FARADAY AS A DISCOVERER

by John Tyndall



Contents.

Preface.

Chapter 1. Parentage: introduction to the royal institution: earliest experiments: first royal society paper: marriage.

Chapter 2. Early researches: magnetic rotations: liquefaction of gases: heavy glass: Charles Anderson: contributions to physics.

Chapter 3. Discovery of Magneto-electricity: Explanation of Argo's magnetism of rotation: Terrestrial magneto-electric induction: The extra current.

Chapter 4. Points of Character.

Chapter 5. Identity of electricities; first researches on electro-chemistry.

Chapter 6. Laws of electro-chemical decomposition.

Chapter 7. Origin of power in the voltaic pile.

Chapter 8. Researches on frictional electricity: induction: conduction: specific inductive capacity: theory of contiguous particles.

Chapter 9. Rest needed—visit to Switzerland.

Chapter 10. Magnetization of light.

Chapter 11. Discovery of diamagnetism—researches on magne-crystallic action.

Chapter 12. Magnetism of flame and gases—atmospheric magnetism.

Chapter 13. Speculations: nature of matter: lines of force.

Chapter 14. Unity and convertibility of natural forces: theory of the electric current.

Chapter 15. Summary.

Chapter 16. Illustrations of Character.



Preface to the fifth edition.

Daily and weekly, from all parts of the world, I receive publications bearing upon the practical applications of electricity. This great movement, the ultimate outcome of which is not to be foreseen, had its origin in the discoveries made by Michael Faraday, sixty-two years ago. From these discoveries have sprung applications of the telephone order, together with various forms of the electric telegraph. From them have sprung the extraordinary advances made in electrical illumination. Faraday could have had but an imperfect notion of the expansions of which his discoveries were capable. Still he had a vivid and strong imagination, and I do not doubt that he saw possibilities which did not disclose themselves to the general scientific mind. He knew that his discoveries had their practical side, but he steadfastly resisted the seductions of this side, applying himself to the development of principles; being well aware that the practical question would receive due development hereafter.

During my sojourn in Switzerland this year, I read through the proofs of this new edition, and by my reading was confirmed in the conviction that the book ought not to be suffered to go out of print. The memoir was written under great pressure, but I am not ashamed of it as it stands. Glimpses of Faraday's character and gleams of his discoveries are there to be found which will be of interest to humanity to the end of time.

John Tyndall. Hind Head, December, 1893.



[Note.—It was, I believe, my husband's intention to substitute this Preface, written a few days before his death, for all former Prefaces. As, however, he had not the opportunity of revising the old prefatory pages himself, they have been allowed to remain just as they stood in the last edition.

Louisa C. Tyndall.]



Preface to the fourth edition.

When consulted a short time ago as to the republication of 'Faraday as a Discoverer,' it seemed to me that the labours, and points of character, of so great a worker and so good a man should not be allowed to vanish from the public eye. I therefore willingly fell in with the proposal of my Publishers to issue a new edition of the little book.

Royal Institution, February, 1884.



Preface to the second edition.

The experimental researches of Faraday are so voluminous, their descriptions are so detailed, and their wealth of illustration is so great, as to render it a heavy labour to master them. The multiplication of proofs, necessary and interesting when the new truths had to be established, are however less needful now when these truths have become household words in science. I have therefore tried in the following pages to compress the body, without injury to the spirit, of these imperishable investigations, and to present them in a form which should be convenient and useful to the student of the present day.

While I write, the volumes of the Life of Faraday by Dr. Bence Jones have reached my hands. To them the reader must refer for an account of Faraday's private relations. A hasty glance at the work shows me that the reverent devotion of the biographer has turned to admirable account the materials at his command.

The work of Dr. Bence Jones enables me to correct a statement regarding Wollaston's and Faraday's respective relations to the discovery of Magnetic Rotation. Wollaston's idea was to make the wire carrying a current rotate round its own axis: an idea afterwards realised by the celebrated Ampere. Faraday's discovery was to make the wire carrying the current revolve round the pole of a magnet and the reverse.

John Tyndall. Royal Institution: December, 1869.



FARADAY AS A DISCOVERER.



Chapter 1.

Parentage: introduction to the royal institution: earliest experiments: first royal society paper: marriage.

