carbonic acid, both of which are common constituents of mineral waters, especially in Victoria. This is true of chloride of gold, and if the sulphide is required in solution, it is only necessary to charge the solution with an excess of sulphuretted hydrogen. In this matter both sulphides may be retained in the same solution, depositing gradually with the escape of the carbonic acid."

Pyritic lodes usually contain a considerable proportion of calcareous matter, mostly carbonates, and consequently it appears not improbable that the gold may remain in some instances as a sulphide, particularly in samples of pyrites, in which it cannot be detected even by the microscope until by calcination the iron sulphide is changed to an oxide, wherein the gold may be seen in minute metallic specks. The whole subject is full of interest, and careful scientific investigation may lead to astonishing results.



CHAPTER V

THE GENESIOLOGY OF GOLD—AURIFEROUS DRIFTS

Having considered the origin of auriferous lodes, and the mode by which in all probability the gold was conveyed to them and deposited as a metal, it is necessary also to inquire into the derivation of the gold of our auriferous drifts, and the reasons for its occurrence therein.

When quite a lad on the Victorian alluvial fields, I frequently heard old diggers assert that gold grew in the drifts where found. At the time we understood this to mean that it grew like potatoes; and, although not prepared with a scientific argument to prove that such was not so, the idea was generally laughed at. I have lived to learn that these old hard-heads were nearer the truth than possibly they clearly realised, and that gold does actually grow or agglomerate; and, indeed, is probably even now thus growing, though it is likely that the chemical and electric action in the mineral waters flowing through the drifts is not in this age nearly so active as formerly.

Most boys have tried the experiment of dipping a clean-bladed knife into sulphate of copper, and so depositing on the steel a film of copper, which adheres closely until worn away. This is a simple demonstration of a hydro-metallurgical process, though probably young hopeful is not aware of the fact; and it is really by an enlargement of this process that our beautiful and artistic gold-and silver-plated ware is produced.

In the great laboratory of Nature similar chemical depositions have taken place in the past, and may still be in progress; indeed, there is sound scientific reason to suppose that in certain localities this is even now the case, and that in this way much of our so-called alluvial gold has been formed, that is, by the deposition on metallic bases of the gold held in solution.

We will, however, take, to begin with, the generally accepted theory as to the occurrence of alluvial gold. First, let it be said, that certain alluvial gold is unquestionably derived from the denudation of quartz lodes. Such is the gold dust found in many Asiatic and African rivers, in the great placer mines of California, as also the gold dust gained from the beach sand on the west coast of New Zealand, or in the enormous alluvial drifts of the Shoalhaven Valley, New South Wales. Of the first, many fabulous tales are told to account for its being found in particular spots each summer after the winter floods, and miraculous agency was asserted, while the early beachcombers of the Hokitika district found an equally ridiculous derivation for their gold, which was always more plentiful after heavy weather. They imagined that the breakers were disintegrating some abnormally rich auriferous reefs out at sea, and that the resultant gold was washed up on the beach.

The facts are simply, with regard to the rivers, that the winter floods break down the drifts in the banks and agitate the auriferous detritus, thus acting as natural sluices, and cause the metal to accumulate in favourable spots; whilst on the New Zealand coast the heavy seas breaking on the shingly beach, carry off the lighter particles, leaving behind the gold, which is so much heavier. These beaches are composed, as also are the "terraces" behind, of enormous glacial and fluvial deposits, all containing more or less gold, and extend inland to the foot of the mountains.

It is almost certain that the usually fine gold got by hydraulicing in Californian canyons, in the gullies of the New Zealand Alps, and the great New South Wales drifts, is largely the result of the attrition of the boulders and gravel of moraines, which has thus freed, to a certain extent, the auriferous particles. But when we find large nuggety masses of high carat gold in the beds of dead rivers, another origin has to be sought.

As previously stated, there is fair reason to assume that at least three salts of gold have existed, and, possibly, may still be found in Nature—silicate, sulphide, and chloride. All of these are soluble and in the presence of certain reagents, also existing naturally, can be deposited in metallic form. Therefore, if, as is contended, reef gold was formed with the reefs from solutions in mineral waters, by inferential reasoning it can be shown that much of our alluvial gold was similarly derived.

The commonly accepted theory, however, is that the alluvial matter of our drifts has been ground out of the solid siliceous lodes by glacial and fluvial action, and that the auriferous leads have been formed by the natural sluicing operations of former streams. To this, however, there are several insuperable objections.

First, how comes it that alluvial gold is usually superior in purity to the "reef" gold immediately adjacent? Second, why is it that masses of gold, such as the huge nuggets found in Victoria and New South Wales, have never been discovered in lodes? Third, how is it that these heavy masses which, from their specific gravity, should be found only at the very bottom of the drifts, if placed by water action, are sometimes found in all positions from the surface to the bottom of the "wash"? And, lastly, why is it that when an alluvial lead is traced up to, or down from, an auriferous reef, that the light, angular gold lies close to the roof, while the heavy masses are often placed much farther away? Any one who has worked a ground sluice knows how extremely difficult it is with a strong head of water to shift from its position an ounce of solid gold. What, then, would be the force required to remove the Welcome Nugget? Under certain circumstances, Niagara would not be equal to the task.

The generally smooth appearance of alleged alluvial gold is adduced as an argument in favour of its having been carried by water from its original place of deposit, and thus in transit become waterworn; while some go so far as to say that it was shot out of the reefs in a molten state. The latter idea has been already disposed of, but if not, it may be dismissed with the statement that the heat which would melt silica in the masses met with in lodes would sublimate any gold contained, and dissipate it, not in nuggets but in fumes. With regard to the assumed waterworn appearance of alluvial gold, I have examined with the microscope the smooth surface of more than one apparently waterworn nugget, and found that it was not scratched and abraded, as would have been the case had it been really waterworn, but that it presented the same appearance, though infinitely finer in grain, as the surface of a piece of metal fresh from the electrical plating-bath.

Mr. Daintree, of the Victorian Geological Survey, many years ago discovered accidentally that gold chloride would deposit its metal on a metallic base in the presence of any organic substance. Mr. Daintree found that a piece of undissolved gold in a bottle containing chloride of gold in solution had, owing to a portion of the cork having fallen into the liquid, grown or accretionised so much that it could not be extracted through the neck. This lead Mr. Charles Wilkinson, who has contributed much to our scientific knowledge of metallurgy, to experiment further in the same direction. He says: "Using the most convenient salt of gold, the terchloride, and employing wood as the decomposing agent, in order to imitate as closely as possible the organic matter supposed to decompose the solution circulating through the drifts, I first immersed a piece of cubic iron pyrites taken from the coal formation of Cape Otway, far distant from any of our gold rocks, and therefore less likely to contain gold than other pyrites. The specimen (No. 1) was kept in dilute solution for about three weeks, and is completely covered with a bright film of gold. I afterwards filed off the gold from one side of a cube crystal to show the pyrites itself and the thickness of the surrounding coating, which is thicker than ordinary notepaper. If the conditions had continued favourable for a very lengthened period, this specimen would doubtless have formed the nucleus of a large nugget. Iron, copper, and arsenical pyrites, antimony, galena, molybdenite, zinc blende, and wolfram were treated in the above manner with similar results. In the above experiments a small chip of wood was employed as the decomposing agent. In one instance I used a piece of leather. All through the wood and leather gold was disseminated in fine particles, and when cut through the characteristic metallic lustre was brightly reflected. The first six of these sulphides were also operated upon simply in the solution without organic matter; but they remained unaltered."

Wilkinson found that when the solution of gold chloride was as strong as, say, four grains to the ounce of water, that the pyrites or other base began to decompose, and the iron sulphide changed to yellow oxide, the "gossan" of our lodes, and that though the gold was deposited, this occurred in an irregular way, and it was coated with a dark brown powdery film something like the "black gold," often found in drifts containing much ferruginous matter. Such were the curious Victorian nuggets Spondulix and Lothair.

Professor Newbery also made a number of similar experiments, and arrived at like results. He states as follows: "I placed a cube of galena in a solution of chloride of gold, with free access of air, and put in organic matter; gold was deposited as usual, in a bright metallic film, apparently completely coating the cube. After a few months the film burst along the edges of the cube, and remained in that state with the cracks open without any further alteration in size or form being apparent. Upon removing it a few days ago and breaking it open, I found that a large portion of the galena had been decomposed, forming chloride and sulphate of lead and free sulphur, which were mixed together, encasing a small nucleus of undecomposed sulphate of lead. The formation of these salts had exerted sufficient force to burst open the gold coating, which upon the outside had the mammillary form noticed by Wilkinson, while the inside was rough and irregular with crystals forcing their way into the lead salts. Had this action continued undisturbed, the result would have been a nugget with a nucleus of lead salts, or if there had been a current to remove the results of decomposition, a nugget without a nucleus of foreign matter."

But Newbery also made another discovery which still further establishes the probability of the accretionary growth of gold in drifts. In the first experiments both investigators used organic substances as the reagent to cause the deposit of gold on its base, and in each case these substances whether woodchips, leather, or even dead flies, were found to be so absolutely impregnated with gold as to leave a golden skeleton when afterwards burned. Timber found in the Ballarat deep leads has been proved to be similarly impregnated.

Newbery found that gold could also be deposited on sulphurets without any other reagent. He says: "In our mineral sulphurets, however, we have agents which are not only capable of reducing gold and silver from solution, but besides are capable of locating them when so reduced in coherent and bulky masses. Thus the aggregation of the nuggety forms of gold from solution becomes a still more simple matter, only one reagent being necessary, so that there is a greater probability of such depositions obtaining than were a double process necessary. Knowing the action of sulphides, the manner or the mode of formation of a portion at least of these nuggets seems apparent. Conceive a stream or river fed by springs rising in a country intersected by auriferous reefs, and consequently in this case carrying gold in solution; the drift of such a country must be to a greater or lesser extent pyritous, so that the debris forming the beds of these streams or rivers will certainly contain nodules of such matters disseminated or even stopping them in actual contact with the flow of water. It follows, then, from what has been previously affirmed, that there will be a reduction of gold by these nodules, and that the metal thus reduced will be firmly attached to them, at first in minute spangles isolated from each other, but afterwards accumulating and connecting in a gradual manner at that point of the pyritous mass most subject to the current until a continuous film of some size appears. This being formed the pyrites and gold are to a certain extent polarised, the film or irregular but connected mass of gold forming the negative, and the pyrites the positive end of a voltaic pair; and so according as the polarisation is advanced to completion the further deposition of gold is changed in its manner from an indiscriminate to an orderly and selective deposition concentrated upon the negative or gold plate. The deposition of gold being thus controlled, its loss by dispersion or from the crumbling away of the sustaining pyrites is nearly or quite prevented, a conservative effect which we could scarcely expect to obtain if organic matter were the reducing agent. Meanwhile there is a gradual wasting away of the pyrites or positive pole, its sulphur being oxidised to sulphuric acid and its iron to sesquioxide of iron, or hematite, a substance very generally associated with gold nuggets. According to the original size of the pyritous mass, the protection it receives from the action of oxidising substances other than gold, the strength of the gold solution, length of exposure to it, the rate of supply and velocity of stream, will be the size of the gold nugget. As to the size of a pyritous mass necessary to produce in this manner a large nugget, it is by no means considerable. A mass of common pyrites (bisulphide of iron) weighing only 12 lbs. is competent for the construction of the famous 'Welcome Nugget,' an Australian find having weight equal to 152 lbs. avoirdupois. Such masses of pyrites are by no means uncommon in our drifts or the beds of our mountain streams. Thus we find that no straining of the imagination is required to conceive of this mode of formation for the huge masses of gold found in Australia in particular, such as the Welcome Nugget, 184 lbs. 9 oz.; the Welcome Stranger, a surface nugget, 190 lbs. after smelting; the Braidwood specimen nugget, 350 lbs., two-thirds gold; besides many other large masses of almost virgin gold which have been obtained from time to time in the alluvial diggings."

The author has made a number of experiments in the same direction, but more with the idea of demonstrating how possibly gold may in certain cases have been deposited in siliceous formations after such formations had solidified. Some of the results were remarkable and indeed unexpected. I found that I could produce artificial specimens of auriferous quartz from stone which had previously contained no gold whatever, also that it was not absolutely necessary that the stone so treated should contain any metallic sulphides.

The following was contributed by the author and is from the "Transactions" of the Australasian Institute of Mining Engineers for 1893:—

"THE DEPOSITION OF GOLD.

"The question as to how gold was originally deposited in our auriferous lodes is one to which a large amount of attention has been given, both by mineralogists and practical miners, and which has been hotly argued by those who held the igneous theory and those who pronounced for the aqueous theory. It was held by the former that as gold was not probably existent in nature in any but its metallic form, therefore it had been deposited in its siliceous matrix while in a molten state, and many ingenious arguments were adduced in support of this contention. Of late, however, most scientific men, and indeed many purely empirical inquirers (using the word empirical in its strict sense) have come to the conclusion that though the mode in which they were composed was not always identical, all lodes, including auriferous formations, were primarily derived from mineral-impregnated waters which deposited their contents in fissures caused either by the cooling of the earth's crust or by volcanic agency.

"The subject is one which has long had a special attraction for the writer, who has published several articles thereon, wherein it was contended that not only was gold deposited in the lodes from aqueous solution, but that some gold found in form of nuggets had not been derived from lodes but was nascent in its alluvial bed; and for this proof was afforded by the fact that certain nuggets have been unearthed having the shape of an adjacent pebble or angular fragment of stone indented in them. Moreover, no true nugget of any great size has ever been found in a lode such as the Welcome, 2159 oz., or the Welcome Stranger, 2280 oz.; while it was accidentally discovered some years ago that gold could be induced to deposit itself from its mineral salt to the metallic state on any suitable base, such as iron sulphide.

"Following out this fact, I have experimented with various salts of gold, and have obtained some very remarkable results. I have found it practicable to produce most natural looking specimens of auriferous quartz from stone which previously, as proved by assay, contained no gold whatever. Moreover, the gold, which penetrates the stone in a thorough manner, assumes some of the more natural forms. It is always more or less mammillary, but at times, owing to causes which I have not yet quite satisfied myself upon, is decidedly dendroidal, as may be seen in one of the specimens which I have submitted to members. Moreover, I find it possible to moderate the colour and to produce a specimen in which the gold shall be as ruddy yellow as in the ferro-oxide gangue of Mount Morgan, or to tone it to the pale primrose hue of the product of the Croydon mines.

"I note that the action of the bath in which the stone is treated has a particularly disintegrating effect on many of the specimens. Some, which before immersion were of a particularly flinty texture, became in a few weeks so friable that they could be broken up by the fingers. So far as my experiments have extended they have proved this, that it was not essential that the silica and gold should have been deposited at the one time in auriferous lodes. A non-auriferous siliceous solution may have filled a fissure, and, after solidifying, some volcanic disturbance may have forced water impregnated with a gold salt through the interstices of the lode formation, when, if the conditions were favourable, the gold would be deposited in metallic forms. I prefer, for reasons which will probably be understood, not to say exactly by what process my results are obtained, but submit specimens for examination.

"(1) Piece of previously non-gold bearing stone. Locality near Adelaide, now showing gold freely in mammillary and dendroidal form.

"(2) Stone from New South Wales, showing gold artificially introduced in interstices and on face.

"(3) Stone from West Australia, very glassy looking, now thoroughly impregnated with gold; the mammillary formation being particularly noticeable.

"(4) Somewhat laminated quartz from Victoria, containing a little antimony sulphide. In this specimen the gold not only shows on the surface but penetrates each of the laminations, as is proved by breaking.

"(5) Consists of fragments of crystallised carbonate of lime from Tarrawingee, in which the gold is deposited in spots, in appearance like ferrous oxide, until submitted to the magnifying glass.

"The whole subject is worthy of much more time than I can possibly give it. The importance lies in this: That having found how the much desired metal may have been deposited in its matrix, the knowledge should help to suggest how it may be economically extracted therefrom."

A very remarkable nugget weighing 16 3/4 oz. was sluiced from near the surface in one of my own mining properties at Woodside, South Australia, some years ago, which illustrated the nuclear theory very beautifully. This nugget is very irregular in shape, fretted and chased as though with a jeweller's graving tool, showing plainly the shape of the pyritous crystals on which it was formed while the interstices were filled with red hematite iron just as found in artificially formed nuggets on a sulphide of iron base. The author has a nugget from the same locality weighing about 1 1/2 oz. which exhibits in a marked degree the same characteristics, as indeed does most of the alluvial gold found in the Mount Lofty Ranges; also a nugget from near the centre of Australia weighing four ounces, in which the original crystals of pyrites are reproduced in gold just as an iron horse-shoe, placed in a launder through which cupriferously impregnated water flows, will in time be changed to nearly pure copper and yet retain its shape.

Now with regard to the four points I have put as to the apparent anomalies of occurrence of alluvial gold. The reason why alluvial gold is of finer quality as a rule than reef is probably because while gold and silver, which have a considerable affinity for each other, were presumably dissolved from their salts and held in solution in the same mineral water, they would in many cases not be deposited together, for the reason that silver is most readily deposited in the presence of alkalies, which would be found in excess in mineral waters coming direct from the basic rocks, while gold is induced to precipitate more quickly in acid solutions, which would be the character of the waters after they had been exposed to atmospheric action and to contact with organic matters.