It has been thought desirable to give you and the world some image of MICHAEL FARADAY, as a scientific investigator and discoverer. The attempt to respond to this desire has been to me a labour of difficulty, if also a labour of love. For however well acquainted I may be with the researches and discoveries of that great master—however numerous the illustrations which occur to me of the loftiness of Faraday's character and the beauty of his life—still to grasp him and his researches as a whole; to seize upon the ideas which guided him, and connected them; to gain entrance into that strong and active brain, and read from it the riddle of the world—this is a work not easy of performance, and all but impossible amid the distraction of duties of another kind. That I should at one period or another speak to you regarding Faraday and his work is natural, if not inevitable; but I did not expect to be called upon to speak so soon. Still the bare suggestion that this is the fit and proper time for speech sent me immediately to my task: from it I have returned with such results as I could gather, and also with the wish that those results were more worthy than they are of the greatness of my theme.

It is not my intention to lay before you a life of Faraday in the ordinary acceptation of the term. The duty I have to perform is to give you some notion of what he has done in the world; dwelling incidentally on the spirit in which his work was executed, and introducing such personal traits as may be necessary to the completion of your picture of the philosopher, though by no means adequate to give you a complete idea of the man.

The newspapers have already informed you that Michael Faraday was born at Newington Butts, on September 22, 1791, and that he died at Hampton Court, on August 25, 1867. Believing, as I do, in the general truth of the doctrine of hereditary transmission—sharing the opinion of Mr. Carlyle, that 'a really able man never proceeded from entirely stupid parents'—I once used the privilege of my intimacy with Mr. Faraday to ask him whether his parents showed any signs of unusual ability. He could remember none. His father, I believe, was a great sufferer during the latter years of his life, and this might have masked whatever intellectual power he possessed. When thirteen years old, that is to say in 1804, Faraday was apprenticed to a bookseller and bookbinder in Blandford Street, Manchester Square: here he spent eight years of his life, after which he worked as a journeyman elsewhere.

You have also heard the account of Faraday's first contact with the Royal Institution; that he was introduced by one of the members to Sir Humphry Davy's last lectures, that he took notes of those lectures; wrote them fairly out, and sent them to Davy, entreating him at the same time to enable him to quit trade, which he detested, and to pursue science, which he loved. Davy was helpful to the young man, and this should never be forgotten: he at once wrote to Faraday, and afterwards, when an opportunity occurred, made him his assistant.[1] Mr. Gassiot has lately favoured me with the following reminiscence of this time:—

'Clapham Common, Surrey,

'November 28, 1867.

'My Dear Tyndall,—Sir H. Davy was accustomed to call on the late Mr. Pepys, in the Poultry, on his way to the London Institution, of which Pepys was one of the original managers; the latter told me that on one occasion Sir H. Davy, showing him a letter, said: "Pepys, what am I to do, here is a letter from a young man named Faraday; he has been attending my lectures, and wants me to give him employment at the Royal Institution—what can I do?" "Do?" replied Pepys, "put him to wash bottles; if he is good for anything he will do it directly, if he refuses he is good for nothing." "No, no," replied Davy; "we must try him with something better than that." The result was, that Davy engaged him to assist in the Laboratory at weekly wages.

'Davy held the joint office of Professor of Chemistry and Director of the Laboratory; he ultimately gave up the former to the late Professor Brande, but he insisted that Faraday should be appointed Director of the Laboratory, and, as Faraday told me, this enabled him on subsequent occasions to hold a definite position in the Institution, in which he was always supported by Davy. I believe he held that office to the last.

'Believe me, my dear Tyndall, yours truly,

'J. P. Gassiot.



'Dr. Tyndall.'

From a letter written by Faraday himself soon after his appointment as Davy's assistant, I extract the following account of his introduction to the Royal Institution:—

'London, Sept. 13, 1813.