This, then, may explain not only the comparatively greater purity of the alluvial gold, but also why big nuggets are found so far from auriferous reefs, and also why heavy masses of gold have been frequently unearthed from among the roots even of living trees, but more particularly in drifts containing organic matter, such as ancient timber.

All, then, that has been adduced goes to establish the belief that the birthplace of our gold is in certain of the earlier rocks comprising the earth's crust, and that its appearance as the metal we value so highly is the result of electro-chemical action, such as we can demonstrate in the laboratory.



CHAPTER VI

GOLD EXTRACTION

We now come to a highly important part of our subject, the practical treatment of ores and matrixes for the extraction of the metals contained. The methods employed are multitudinous, but may be divided into four classes, namely, washing, amalgamating with mercury, chlorinating, cyaniding and other leaching processes, and smelting. The first is used in alluvial gold and tin workings and in preparing some silver, copper, and other ores for smelting, and consists merely in separating the heavier metals and minerals from their gangues by their greater specific gravity in water. The second includes the trituration of the gangue and the extraction of its gold or silver by means of mercury. Chlorinating and leaching generally is a process whereby metals are first changed by chemical action into their mineral salts, as chloride of gold, nitrate of silver, sulphate of copper, and being dissolved in water are afterwards redeposited in the metallic form by means of well-known re-agents.

In really successful mining it is in the last degree important that the mode of extraction of metals in the most scientific manner should be thoroughly understood, but as a general rule the science of metallurgy is but very superficially grasped even by those whose special business it is to treat ore bodies in order to extract their metalliferous contents, and whether in quartz crushing mill, lixiviating, or smelting works there is much left to be desired in the method of treating our ores.

My attention was recently attracted to an article written by Mr. F. A. H. Rauft, M.E., from which I make the following extract:

He says, speaking of the German treatment of ores and the mode of procedure in Australia, "It is high time that Government stepped in and endeavoured by prompt and decisive action to bring the mining industry upon a sound and legitimate basis. Though our ranges abound in all kinds of minerals that might give employment to hundreds of thousands of people, mining is carried on in a desultory, haphazard fashion. There is no system, and the treatment of ores is of necessity handed over to the tender mercies of men who have not even an idea of what an intricate science metallurgy has become in older countries. During many years of practical experience I have never known a single instance where a lode, on being worked, gave a return according to assay, and I have never known any mine where some of the precious metals could not be found in the tailings or slag. The Germans employ hundreds of men in working for zinc which produces some two or three per cent to the ton; here the same percentage of tin could hardly be made payable, and this, mark you, is owing not to cheaper labour alone, but chiefly to the labour-saving appliances and the results of the researches of such gigantic intellects as Professor Kerl and many others, of whom we in this country never even hear. Go into any of the great mining works of central Germany, and you may see acres covered by machinery ingeniously constructed to clean, break, and sort, and ultimately deliver the ores into trucks or direct into the furnace, and the whole under the supervision of a youngster or two. When a parcel of ore arrives at any of the works, say Freiberg or Clausthal, it is carefully assayed by three or four different persons and then handed over to practical experts, who are expected to produce the full amount of previous metal according to assay; and if by any chance they do not, a fixed percentage of the loss is deducted from their salary; or, if the result is in excess of this assay which is more frequently the case, a small bonus is added to their pay. Compare this system with our own wasteful, reckless method of dealing with our precious metals, and we may hide our heads in very shame."

All really practical men will, I think, endorse Mr. Rauft's opinion. Well organised and conducted schools of mines will gradually ameliorate this unsatisfactory state of things, and I hope before long that we shall have none but qualified certificated men in our mines. In the meantime a few practical hints, particularly on that very difficult branch of the subject, the saving of gold, will, it is hoped, be found of service.

The extraction of gold from the soil is an industry so old that its first introduction is lost in the mist of ages. As before stated, gold is one of the most widely disseminated of the metals, and man, so soon as he had risen from the lowest forms of savagery, began to be attracted by the kingly metal, which he found to be easily fashioned into articles of ornament and use, and to be practically non-corrodable.

What we now term the dish or pan, then, doubtless generally a wooden bowl, was the appliance first used; but they had also an arrangement, somewhat like our modern blanket tables, over which the auriferous sand was passed by means of a stream of water. The sands of some of the rivers from which portions of the gold supply of the old world was derived are still washed over year after year in exactly the same manner as was employed, probably, thousands of years ago, the labour, very arduous, being often carried on by women, who, standing knee deep in water, pan off the sand in wooden bowls much as the digger in modern alluvial fields does with his tin dish. The resulting gold often consists of but a grain or two of fine dust-gold, which is carefully collected in quills, and so exported or traded for goods.

The digger of to-day having discovered payable alluvial dirt at such a depth as to permit of its being profitably worked by small parties of men with limited or no capital, procures first a half hogshead for a puddling tub, a "cradle," or "long tom," and tin dish. The "wash dirt," as the auriferous drift is usually termed, contains a considerable admixture of clay of a more or less tenacious character, and the bulk of this has to be puddled and so disintegrated before the actual separation of the gold is attempted in the cradle or dish. This is done in the tub by constantly stirring with a shovel, and changing the water as it becomes charged with the floating argillaceous, or clayey, particles. The gravel is then placed in the hopper of the cradle which separates the larger stones and pebbles, the remainder passing down over inclined ledges as the cradle is slowly rocked and supplied with water. At the bottom of each ledge is a riffle to arrest the particles of gold. Sometimes, when the gold is very fine, amalgamated copper plates are introduced and the lower ledges are covered with green baize to act as blanket tables and catch gold which might otherwise be lost.

A long tom is a trough some 12 feet in length by 20 inches in width at the upper end, widening to 30 inches at the lower end; it is about 9 inches deep and has a fall of 1 inch to a foot. An iron screen is placed at the lower end where large stones are caught, and below this screen is the riffle box, 12 feet long, 3 feet wide, and having the same inclination as the upper trough. It is fitted with several riffles in which mercury is sometimes placed.

Much more work can be done with this appliance than with the cradle, which it superseded. Of course, the gold must be coarse and water plentiful.

When, however, the claim is paying, and the diggings show signs of some permanency, a puddling machine is constructed. This is described in the chapter called "Rules of Thumb."

Hydraulicing and ground sluicing is a very cheap and effective method of treating large quantities of auriferous drift, and, given favourable circumstances, such as a plentiful supply of water with good fall and extensive loose auriferous deposits, a very few grains to the ton or load can be made to give payable returns. The water is conveyed in flumes, or pipes to a point near where it is required, thence in wrought iron pipes gradually reduced in size and ending in a great nozzle somewhat like that of a fireman's hose. The "Monitor," as it is sometimes called, is generally fixed on a movable stand, so arranged that the strong jet of water can be directed to any point by a simple adjustment. A "face" is formed in the drift, and the water played against the lower portion of the ledge, which is quickly undermined, and falls only to be washed away in the stream of water, which is conducted through sluices with riffles, and sometimes over considerable lengths of amalgamated copper plates. This class of mining has been most extensively carried out in California and New Zealand, and some districts of Victoria, but the truly enormous drifts of the Shoalhaven district in New South Wales must in the near future add largely to the world's gold supply. These drifts which are auriferous from grass roots to bed rock extend for nearly fifty miles, and are in places over 200 feet deep. Want of capital and want of knowledge has hitherto prevented their being profitably worked on a large scale.

The extraction of reef gold from its matrix is a much more complicated process, and the problem how most effectively to obtain that great desideratum—a complete separating and saving operation—is one which taxes the skill and evokes the ingenuity of scientific men all over the world. The difficulty is that as scarcely any two gangues, or matrixes, are exactly alike, the treatment which is found most effective on one mine will often not answer in another. Much also depends on the proportion of gold to the ton of rock under treatment, as the most scientific and perfect processes of lixiviation hitherto adopted will not pay, even when all other conditions are favourable, if the amount of gold is much under half an ounce to the ton and even then will leave but a very small profit. If, however, the gold is "free," and the lode large, a very few pennyweights (or "dollars," as the Americans say) to the ton will pay handsomely. The mode of extraction longest in vogue, and after all the cheapest and most effective, for free milling ores where the gold is not too fine, is amalgamation with mercury, which metal has a strong affinity for gold, silver, and copper.

As to crushing appliances, I shall not say much. "Their name is legion for they are many," and the same may be said of concentrators. It may be old-fashioned, but I admit my predilection is still in favour of the stamper-battery, for the reason that though it may be slower in proportion to the power employed, it is simple and not liable to get out of order, a great advantage when one has so often to depend on men who bring to their work a supply principally of main strength and stupidity. For the same reason I prefer the old draw and lift, and plunger pumps to newer but more complicated water-lifters.