'As for myself, I am absent (from home) nearly day and night, except occasional calls, and it is likely shall shortly be absent entirely, but this (having nothing more to say, and at the request of my mother) I will explain to you. I was formerly a bookseller and binder, but am now turned philosopher,[2] which happened thus:—Whilst an apprentice, I, for amusement, learnt a little chemistry and other parts of philosophy, and felt an eager desire to proceed in that way further. After being a journeyman for six months, under a disagreeable master, I gave up my business, and through the interest of a Sir H. Davy, filled the situation of chemical assistant to the Royal Institution of Great Britain, in which office I now remain; and where I am constantly employed in observing the works of nature, and tracing the manner in which she directs the order and arrangement of the world. I have lately had proposals made to me by Sir Humphry Davy to accompany him in his travels through Europe and Asia, as philosophical assistant. If I go at all I expect it will be in October next—about the end; and my absence from home will perhaps be as long as three years. But as yet all is uncertain.'

This account is supplemented by the following letter, written by Faraday to his friend De la Rive,[3] on the occasion of the death of Mrs. Marcet. The letter is dated September 2, 1858:—

'My Dear Friend,—Your subject interested me deeply every way; for Mrs. Marcet was a good friend to me, as she must have been to many of the human race. I entered the shop of a bookseller and bookbinder at the age of thirteen, in the year 1804, remained there eight years, and during the chief part of my time bound books. Now it was in those books, in the hours after work, that I found the beginning of my philosophy.

There were two that especially helped me, the "Encyclopaedia Britannica," from which I gained my first notions of electricity, and Mrs. Marcet's "Conversation on Chemistry," which gave me my foundation in that science.

'Do not suppose that I was a very deep thinker, or was marked as a precocious person. I was a very lively imaginative person, and could believe in the "Arabian Nights" as easily as in the "Encyclopaedia." But facts were important to me, and saved me. I could trust a fact, and always cross-examined an assertion. So when I questioned Mrs. Marcet's book by such little experiments as I could find means to perform, and found it true to the facts as I could understand them, I felt that I had got hold of an anchor in chemical knowledge, and clung fast to it. Thence my deep veneration for Mrs. Marcet—first as one who had conferred great personal good and pleasure on me; and then as one able to convey the truth and principle of those boundless fields of knowledge which concern natural things to the young, untaught, and inquiring mind.

'You may imagine my delight when I came to know Mrs. Marcet personally; how often I cast my thoughts backward, delighting to connect the past and the present; how often, when sending a paper to her as a thank-offering, I thought of my first instructress, and such like thoughts will remain with me.

'I have some such thoughts even as regards your own father; who was, I may say, the first who personally at Geneva, and afterwards by correspondence, encouraged, and by that sustained me.'

Twelve or thirteen years ago Mr. Faraday and myself quitted the Institution one evening together, to pay a visit to our friend Grove in Baker Street. He took my arm at the door, and, pressing it to his side in his warm genial way, said, 'Come, Tyndall, I will now show you something that will interest you.' We walked northwards, passed the house of Mr. Babbage, which drew forth a reference to the famous evening parties once assembled there. We reached Blandford Street, and after a little looking about he paused before a stationer's shop, and then went in. On entering the shop, his usual animation seemed doubled; he looked rapidly at everything it contained. To the left on entering was a door, through which he looked down into a little room, with a window in front facing Blandford Street. Drawing me towards him, he said eagerly, 'Look there, Tyndall, that was my working-place. I bound books in that little nook.' A respectable-looking woman stood behind the counter: his conversation with me was too low to be heard by her, and he now turned to the counter to buy some cards as an excuse for our being there. He asked the woman her name—her predecessor's name—his predecessor's name. 'That won't do,' he said, with good-humoured impatience; 'who was his predecessor?' 'Mr. Riebau,' she replied, and immediately added, as if suddenly recollecting herself, 'He, sir, was the master of Sir Charles Faraday.' 'Nonsense!' he responded, 'there is no such person.' Great was her delight when I told her the name of her visitor; but she assured me that as soon as she saw him running about the shop, she felt-though she did not know why—that it must be 'Sir Charles Faraday.'