On both these points, however, I am constrained to admit that my opinion has recently been somewhat shaken.

I have lately seen two appliances which appear to mark a new era in the scientific progress of mining. One is the "Griffin Mill," the other the "Lemichel Siphon Elevateur."

The first is in some respects on the principle of the Huntingdon Mill. The latter, if the inventor may be believed and the results seem to show he can be, will be a wonderful factor in developing not only mining properties where a preponderance of water is the trouble, but also in providing an automatic, and therefore extremely cheap, mode of water-raising and supply, which in simplicity is thus far unexampled. Atmospheric pressure alone is relied on. The well-known process of the syphon is the basis, but with this essential difference, that a large proportion of the water drawn up to the apex of the syphon is super-elevated to heights regulated by the fall obtained in the outlet leg. This elevation can be repeated almost indefinitely by returning the waste water to the reservoirs.

The Lemichel Syphon is a wonderful, yet most simple application of natural force. The inlet leg of the syphon is larger in diameter than the outlet leg, and is provided at the bottom with a valve or "clack." The outlet leg has a tap at its base. At the apex are two chambers, with an intermediary valve, regulated by a counterpoise weighted lever. The first chamber has also a vertical valve and pipe.

When the tap of the outlet leg is turned, the water flows as in an ordinary syphon, but owing to the rapid automatic opening and shutting of the valve in the first chamber about 45 per cent of the water is diverted, and may be raised to a height of many feet above the top of the syphon.

It need not be impressed on practical men that if this invention will perform anything like what is claimed for it, its value can hardly be calculated. After a careful inspection of the appliance in operation, I believe it will do all that is stated.

Another invention is combined with this which, by a very small expenditure of fuel, will enable the first point of atmospheric pressure to be attained. In this way the unwatering of mines may be very inexpensively effected, or water for irrigation purposes may be raised from an almost level stream.

The Griffin Mill is a centrifugal motion crusher with one roller only, which, by an ingenious application of motive force, revolves in an opposite direction to its initial momentum, and which evolves a force of 6000 lb. against the tire, which is only 30 inches in diameter. For hard quartz the size should be increased by at least 6 inches. It is claimed for this mill that it will pulverise to a gauge of 900 holes to the square inch from 1 1/2 to 2 1/2 tons per hour, or, say roughly, 150 tons per week.

The Huntingdon mill is a good crusher and amalgamator where the material to be operated on is comparatively soft, but does not do such good work when the stone is of a hard flinty nature.

A No. 4 Dodge stone-breaker working about 8 hours will keep a five-foot Huntingdon mill going 24 hours, and an automatic feeder is essential. For that matter both are almost essential for an ordinary stamper battery, and will certainly increase the crushing capacity and do better work from the greater regularity of the feed.

A 10 h.-p. (nominal) engine of good type is sufficient for Huntingdon mill, rock breaker, self-feeder and steam pump. A five-foot mill under favourable circumstances will crush about as much as eight head of medium weight stamps.

The Grusonwek Ball Mills, made by Krupp of Germany, also that made by the Austral Otis Company, Melbourne, are fast and excellent crushing triturating appliances for either wet or dry working, but are specially suited only for ores when the gold is fine and evenly distributed in the stone. The trituration is effected by revolving the stone in a large cylinder together with a number of steel balls of various sizes, the attrition of which with the rock quickly grinds it to powder of any required degree of fineness.

More mines have been ruined by bad mill management probably than by bad mining, though every experienced man must have seen in his time many most flagrant instances of bungling in the latter respect. Shafts are often sunk on the wrong side of the lode or too near or too far away therefrom, while instances have not been wanting where the (mis) manager has, after sinking his shaft, driven in the opposite direction to that where the lode should be found.

A common error is that of erecting machinery before there is sufficient ore in sight to make it certain that enough can be provided to keep the plant going. In mines at a distance from the centre of direction it is almost impossible to check mistakes of this description, caused by the ignorance or over sanguineness of the mine superintendent, and they are often as disastrous as they are indefensible. Another fertile source of failure is the craze for experimenting with untried inventions, alleged to be improvements on well-known methods.

A rule in the most scientific of card games, whist, is "when in doubt lead trumps." It might be paraphrased for mining thus: "When in doubt about machinery use that which has been proved." Let some one else do the experimenting.

The success of a quartz mine depends as much on favourable working conditions as on its richness in gold. Thus it may be that a mine carrying 5 or 6 oz. of gold to the ton but badly circumstanced as to distance, mountainous roads, lack of wood and water, in some cases a plethora of the latter, or irregularly faulted country, may be less profitable than another showing only 5 or 6 dwt., but favourably situated.

It is usually desirable to choose for the battery site, when possible, the slope of a hill which consists of rock that will give a good foundation for your battery.

The economical working depends greatly on the situation, which is generally fixed more or less, in the proximity of the water. The advantages of having ample water for battery purposes, or of using water as a motive power, are so great that it is very often desirable to construct a tramway of considerable length, when, by so doing, that power can be utilised; hence most quartz mills are placed near streams, or in valleys where catchment dams can be effectively constructed, except, of course, in districts where much water has to be pumped from the mine.

If water-power can be used, the water-motor will necessarily be placed as low as possible, in order to obtain the fullest available power. One point is essential. Special care must be taken to keep the appliances above the flood-level. If the water in the stream is not sufficient to carry off the tailings, the battery should be placed at such a height as to leave sufficient slope for tailings' dumps. This is more important when treating ore of such value that the tailings are worth saving for secondary treatment. In this case provision should be made for tailings, dams, or slime pits.

Whether the battery is worked by water, steam, or gas power, an ample supply of water is absolutely necessary, at least until some thoroughly effective mode of dry treatment is established. If it can be possibly arranged the water should be brought in by gravitation, and first cost is often least cost; but where this is impossible, pumps of sufficient capacity, not only to provide the absolute quantity used, but to meet any emergency, should be erected.

The purer the water the better it will be for amalgamating purposes, and in cold climates it is desirable to make provision for heating the water supplied to the battery. This can be done by means of steam from the boiler led through the feed tanks; but where the boiler power is not more than required, waste steam from the engine may be employed, but care must be taken that no greasy matter comes in contact with the plates. The exhaust steam from the engine may be utilised by carrying it through tubes fitted in an ordinary 400 gallon tank.

Reducing appliances have often to be placed in districts where the water supply is insufficient for the battery. When this is so every available means must be adopted for saving the precious liquid, such as condensing the exhaust steam from the engine. This may be done by conducting it through a considerable length of ordinary zinc piping, such as is used for carrying the water from house roofs. Also tailings pits should be made, in which the tailings and slimes are allowed to settle, and the cleared water is pumped back to be again used. These pits should, where practicable, be cemented. It is usual, also, to have one or two tailings dams at different levels; the tailings are run into the upper dam, and are allowed to settle; the slimes overflow from it into the lower dam, and are there deposited, while the cleared water is pumped back to the battery. Arrangements are made by which all these reservoirs can be sluiced out when they are filled with accumulated tailings. It is well not to leave the sluicing for too long a period, as when the slimes and tailings are set hard they are difficult to remove.

Where a permanent reducing plant is to be erected, whatever form of mill may be adopted, it is better for many reasons to use automatic ore feeders. Of these the best two I have met are the "Tulloch" and "Challenge" either of which can be adapted to any mill and both do good work.

By their use the reducing capacity of the mill is increased, and the feeding being regular the wear and tear is decreased, while by the regulated feeding of the "pulp" in the battery box or mortar can be maintained at any degree of consistency which may be found desirable, and thus the process of amalgamation will be greatly facilitated. The only objection which can be urged against the automatic feeder is that the steel points of picks, gads, drills, and other tools may be allowed to pass into the mortar or mill, and thus cause considerable wear and tear. This, I think, can be avoided by the adoption of the magnet device, described in "Rules of Thumb."

There are many mines where 3 to 4 dwt. of gold cover all the cost, the excess being clear profit. In fact there are mines which with a yield of 1 1/2 to 2 dwt. a ton, and crushing with water power, have actually yielded large profits. On the other hand, mines which have given extraordinary trial crushings have not paid working expenses. Everything depends on favourable local conditions and proper management.

Having decided what class of crushing machinery you will adopt, the first point is to fix on the best possible site for its erection. This requires much judgment, as success or failure may largely depend on the position of your machinery. One good rule is to get your crusher as reasonably high as possible, as it is cheaper to pump your feed water a few feet higher so as to get a good clear run for your tailings, and also to give you room to erect secondary treatment appliances, such as concentrators and amalgamators below your copper plates and blanket strakes.

Next, and this is most important, see that your foundations are solid and strong. A very large number of the failures of quartz milling plants is due to neglect of this rule.

I once knew a genius who erected a 10-Lead mill in a new district, and who adopted the novel idea of placing a "bed log" laterally beneath his stampers. The log was laid in a little cement bed which, when the battery started, was not quite dry. The effect was comical to every one but the unfortunate owners. It was certainly the liveliest, but at the same time one of the most ineffective batteries I have seen.

In a stamp mill the foundations are usually made of hard wood logs about 5 to 6 feet long, set on end, the bottom end resting on rock and set round with cement concrete. These are bolted together, and the "box" or mortar is bolted to them. The horizontal logs to carry the "horses" or supports for the battery frame should also be of good size, and solidly and securely bolted. The same applies to your engine-bed, but whether it be of timber, or mason work, above all things provide that the whole of your work is set out square and true to save after-wear and friction.

Considerable difference of opinion exists as to the most effective weight for stamps. My experience has been that this largely depends on the nature of your rock, as does also the height for the drop. I have usually found that with medium stamps, say 7 to 7 1/2 cwt. with fair drop and lively action, about 80 falls per minute, the best results were obtained, but the tendency of modern mill men is towards the heavier stamps, 9 cwt. and even heavier.

To find the horse-power required to drive a battery, multiply the weight of one stamp by the number of stamps in the battery; the height of lift in feet by the number of lifts per minute; add one-third of the product for friction, and the result will be the number of feet-lbs. per minute; divide this by 33,000 which is the number of feet-lbs. per minute equal to 1 h.-p. and the result will be the h.-p. required. Thus if a stamp weighs 800 lb. and you have five in the box, and each stamp has a lift of 9 in. = 0.75 ft. and strikes 80 blows per minute, then 800 x 5 x 0.75 x 80 = 240,000; one-third of 240,000 = 80,000 which added to 240,000 = 320,000; and 320,000 divided by 33,000 = 9.7 h.-p. or 1.9 h.-p. each stamp.

The total weight of a battery, including stamper box, stampers, etc., may be roughly estimated at about 1 ton per stamp. Medium weight stampers, including shank cam, disc, head, and shoe, weigh from 600 to 700 lb., and need about 3/4 h.-p. to work them.

The quantity of water required for the effective treatment of gold-bearing rock in a stamper battery varies according to the composition of the material to be operated upon, but generally it is more than the inexperienced believe. For instance, "mullocky" lode stuff, containing much clayey matter or material carrying a large percentage of heavy metal, such as titanic iron or metallic sulphides, will need a larger quantity of water per stamp than clean quartz. A fair average quantity would be 750 to 1000 gallons per hour for each box of five stamps. In general practice I have seldom found 1000 gallons per hour more than sufficient.

As to the most effective mesh for the screen or grating no definite rule can be given, as that depends so largely on the size of the gold particles contained in the gangue. The finer the particles the closer must be the mesh, and nothing but careful experiment will enable the battery manager to decide this most important point. The American slotted screens are best; they wear better than the punched gratings and can be used of finer gauge. Woven steel wire gauze is employed with good effect in some mills where especially fine trituration is required. This class of screen requires special care as it is somewhat fragile, but with intelligent treatment does good work.

The fall or inclination of the tables, both copper and blanket strakes, is also regulated by the class of ore. If it should be heavy then the fall must be steeper. A fair average drop is 3/4 inch to the foot. Be careful that your copper tables are thoroughly water-tight, for remember you are dealing with a very volatile metal, quicksilver; and where water will percolate mercury will penetrate.

The blanket tables are simply a continuation of the mercury tables, but covered with strips of coarse blanket, green baize, or other flocculent material, intended to arrest the heavier metallic particles which, owing to their refractory nature, have not been amalgamated.

The blanket table is, however, a very unsatisfactory concentrator at best, and is giving place to mechanical concentrators of various descriptions.

An ancient Egyptian gold washing table was used by the Egyptians in treating the gold ores of Lower Egypt. The ore was first ground, it is likely by means of some description of stone arrasts and then passed over the sloping table with water, the gold being retained in the riffles. In these the material would probably be mechanically agitated. Although for its era ingenious it will be plain to practical men that if the gold were fine the process would be very ineffective. Possibly, but of this I have no evidence, mercury was used to retain the gold on the riffles, as previously stated. This method of saving the precious metal was known to the ancients.

At a mine of which I was managing director the lode was almost entirely composed of sulphide of iron, carbonate of lime or calcspar, with a little silica. In this case it has been found best to crush without mercury, then run the pulp into pans, where it is concentrated. The concentrates are calcined in a common reverberatory furnace, and afterwards amalgamated with mercury in a special pan, the results as to the proportion of gold extracted being very satisfactory; but it does not therefore follow that this process would be the most suitable in another mine where the lode stuff, though in some respects similar, yet had points of difference.

I was lately consulted with respect to the treatment of a pyritic ore in a very promising mine, but could not recommend the above treatment, because though the pyrites in the gangue was similar, the bulk of the lode consisted of silica, consequently there would be a great waste of power in triturating the whole of the stuff to what, with regard to much of it, would be an unnecessary degree of fineness. I am of opinion that in cases such as this, where it is not intended to adopt the chlorination or cyanogen process, it will be found most economical to crush to a coarse gauge, concentrate, calcine the concentrates, and finally amalgamate in some suitable amalgamator.

Probably for this mode of treatment Krom rolls would be found more effective reducing agents than stampers, as with them the bulk of the ore can be broken to any required gauge and there would consequently be less loss in "slimes."

The great art in effective battery work is to crush your stuff to the required fineness only, and then to provide that each particle is brought into contact with the mercury either in box, trough, plate, or pan. To do this the flow of water must be carefully regulated; neither so much must be used as to carry the stuff off too quickly nor so little as to cause the troughs and plates to choke. In cold weather the water may be warmed by passing the feed-pipe through a tank into which the steam from the engine exhausts, and this will be found to keep the mercury bright and lively. But be careful no engine oil or grease mingles with the water, as grease on the copper tables will absolutely prevent amalgamation.

The first point, then, is to crush the gangue effectively, the degree of fineness being regulated by the fineness of the gold itself. This being done, then comes the question of saving the gold. If the quartz be clean, and the gold unmixed with base metal, the difficulty is small. All that is required is to ensure that each particle of the Royal metal shall be brought into contact with the mercury. The main object is to arrest the gold at the earliest possible stage; therefore, if you are treating clean stone containing free gold, either coarse or fine, I advise the use of mercury in the boxes, for the reason that a considerable proportion of the gold will be caught thereby, and settling to the bottom, or adhering to amalgamated plates in the boxes, where such are used, will not be afterwards affected by the crushing action, which might otherwise break up, or "flour," the mercury. On the whole, I rather favour the use of mercury in the box at any time, unless the ore is very refractory—that is, contains too great a proportion of base metals, particularly sulphides of iron, arsenic, etc., when the result will not be satisfactory, but may entail great loss by the escape of floured mercury carrying with it particles of gold. Here only educated intelligence, with experience, will assist the battery manager to adopt the right system.

The crushed stuff—generally termed the "pulp"—passes from the boxes through the "screens" or "gratings," and so on to the "tables"—i.e., sheets of copper amalgamated on the upper surface with mercury, and sometimes electroplated with silver and afterwards treated with mercury. Unless the quartz is very clean, and, consequently light, I am opposed to the form of stamper box with mercury troughs cast in the "lip," nor do I think that a trough under the lip is a good arrangement, as it usually gets so choked and covered with the heavy clinging base metals as to make it almost impossible for the gold to come in contact with the mercury. It will be found better where the gold is fine, or the gangue contains much base metal, to run the pulp from the lip of the battery into a "distributor."

The distributor is a wooden box the full width of the "mortar," having a perforated iron bottom set some three to four inches above the first copper plate, which should come up under the lip. The effect of this arrangement is that the pulp is dashed on the plate by the falling water, and the gold at once coming in contact with the mercury begins to accumulate and attract that which follows, till the amalgam becomes piled in little crater-shaped mounds, and thus 75 per cent of the gold is saved on the top plate.

I have tried a further adaptation of this process when treating ores containing a large percentage of iron oxide, where the bulk of the gold is impalpably fine, and contained in the "gossan." At the end of the blanket table, or at any point where the crushed stuff last passes before going to the "tailings heap," or "sludge pit," a "saver" is placed. The saver is a strong box about 15 in. square by 3 ft. high, one side of which is removable, but must fit tight. Nine slots are cut inside at 4 in. apart, and into these are fitted nine square perforated copper plates, having about eighty to a hundred 1/4 in. holes in each; the perforations should not come opposite each other. These plates are to be amalgamated on both sides with mercury, in which a very little sodium has been placed (if acid ores are being treated, zinc should be employed in place of sodium, and to prevent the plates becoming bare, if the stuff is very poor, thick zinc amalgam may be used with good effect; but in that case discontinue the sodium, and occasionally, if required, say once or twice in the day, mix an ounce of sulphuric acid in a quart of water and slowly pour it into the launder above the saver). Underneath the "saver" you require a few riffles, or troughs, to catch any waste mercury, but if not overfed there should be no waste. This simple appliance, which is automatic and requires little attention, will sometimes arrest a considerable quantity of gold.