Faraday did, as you know, accompany Davy to Rome: he was re-engaged by the managers of the Royal Institution on May 15, 1815. Here he made rapid progress in chemistry, and after a time was entrusted with easy analyses by Davy. In those days the Royal Institution published 'The Quarterly Journal of Science,' the precursor of our own 'Proceedings.' Faraday's first contribution to science appeared in that journal in 1816. It was an analysis of some caustic lime from Tuscany, which had been sent to Davy by the Duchess of Montrose. Between this period and 1818 various notes and short papers were published by Faraday. In 1818 he experimented upon 'Sounding Flames.' Professor Auguste De la Rive had investigated those sounding flames, and had applied to them an explanation which completely accounted for a class of sounds discovered by himself, but did not account for those known to his predecessors. By a few simple and conclusive experiments, Faraday proved the explanation insufficient. It is an epoch in the life of a young man when he finds himself correcting a person of eminence, and in Faraday's case, where its effect was to develop a modest self-trust, such an event could not fail to act profitably.

From time to time between 1818 and 1820 Faraday published scientific notes and notices of minor weight. At this time he was acquiring, not producing; working hard for his master and storing and strengthening his own mind. He assisted Mr. Brande in his lectures, and so quietly, skilfully, and modestly was his work done, that Mr. Brande's vocation at the time was pronounced 'lecturing on velvet.' In 1820 Faraday published a chemical paper 'on two new compounds of chlorine and carbon, and on a new compound of iodine, carbon, and hydrogen.' This paper was read before the Royal Society on December 21, 1820, and it was the first of his that was honoured with a place in the 'Philosophical Transactions.'

On June 12, 1821, he married, and obtained leave to bring his young wife into his rooms at the Royal Institution. There for forty-six years they lived together, occupying the suite of apartments which had been previously in the successive occupancy of Young, Davy, and Brande. At the time of her marriage Mrs. Faraday was twenty-one years of age, he being nearly thirty. Regarding this marriage I will at present limit myself to quoting an entry written in Faraday's own hand in his book of diplomas, which caught my eye while in his company some years ago. It ran thus:—

'25th January, 1847. 'Amongst these records and events, I here insert the date of one which, as a source of honour and happiness, far exceeds all the rest. We were married on June 12, 1821.

'M. Faraday.'

Then follows the copy of the minutes, dated May 21, 1821, which gave him additional rooms, and thus enabled him to bring his wife to the Royal Institution. A feature of Faraday's character which I have often noticed makes itself apparent in this entry. In his relations to his wife he added chivalry to affection.

Footnotes to Chapter 1

[1] Here is Davy's recommendation of Faraday, presented to the managers of the Royal Institution, at a meeting on the 18th of March, 1813, Charles Hatchett, Esq., in the chair:—

'Sir Humphry Davy has the honour to inform the managers that he has found a person who is desirous to occupy the situation in the Institution lately filled by William Payne. His name is Michael Faraday. He is a youth of twenty-two years of age. As far as Sir H. Davy has been able to observe or ascertain, he appears well fitted for the situation. His habits seem good; his disposition active and cheerful, and his manner intelligent. He is willing to engage himself on the same terms as given to Mr. Payne at the time of quitting the Institution.

'Resolved,—That Michael Faraday be engaged to fill the situation lately occupied by Mr. Payne, on the same terms.'

[2] Faraday loved this word and employed it to the last; he had an intense dislike to the modern term physicist.

[3] To whom I am indebted for a copy of the original letter.



Chapter 2.

Early researches: magnetic rotations: liquefaction of gases: heavy glass: Charles Anderson: contributions to physics.

Oersted, in 1820, discovered the action of a voltaic current on a magnetic needle; and immediately afterwards the splendid intellect of Ampere succeeded in showing that every magnetic phenomenon then known might be reduced to the mutual action of electric currents. The subject occupied all men's thoughts: and in this country Dr. Wollaston sought to convert the deflection of the needle by the current into a permanent rotation of the needle round the current. He also hoped to produce the reciprocal effect of causing a current to rotate round a magnet. In the early part of 1821, Wollaston attempted to realise this idea in the presence of Sir Humphry Davy in the laboratory of the Royal Institution.[1] This was well calculated to attract Faraday's attention to the subject. He read much about it; and in the months of July, August, and September he wrote a 'history of the progress of electro-magnetism,' which he published in Thomson's 'Annals of Philosophy.' Soon afterwards he took up the subject of 'Magnetic Rotations,' and on the morning of Christmas-day, 1821, he called his wife to witness, for the first time, the revolution of a magnetic needle round an electric current. Incidental to the 'historic sketch,' he repeated almost all the experiments there referred to; and these, added to his own subsequent work, made him practical master of all that was then known regarding the voltaic current. In 1821, he also touched upon a subject which subsequently received his closer attention—the vaporization of mercury at common temperatures; and immediately afterwards conducted, in company with Mr. Stodart, experiments on the alloys of steel. He was accustomed in after years to present to his friends razors formed from one of the alloys then discovered.

During Faraday's hours of liberty from other duties, he took up subjects of inquiry for himself; and in the spring of 1823, thus self-prompted, he began the examination of a substance which had long been regarded as the chemical element chlorine, in a solid form, but which Sir Humphry Davy, in 1810, had proved to be a hydrate of chlorine, that is, a compound of chlorine and water. Faraday first analysed this hydrate, and wrote out an account of its composition. This account was looked over by Davy, who suggested the heating of the hydrate under pressure in a sealed glass tube. This was done. The hydrate fused at a blood-heat, the tube became filled with a yellow atmosphere, and was afterwards found to contain two liquid substances. Dr. Paris happened to enter the laboratory while Faraday was at work. Seeing the oily liquid in his tube, he rallied the young chemist for his carelessness in employing soiled vessels. On filing off the end of the tube, its contents exploded and the oily matter vanished. Early next morning, Dr. Paris received the following note:—

'Dear Sir,—The oil you noticed yesterday turns out to be liquid chlorine.

'Yours faithfully,

'M. Faraday.'[2]

The gas had been liquefied by its own pressure. Faraday then tried compression with a syringe, and succeeded thus in liquefying the gas.

To the published account of this experiment Davy added the following note:—'In desiring Mr. Faraday to expose the hydrate of chlorine in a closed glass tube, it occurred to me that one of three things would happen: that decomposition of water would occur;... or that the chlorine would separate in a fluid state.' Davy, moreover, immediately applied the method of self-compressing atmosphere to the liquefaction of muriatic gas. Faraday continued the experiments, and succeeded in reducing a number of gases till then deemed permanent to the liquid condition. In 1844 he returned to the subject, and considerably expanded its limits. These important investigations established the fact that gases are but the vapours of liquids possessing a very low boiling-point, and gave a sure basis to our views of molecular aggregation. The account of the first investigation was read before the Royal Society on April 10, 1823, and was published, in Faraday's name, in the 'Philosophical Transactions.' The second memoir was sent to the Royal Society on December 19, 1844. I may add that while he was conducting his first experiments on the liquefaction of gases, thirteen pieces of glass were on one occasion driven by an explosion into Faraday's eye.

Some small notices and papers, including the observation that glass readily changes colour in sunlight, follow here. In 1825 and 1826 Faraday published papers in the 'Philosophical Transactions' on 'new compounds of carbon and hydrogen,' and on 'sulphonaphthalic acid.' In the former of these papers he announced the discovery of Benzol, which, in the hands of modern chemists, has become the foundation of our splendid aniline dyes. But he swerved incessantly from chemistry into physics; and in 1826 we find him engaged in investigating the limits of vaporization, and showing, by exceedingly strong and apparently conclusive arguments, that even in the case of mercury such a limit exists; much more he conceived it to be certain that our atmosphere does not contain the vapour of the fixed constituents of the earth's crust. This question, I may say, is likely to remain an open one. Dr. Rankine, for example, has lately drawn attention to the odour of certain metals; whence comes this odour, if it be not from the vapour of the metal?

In 1825 Faraday became a member of a committee, to which Sir John Herschel and Mr. Dollond also belonged, appointed by the Royal Society to examine, and if possible improve, the manufacture of glass for optical purposes. Their experiments continued till 1829, when the account of them constituted the subject of a 'Bakerian Lecture.' This lectureship, founded in 1774 by Henry Baker, Esq., of the Strand, London, provides that every year a lecture shall be given before the Royal Society, the sum of four pounds being paid to the lecturer. The Bakerian Lecture, however, has long since passed from the region of pay to that of honour, papers of mark only being chosen for it by the council of the Society. Faraday's first Bakerian Lecture, 'On the Manufacture of Glass for Optical Purposes,' was delivered at the close of 1829. It is a most elaborate and conscientious description of processes, precautions, and results: the details were so exact and so minute, and the paper consequently so long, that three successive sittings of the Royal Society were taken up by the delivery of the lecture.[3] This glass did not turn out to be of important practical use, but it happened afterwards to be the foundation of two of Faraday's greatest discoveries.[4]