We now come to the subsidiary processes of battery work, the "cleaning" of plates, and "scaling" same when it is desired to get all the gold off them, the cleaning and retorting of amalgam, and of the mercury, smelting gold, etc.

Plates should be tenderly treated, kept as smooth as possible, and when cleaning up after crushing, in your own battery, the amalgam—except, say, at half-yearly intervals—should be removed with a rubber only; the rubber is simply a square of black indiarubber or soft pine wood.

When crushing rich ore, and you want to get nearly all the gold off your plates, the scraper may be resorted to. This is usually made by the mine blacksmith from an old flat file which is cut in half, the top turned over, beaten out to a sharp blade, and kept sharp by touching it up on the grinding-stone. This, if carefully used, will remove the bulk of the amalgam without injury to the plate.

Various methods of "scaling" plates will be found among "Rules of Thumb."

Where base metals are present in the lode stuff frequent retortings of the mercury, say not less than once a month, will be found to have a good effect in keeping it pure and active. For this purpose, and in order to prevent stoppage of the machinery, a double quantity is necessary, so that half may be used alternately. Less care is required in retorting the mercury than in treating the amalgam, as the object in the one case is more to cleanse the metal of impurities than to save gold, which will for the most part have been extracted by squeezing through the chamois leather or calico. A good strong heat may therefore at once be applied to the retort and continued, the effect being to oxidise the arsenic, antimony, lead, etc., which, in the form of oxides, will not again amalgamate with the mercury, but will either lie on its surface under the water, into which the nozzle of the retort is inserted, or will float away on the surface of the water. I have also found that covering the top of the mercury with a few inches of broken charcoal when retorting has an excellent purifying effect.

In retorting amalgam, much care and attention is required.

First, never fill the retort too full, give plenty of room for expansion; for, when the heat is applied, the amalgam will rise like dough in an oven, and may be forced into the discharge pipe, the consequence being a loss of amalgam or the possible bursting of the retort. Next, be careful in applying the heat, which should be done gradually, commencing at the top. This is essential to prevent waste and to turn out a good-looking cake of gold, which all battery managers like to do, even if they purpose smelting into bars.

Sometimes special difficulties crop up in the process of separating the gold from the amalgam. At the first "cleaning up" on the Frasers Mine at Southern Cross, West Australia, great consternation was excited by the appearance of the retorted gold, which, as an old miner graphically put it, was "as black as the hind leg of a crow," and utterly unfit for smelting, owing to the presence of base metals. Some time after this I was largely interested in the Blackborne mine in the same district when a similar trouble arose. This I succeeded in surmounting, but a still more serious one was too much for me—i.e., the absence of payable gold in the stone. I give here an extract from the Australian Mining Standard, of December 9th, 1893, with reference to the mode of cleaning the amalgam which I adopted.

NEW METHOD OF SEPARATING GOLD FROM IMPURE AMALGAM.

I had submitted to me lately a sample of amalgam from a mine in West Australia which amalgam had proved a complete puzzle to the manager and amalgamator. The Mint returns showed a very large proportion of impurity, even in the smelted gold. When retorted only, the Mint authorities refused to take it after they had treated two cakes, one of 119 oz., which yielded only 35 oz. 5 dwt. standard gold, and one of 140 oz., which gave 41 oz. 10 dwt. The gold smelted on the mine was nearly as bad proportionately. Thus, 128 oz. smelted down at the Mint to 87 oz. 8 dwt. and 109 oz. to 55 oz. 10 dwt. The impurity was principally iron, a most unusual thing in my experience, and was due to two causes revealed by assay of the ore and analysis of the mine water, viz., an excess of arsenate of iron in the stone, and the presence in large proportions of mineral salts, principally chloride of Calcium CaCl., sodium NaCl, and magnesium MgCl2, in the mine water used in the battery. The exact analysis of the water was as follows:—

Carbonate of Iron FeCO3 2.76 grains per gallon Carbonate of Calcium CaCO3 7.61 grains per gallon Sulphate of Calcium CaSO4 81.71 grains per gallon Chloride of Calcium CaCl2 2797.84 grains per gallon Chloride of Magnesium MgCl2 610.13 grains per gallon Chloride of Sodium or Common Salt NaCl 5072.65 grains per gallon

Total solid matter 8572.70 = 19.5 oz. to the gallon.

It will be seen, then, that this water is nearly four times more salt that that of the sea. The effect of using a water of this character, as I have previously found, is to cause the amalgamation of considerable quantities of iron with the gold as in this case.

I received 10 oz. of amalgam, and having found what constituted its impurities proceeded to experiment as to its treatment. When retorted on the mine it was turned out in a black cake so impure as almost to make it impossible to smelt properly. I found the same result on first retorting, and after a number of experiments which need not be recapitulated though some were fairly effective, I hit on the following method, which was found to be most successful and will probably be so found in other localities where similarly unfavourable conditions prevail.

I took a small ball of amalgam, placed it in a double fold of new fine grained calico, and after soaking in hot water put it under a powerful press. The weight of the ball before pressing was 1583 gr. From this 383 gr. of mercury was expressed and five-eighths of a grain of gold was retorted from this expressed mercury. The residue, in the form of a dark, grey, and very friable cake, was powdered up between the fingers and retorted, when it became a brown powder; it was afterwards calcined on a flat sheet in the open air; result, 510 gr. of russet-coloured powder. Smelted with borax, the iron oxide readily separated with the slag; result, 311 gr. gold 871-1000 fine; a second smelting brought this up to 914-1000 fine. Proportion of smelted gold to amalgam, one-fifth.

The principal point about this mode of treatment is the squeezing out of the mercury, whereby the amalgam goes into the retort in the form of powder, thus preventing the slagging of the iron and enclosure of the gold. The second point of importance is thorough calcining before smelting.

Of course it would be practicable, if desired, to treat the powder with hydrochloric acid, and thus remove all the iron, but in a large way this would be too expensive, and my laboratory treatment, though necessarily on a small scale, was intended to be on a practical basis.

The amalgam at this mine was in this way afterwards treated with great success.

For the information of readers who do not understand the chemical symbols it may be said that

FeCO3 is carbonate of iron; CaCO3 is carbonate of calcium; CaSO4 is sulphate of calcium; CaCl2 is chloride of calcium; MgCl2 is chloride of magnesium; NaCl is chloride of sodium, or common salt.



CHAPTER VII

GOLD EXTRACTION—SECONDARY PROCESSES AND LIXIVIATION

Before any plan is adopted for treating the ore in a new mine the management should very seriously and carefully consider the whole circumstances of the case, taking into account the quantity and quality of the lode stuff to be operated on, and ascertain by analysis what are its component parts, for, as before stated, the treatment which will yield most satisfactory results with a certain class of gangue on one mine will sometimes, even when the material is apparently similar, prove a disastrous failure in another. Some time since I was glad to note that the manager of a prominent mine strongly discountenanced the purchase of any extracting plant until he was fully satisfied as to the character of the bulk of the ore he would have to treat. It would be well for the pockets of shareholders and the reputation of managers, if more of our mine superintendents followed this prudent and sensible course.

Having treated on gold extraction with mercury by amalgamated plates and their accessories, something must be said about secondary modes of saving in connection with the amalgamation process. The operations described hitherto have been the disintegration of the gold-bearing material and the extraction therefrom of the coarser free gold. But it must be understood that most auriferous lode stuff contains a proportion of sulphides of various metals, wherein a part of the gold, usually in a very finely divided state, is enclosed, and on this gold the mercury has no influence. Also many lodes contain hard heavy ferric ores, such as titanic iron, tungstate of iron, and hematite, in which gold is held. In others, again, are found considerable quantities of soft powdery iron oxide or "gossan," and compounds such as limonite, aluminous clay, etc., which, under the action of the crushing mill become finely divided and float off in water as "slimes," carrying with them atoms of gold, often microscopically small. To save the gold in such matrixes as these is an operation which even the best of our mechanical appliances have not yet fully accomplished.

Where there is not too great a proportion of base metals on which the solvent will act, and when the material is rich enough in gold to pay for the extra cost of treatment, chlorination or cyanisation are the best modes of extraction yet practically adopted.

Presuming, however, that we are working by the amalgamation process, and have crushed our stone and obtained the free gold, the next requirement is an effective concentrator. Of these there are many before the public, and some do excellent work, but do not act equally well in all circumstances. The first and most primitive is the blanket table, previously mentioned; but it can hardly be said to be very effective, and requires constant attention and frequent changing and washing of the strips of blanket.

Instead of blanket tables percussion tables are sometimes used, to which a jerking motion is given against the flow of the water and pulp, and by this means the heavier minerals are gathered towards the upper part of the table, and are from thence removed from time to time as they become concentrated.

I have seen this appliance doing fairly good work, but it is by no means a perfect concentrator.

Another form of "shaking table" is one in which the motion is given sideways, and this, whether amalgamated, or provided with small riffles, or covered with blanket, keeps the pulp lively and encourages the retention of the heavier particles, whether of gold or base metals containing gold. There has also been devised a rocking table the action of which is analogous to that of the ordinary miner's cradle. This appliance, working somewhat slowly, swings on rockers from side to side, and is usually employed in mills where, owing to the complexity of the ore, difficulties have been met with in amalgamating the gold. Riffles are provided and even very fine gold is sometimes effectively recovered by their aid.

The Frue vanner will, as a rule, act well when the pulp is sufficiently fine. It is really a adaptation of an old and simple apparatus used in China and India for washing gold dust from the sands of rivers. The original consisted of an endless band of strong cloth or closely woven matting, run on two horizontal rollers placed about seven feet apart, one being some inches lower than the other. The upper is caused to revolve by means of a handle. The cloth is thus dragged upwards against a small stream of water and sand fed to it by a second man, the first man not only turning the handle but giving a lateral motion to the band by means of a rope tied to one side.

Chinamen were working these forerunners of the Frue vanner forty years ago in Australia, and getting fair returns.

The Frue vanner is an endless indiarubber band drawn over an inclined table, to which a revolving and side motion is given by ingenious automatic mechanism, the pulp being automatically fed from the upper end, and the concentrates collected in a trough containing water in which the band is immersed in its passage under the table; the lighter particles wash over the lower end. The only faults with the vanner are—first, it is rather slow; and secondly, though so ingenious it is just a little complicated in construction for the average non-scientific operative.

Of pan concentrators there is an enormous selection, the principle in most being similar—i.e., a revolving muller, which triturates the sand, so freeing the tiny golden particles and admitting of their contact with the mercury. The mistake with respect to most of these machines is the attempt to grind and amalgamate in one operation. Even when the stone under treatment contains no deleterious compounds the simple action of grinding the hard siliceous particles has a bad effect on the quicksilver, causing it to separate into small globules, which either oxidising or becoming coated with the impurities contained in the ore will not reunite, but wash away in the slimes and take with them a percentage of the gold. As a grinder and concentrator, and in some cases as an amalgamator, when used exclusively for either purpose, the Watson and Denny pan is effective; but although successfully used at one mine I know, the mode there adopted would, for reasons previously given, be very wasteful in many other mines.

There is considerable misconception, even among men with some practical knowledge, as to the proper function of these secondary saving appliances; and sometimes good machines are condemned because they will not perform work for which they were never intended. It cannot be too clearly realized that the correct order of procedure for extracting the gold held in combination with base metals is—first, reduction of the particles to a uniform gauge and careful concentration only; next, the dissipation, usually by simple calcination, of substances in the concentrates inimical to the thorough absorption of the gold by the mercury; and lastly, the amalgamation of the gold and mercury.

For general purposes, where the gangue has not been crushed too fine, I think the Duncan pan will usually be found effective in saving the concentrates. In theory it is an enlargement of the alluvial miner's tin dish, and the motion imparted to it is similar to the eccentric motion of that simple separator.

The calcining may be effectively carried out in an ordinary reverberatory furnace, the only skill required being to prevent over roasting and so slagging the concentrates; or not sufficiently calcining so as to remove all deleterious constituents; the subject, however, is fully treated in Chapter VIII.

For amalgamating I prefer some form of settler to any further grinding appliance, but I note also improvements in the rotary amalgamating barrel, which, though slow, is, under favourable conditions, an effective amalgamator. The introduction of steam under pressure into an iron cylinder containing a charge of concentrates with mercury is said to have produced good results, and I am quite prepared to believe such would be the case, as we have long known that the application of steam to ores in course of amalgamation facilitates the process considerably.

Some seventeen years since I was engaged on the construction of a dry amalgamator in which sublimated mercury was passed from a retort through the descending gangue in a vertical cylinder, the material thence falling through an aperture into a revolving settler, the object being to save water on mines in dry country. The model, about quarter size, was completed when my attention was called to an American invention, in which the same result was stated to be attained more effectively by blowing the mercury spray through the triturated material by means of a steam jet. I had already encountered a difficulty, since found so obstructive by experimentalists in the same direction, that is, the getting of the mercury back into its liquid metallic form. This difficulty I am now convinced can be largely obviated by my own device of using a very weak solution of sulphuric acid (it can hardly be too weak) and adding a small quantity of zinc to the mercury. It is perfectly marvellous how some samples of mercury "sickened" or "floured" by bad treatment, may be brought back to the bright limpid metal by a judicious use of these inexpensive materials.

Thus it will probably be found practicable to crush dry and amalgamate semi-dry by passing the material in the form of a thin pasty mass to a settler, as in the old South American arrastra, and, by slowly stirring, recover the mercury, and with it the bulk of the gold.

The following is from the Australian Mining Standard, and was headed "Amalgamation Without Overflow":

"Recent experiments at the Ballarat School of Mines have proved that a deliverance from difficulties is at hand from an unexpected quarter. The despised Chilian mill and Wheeler pan, discarded at many mines, will solve the problem, but the keynote of success is amalgamation without overflow. Dispense with the overflow and the gold is saved.

"Two typical mines—the Great Mercury Proprietary Gold Mine, of Kuaotunu, N.Z., the other, the Pambula, N.S.W.—have lately been conducting a series of experiments with the object of saving their fine gold in an economical manner. The last and best trials made by these companies were at the Ballarat School of Mines, where amalgamation without overflow was put to a crucial test, in each case with the gratifying result that ninety-six per cent of the precious metal was secured. What this means to the Great Mercury Mine, for instance, can easily be imagined when it is understood that notwithstanding all the latest gold-saving adjuncts during the last six months 1260 tons of ore, worth 4l. 17s. 10 23d. a ton, have been put through for a saving of 1l. 9s. 1 23d. only; or in other words over two-thirds of the gold has gone to waste (for the time being) in the tailings, and in the tailings at the present moment lie the dividends that should have cheered shareholders' hearts.

"And now for the modus operandi, which, it must be remembered, is not hedged in by big royalties to any one, rights, patent or otherwise. The ore to be treated is first calcined, then put through a rock-breaker or stamper battery in a perfectly dry state. If the battery is used, ordinary precautions, of course, must be taken to prevent waste, or the dust becoming obnoxious to the workmen. The ore is then transferred to the Chilian mill and made to the consistency of porridge, the quicksilver being added. When the principal work of amalgamation is done (experience soon teaching the amount of grinding necessary), from the Chilian mill the paste (so to say) is passed to a Wheeler or any other good pan of a similar type, when the gold-saving operation is completed."

This being an experiment in the same direction as my own, I tried it on a small scale. I calcined some very troublesome ore till it was fairly "sweet," triturated it, and having reduced it with water to about the consistency of invalid's gruel, put it into a little berdan pan made from a "camp oven," which I had used for treating small quantities of concentrates, and from time to time drove a spray of mercury, wherein a small amount of zinc had been dissolved, into the pasty mass by means of a steam jet, added about half an ounce of sulphuric acid and kept the pan revolving for several hours. The result was an unusually successful amalgamation and consequent extraction—over ninety per cent.

Steam—or to use the scientific term, hydro-thermal action—has played such an important part in the deposition of metals that I cannot but think that under educated intelligence it will prove a powerful agent in their extraction. About fourteen years ago I obtained some rather remarkable results from simply boiling auriferous ferro-sulphides in water. There is in this alone an interesting, useful, and profitable field for investigation and experiment.

The most scientific and perfect mode of gold extraction (when the conditions are favourable) is lixiviation by means of chlorine, potassium cyanide, or other aurous solvent, for by this means as much as 98 per cent of the gold contained in suitable ores can be converted into its mineral salt, and being dissolved in water, re-deposited in metallic form for smelting; but lode stuff containing much lime would not be suitable for chlorination, or the presence of a considerable proportion of such a metal as copper, particularly in metallic form, would be fatal to success, while cyanide of potassium will also attack metals other than gold, and hence discount the effect of this solvent.