The experiments here referred to were commenced at the Falcon Glass Works, on the premises of Messrs. Green and Pellatt, but Faraday could not conveniently attend to them there. In 1827, therefore, a furnace was erected in the yard of the Royal Institution; and it was at this time, and with a view of assisting him at the furnace, that Faraday engaged Sergeant Anderson, of the Royal Artillery, the respectable, truthful, and altogether trustworthy man whose appearance here is so fresh in our memories. Anderson continued to be the reverential helper of Faraday and the faithful servant of this Institution for nearly forty years.[5]

In 1831 Faraday published a paper, 'On a peculiar class of Optical Deceptions,' to which I believe the beautiful optical toy called the Chromatrope owes its origin. In the same year he published a paper on Vibrating Surfaces, in which he solved an acoustical problem which, though of extreme simplicity when solved, appears to have baffled many eminent men. The problem was to account for the fact that light bodies, such as the seed of lycopodium, collected at the vibrating parts of sounding plates, while sand ran to the nodal lines. Faraday showed that the light bodies were entangled in the little whirlwinds formed in the air over the places of vibration, and through which the heavier sand was readily projected. Faraday's resources as an experimentalist were so wonderful, and his delight in experiment was so great, that he sometimes almost ran into excess in this direction. I have heard him say that this paper on vibrating surfaces was too heavily laden with experiments.

Footnotes to Chapter 2

[1] The reader's attention is directed to the concluding paragraph of the 'Preface to the Second Edition written in December, 1869. Also to the Life of Faraday by Dr. Bence Jones, vol. i. p. 338 et seq.

[2] Paris: Life of Davy, p. 391.

[3] Viz., November 19, December 3 and 10.

[4] I make the following extract from a letter from Sir John Herschel, written to me from Collingwood, on the 3rd of November, 1867:—'I will take this opportunity to mention that I believe myself to have originated the suggestion of the employment of borate of lead for optical purposes. It was somewhere in the year 1822, as well as I can recollect, that I mentioned it to Sir James (then Mr.) South; and, in consequence, the trial was made in his laboratory in Blackman Street, by precipitating and working a large quantity of borate of lead, and fusing it under a muffle in a porcelain evaporating dish. A very limpid (though slightly yellow) glass resulted, the refractive index 1.866! (which you will find set down in my table of refractive indices in my article "Light," Encyclopaedia Metropolitana). It was, however, too soft for optical use as an object- glass. This Faraday overcame, at least to a considerable degree, by the introduction of silica.'

[5] Regarding Anderson, Faraday writes thus in 1845:—'I cannot resist the occasion that is thus offered to me of mentioning the name of Mr. Anderson, who came to me as an assistant in the glass experiments, and has remained ever since in the laboratory of the Royal Institution. He assisted me in all the researches into which I have entered since that time; and to his care, steadiness, exactitude, and faithfulness in the performance of all that has been committed to his charge, I am much indebted.—M. F.' (Exp. Researches, vol. iii. p. 3, footnote.)



Chapter 3.

Discovery of Magneto-electricity: Explanation of Argo's magnetism of rotation: Terrestrial magneto-electric induction: The extra current.

The work thus referred to, though sufficient of itself to secure no mean scientific reputation, forms but the vestibule of Faraday's achievements. He had been engaged within these walls for eighteen years. During part of the time he had drunk in knowledge from Davy, and during the remainder he continually exercised his capacity for independent inquiry. In 1831 we have him at the climax of his intellectual strength, forty years of age, stored with knowledge and full of original power. Through reading, lecturing, and experimenting, he had become thoroughly familiar with electrical science: he saw where light was needed and expansion possible. The phenomena of ordinary electric induction belonged, as it were, to the alphabet of his knowledge: he knew that under ordinary circumstances the presence of an electrified body was sufficient to excite, by induction, an unelectrified body. He knew that the wire which carried an electric current was an electrified body, and still that all attempts had failed to make it excite in other wires a state similar to its own.