The earlier practical applications of chlorine to gold extraction were known as Mears' and Plattner's processes, and consisted in placing the material to be operated on in vats with water, and introducing chlorine gas at the bottom, the mixture being allowed to stand for a number of hours, the minimum about twelve, the maximum forty-eight. The chlorinated water was then drawn off containing the gold in solution which was deposited as a brown powder by the addition of sulphate of iron.

Great improvements on this slow and imperfect method have been made of late years, among the earlier of which was that of Messrs. Newbery and Vautin. They placed the pulp with water in a gaslight revolving cylinder, into which the chlorine was introduced, and atmospheric air to a pressure of 60 lb. to the square inch was pumped in. The cylinder with its contents was revolved for two hours, then the charge was withdrawn and drained nearly dry by suction, the resultant liquid being slowly filtered through broken charcoal on which the chloride crystals were deposited, in appearance much like the bromo-chlorides of silver ore seen on some of the black manganic oxides of the Barrier silver mines. The charcoal, with its adhering chlorides, was conveyed to the smelting-house and the gold smelted into bars of extremely pure metal. Messrs. Newbery and Vautin claimed for their process decreased time for the operation with increased efficiency.

At Mount Morgan, when I visited that celebrated mine, they were using what might be termed a composite adaptation process. Their chlorination works, the largest in the world, were putting through 1500 tons per week. The ore as it came from the mine was fed automatically into Krom roller mills, and after being crushed and sifted to regulation gauge was delivered into trucks and conveyed to the roasting furnaces, and thence to cooling floors, from which it was conveyed to the chlorinating shed. Here were long rows of revolving barrels, on the Newbery-Vautin principle, but with this marked difference, that the pressure in the barrel was obtained from an excess of the gas itself, generated from a charge of chloride of lime and sulphuric acid. On leaving the barrels the pulp ran into settling vats, somewhat on the Plattner plan, and the clear liquid having been drained off was passed through a charcoal filter, as adopted by Newbery and Vautin. The manager, Mr. Wesley Hall, stated that he estimated cost per ton was not more than 30s., and he expected shortly to reduce that when he began making his own sulphuric acid. As he was obtaining over 4 oz. to the ton the process was paying very well, but it will be seen that the price would be prohibitive for poor ores unless they could be concentrated before calcination.

The Pollok process is a newer, and stated to be a cheaper mode of lixiviation by chlorine. It is the invention of Mr. J. H. Pollok, of Glasgow University, and a strong Company was formed to work it. With him the gas is produced by the admixture of bisulphate of sodium (instead of sulphuric acid, which is a very costly chemical to transport) and chloride of lime. Water is then pumped into a strong receptacle containing the material for treatment and powerful hydraulic pressure is applied. The effect is stated to be the rapid change of the metal into its salt, which is dissolved in the water and afterwards treated with sulphate of iron, and so made to resume its metallic form.

It appears, however, to me that there is no essential difference in the pressure brought to bear for the quickening of the process. In each case it is an air cushion, induced in the one process by the pumping in of air to a cylinder partly filled with water, and in the other by pumping in water to a cylinder partly filled with air.

The process of extracting gold from lode stuff and tailings by means of cyanide of potassium is now largely used and may be thus briefly described:—It is chiefly applied to tailings, that is, crushed ore that has already passed over the amalgamating and blanket tables. The tailings are placed in vats, and subjected to the action of solutions of cyanide of potassium of varying strengths down to 0.2 per cent. These dissolve the gold, which is leached from the tailings, passed through boxes in which it is precipitated either by means of zinc shavings, electricity, or to the precipitant. The solution is made up to its former strength and passed again through fresh tailings. When the tailings contain a quantity of decomposed pyrites, partly oxidised, the acidity caused by the freed sulphuric acid requires to be neutralised by an alkali, caustic soda being usually employed.

When "cleaning up," the cyanide solution in the zinc precipitating boxes is replaced by clean water. After careful washing in the box, to cause all pure gold and zinc to fall to the bottom, the zinc shavings are taken out. The precipitates are then collected, and after calcination in a special furnace for the purpose of oxidising the zinc, are smelted in the usual manner.

The following description of an electrolytic method of gold deposition from a cyanide solution was given by Mr. A. L. Eltonhead before the Engineers' Club of Philadelphia.

A description of the process is as follows:—"The ore is crushed to a certain fineness, depending on the character of the gangue. It is then placed in leaching vats, with false bottoms for filtration, similar to other leaching plants. A solution of cyanide of potassium and other chemicals of known percentage is run over the pulp and left to stand a certain number of hours, depending on the amount of metal to be extracted. It is then drained off and another charge of the same solution is used, but of less strength, which is also drained. The pulp is now washed with clean water, which leaches all the gold and silver out, and leaves the tailings ready for discharge, either in cars or sluiced away by water, if it is plentiful.

"The chemical reaction of cyanide of potassium with gold is as follows, according to Elsner:—

2Au + 4KCy + O + H2O = 2KAuCy2 + 2KHO.

"That is, a double cyanide of gold and potassium is formed.

"All filtered solutions and washings from the leaching vats are saved and passed through a precipitating 'box' of novel construction, which may consist either of glass, iron or wood, and be made in any shape, either oval, round, or rectangular—if the latter, it will be about 10 ft. long, 4 ft. wide and 1 ft. high—and is partitioned off lengthwise into five compartments. Under each partition, on the inside or bottom of the 'box,' grooves may be cut a quarter-to a half-inch deep, extending parallel with the partitions to serve as a reservoir for the amalgam, and give a rolling motion to the solution as it passes along and through the four compartments. The centre compartment is used to hold the lead or other suitable anode and electrolyte.

"The anode is supported on a movable frame or bracket, so it may be moved either up or down as desired, it being worked by thumb-screws at each end.

"The electrolyte may consist of saturated solutions of soluble alkaline metals and earth. The sides or partitions of each compartment dip into the mercury, which must cover the 'box' evenly on the bottom to the depth of about a half-inch.

"Amalgamated copper strips or discs are placed in contact with the mercury and extended above it, to allow the gold and silver solution of cyanide to come in contact.

"The electrodes are connected with the dynamo; the anode of lead being positive and the cathode of mercury being negative. The dynamo is started, and a current of high amperage and low voltage is generated, generally 100 to 125 amperes, and with sufficient pressure to decompose the electrolyte between the anode and the cathode.

"As the gas is generated at the anode, a commotion is created in the liquid, which brings a fresh and saturated solution of electrolyte between the electrodes for electrolysis, and makes it continuous in its action.

"The solution of double cyanide of gold, silver, and potassium, which has been drained from the leaching vats, is passed over the mercury in the precipitating 'box' when the decomposition of the electrolyte by the electric current is being accomplished, the gold and silver are set free and unite with the mercury, and are also deposited on the plates or discs of copper, forming amalgam, which is collected and made marketable by the well known and tried methods. The above solution is regenerated with cyanide of potassium by the setting free of the metals in the passage over the 'box.'

"In using this solution again for a fresh charge of pulp, it is reinforced to the desired percentage, or strengthened with cyanide of potassium and other chemicals, and is always in good condition for continuing the operation of dissolving.

"The potassium acting on the water of the solution creates nascent hydrogen and potassium hydrate; the nascent hydrogen sets free the metals (gold and silver), which are precipitated into the mercury and form amalgam, leaving hydrocyanic acid; this latter combines with the potassium hydrate of the former reaction, thus forming cyanide of potassium. There are other reactions for which I have not at present the chemical formulas.

"As the solution passes over the mercury, the centre compartment of the 'box' is moved slowly longitudinally, which spreads the mercury, the solution is agitated and comes in perfect contact with the mercury, as well as the amalgamated plates or discs of copper, ensuring a perfect precipitation.

"It is not always necessary to precipitate all the gold and silver from the solution, for it is used over and over again indefinitely; but when it is required, it can be done perfectly and cheaply in a very short time.

"No solution leached from the pulp, containing cyanide of potassium, gold and silver, need be run to waste, which is in itself an enormous saving over the use of zinc shavings when handling large quantities of pulp and solution.

"Some of the advantages the electro-chemical process has over other cyanide processes are: Its cleanliness, quickness of action, cheapness, and large saving of cyanide of potassium by regeneration; not wasting the solutions, larger recovery of the gold and silver from the solutions; the cost of recovery less; the loss of gold, silver, and cyanide of potassium reduced to a minimum; the use of caustic alkali in such quantity as may be desired to keep the cyanide solution from being destroyed by the solidity of the pulp, and also sometimes to give warmth, as a warm cyanide solution will dissolve gold and silver quicker than a cold one. These caustic alkalies do not interfere with or prevent the perfect precipitation of the metals. The bullion recovered in this process is very fine, while the zinc-precipitated bullion is only about 700 fine.