What was the reason of this failure? Faraday never could work from the experiments of others, however clearly described. He knew well that from every experiment issues a kind of radiation, luminous in different degrees to different minds, and he hardly trusted himself to reason upon an experiment that he had not seen. In the autumn of 1831 he began to repeat the experiments with electric currents, which, up to that time, had produced no positive result. And here, for the sake of younger inquirers, if not for the sake of us all, it is worth while to dwell for a moment on a power which Faraday possessed in an extraordinary degree. He united vast strength with perfect flexibility. His momentum was that of a river, which combines weight and directness with the ability to yield to the flexures of its bed. The intentness of his vision in any direction did not apparently diminish his power of perception in other directions; and when he attacked a subject, expecting results he had the faculty of keeping his mind alert, so that results different from those which he expected should not escape him through preoccupation.

He began his experiments 'on the induction of electric currents' by composing a helix of two insulated wires which were wound side by side round the same wooden cylinder. One of these wires he connected with a voltaic battery of ten cells, and the other with a sensitive galvanometer. When connection with the battery was made, and while the current flowed, no effect whatever was observed at the galvanometer. But he never accepted an experimental result, until he had applied to it the utmost power at his command. He raised his battery from 10 cells to 120 cells, but without avail. The current flowed calmly through the battery wire without producing, during its flow, any sensible result upon the galvanometer.

'During its flow,' and this was the time when an effect was expected—but here Faraday's power of lateral vision, separating, as it were, from the line of expectation, came into play—he noticed that a feeble movement of the needle always occurred at the moment when he made contact with the battery; that the needle would afterwards return to its former position and remain quietly there unaffected by the flowing current. At the moment, however, when the circuit was interrupted the needle again moved, and in a direction opposed to that observed on the completion of the circuit.

This result, and others of a similar kind, led him to the conclusion 'that the battery current through the one wire did in reality induce a similar current through the other; but that it continued for an instant only, and partook more of the nature of the electric wave from a common Leyden jar than of the current from a voltaic battery.' The momentary currents thus generated were called induced currents, while the current which generated them was called the inducing current. It was immediately proved that the current generated at making the circuit was always opposed in direction to its generator, while that developed on the rupture of the circuit coincided in direction with the inducing current. It appeared as if the current on its first rush through the primary wire sought a purchase in the secondary one, and, by a kind of kick, impelled backward through the latter an electric wave, which subsided as soon as the primary current was fully established.

Faraday, for a time, believed that the secondary wire, though quiescent when the primary current had been once established, was not in its natural condition, its return to that condition being declared by the current observed at breaking the circuit. He called this hypothetical state of the wire the electro-tonic state: he afterwards abandoned this hypothesis, but seemed to return to it in later life. The term electro-tonic is also preserved by Professor Du Bois Reymond to express a certain electric condition of the nerves, and Professor Clerk Maxwell has ably defined and illustrated the hypothesis in the Tenth Volume of the 'Transactions of the Cambridge Philosophical Society.'

The mere approach of a wire forming a closed curve to a second wire through which a voltaic current flowed was then shown by Faraday to be sufficient to arouse in the neutral wire an induced current, opposed in direction to the inducing current; the withdrawal of the wire also generated a current having the same direction as the inducing current; those currents existed only during the time of approach or withdrawal, and when neither the primary nor the secondary wire was in motion, no matter how close their proximity might be, no induced current was generated.

Faraday has been called a purely inductive philosopher. A great deal of nonsense is, I fear, uttered in this land of England about induction and deduction. Some profess to befriend the one, some the other, while the real vocation of an investigator, like Faraday, consists in the incessant marriage of both. He was at this time full of the theory of Ampere, and it cannot be doubted that numbers of his experiments were executed merely to test his deductions from that theory. Starting from the discovery of Oersted, the illustrious French philosopher had shown that all the phenomena of magnetism then known might be reduced to the mutual attractions and repulsions of electric currents. Magnetism had been produced from electricity, and Faraday, who all his life long entertained a strong belief in such reciprocal actions, now attempted to effect the evolution of electricity from magnetism. Round a welded iron ring he placed two distinct coils of covered wire, causing the coils to occupy opposite halves of the ring. Connecting the ends of one of the coils with a galvanometer, he found that the moment the ring was magnetised, by sending a current through the other coil, the galvanometer needle whirled round four or five times in succession. The action, as before, was that of a pulse, which vanished immediately. On interrupting the circuit, a whirl of the needle in the opposite direction occurred. It was only during the time of magnetization or demagnetization that these effects were produced. The induced currents declared a change of condition only, and they vanished the moment the act of magnetization or demagnetization was complete.

The effects obtained with the welded ring were also obtained with straight bars of iron. Whether the bars were magnetised by the electric current, or were excited by the contact of permanent steel magnets, induced currents were always generated during the rise, and during the subsidence of the magnetism. The use of iron was then abandoned, and the same effects were obtained by merely thrusting a permanent steel magnet into a coil of wire. A rush of electricity through the coil accompanied the insertion of the magnet; an equal rush in the opposite direction accompanied its withdrawal. The precision with which Faraday describes these results, and the completeness with which he defines the boundaries of his facts, are wonderful. The magnet, for example, must not be passed quite through the coil, but only half through; for if passed wholly through, the needle is stopped as by a blow, and then he shows how this blow results from a reversal of the electric wave in the helix. He next operated with the powerful permanent magnet of the Royal Society, and obtained with it, in an exalted degree, all the foregoing phenomena.

And now he turned the light of these discoveries upon the darkest physical phenomenon of that day. Arago had discovered, in 1824, that a disk of non-magnetic metal had the power of bringing a vibrating magnetic needle suspended over it rapidly to rest; and that on causing the disk to rotate the magnetic needle rotated along with it. When both were quiescent, there was not the slightest measurable attraction or repulsion exerted between the needle and the disk; still when in motion the disk was competent to drag after it, not only a light needle, but a heavy magnet. The question had been probed and investigated with admirable skill both by Arago and Ampere, and Poisson had published a theoretic memoir on the subject; but no cause could be assigned for so extraordinary an action. It had also been examined in this country by two celebrated men, Mr. Babbage and Sir John Herschel; but it still remained a mystery. Faraday always recommended the suspension of judgment in cases of doubt. 'I have always admired,' he says, 'the prudence and philosophical reserve shown by M. Arago in resisting the temptation to give a theory of the effect he had discovered, so long as he could not devise one which was perfect in its application, and in refusing to assent to the imperfect theories of others.' Now, however, the time for theory had come. Faraday saw mentally the rotating disk, under the operation of the magnet, flooded with his induced currents, and from the known laws of interaction between currents and magnets he hoped to deduce the motion observed by Arago. That hope he realised, showing by actual experiment that when his disk rotated currents passed through it, their position and direction being such as must, in accordance with the established laws of electro-magnetic action, produce the observed rotation.

Introducing the edge of his disk between the poles of the large horseshoe magnet of the Royal Society, and connecting the axis and the edge of the disk, each by a wire with a galvanometer, he obtained, when the disk was turned round, a constant flow of electricity. The direction of the current was determined by the direction of the motion, the current being reversed when the rotation was reversed. He now states the law which rules the production of currents in both disks and wires, and in so doing uses, for the first time, a phrase which has since become famous. When iron filings are scattered over a magnet, the particles of iron arrange themselves in certain determinate lines called magnetic curves. In 1831, Faraday for the first time called these curves 'lines of magnetic force'; and he showed that to produce induced currents neither approach to nor withdrawal from a magnetic source, or centre, or pole, was essential, but that it was only necessary to cut appropriately the lines of magnetic force. Faraday's first paper on Magneto-electric Induction, which I have here endeavoured to condense, was read before the Royal Society on the 24th of November, 1831.

On January 12, 1832, he communicated to the Royal Society a second paper on Terrestrial Magneto-electric Induction, which was chosen as the Bakerian Lecture for the year. He placed a bar of iron in a coil of wire, and lifting the bar into the direction of the dipping needle, he excited by this action a current in the coil. On reversing the bar, a current in the opposite direction rushed through the wire. The same effect was produced when, on holding the helix in the line of dip, a bar of iron was thrust into it. Here, however, the earth acted on the coil through the intermediation of the bar of iron. He abandoned the bar and simply set a copper plate spinning in a horizontal plane; he knew that the earth's lines of magnetic force then crossed the plate at an angle of about 70degrees. When the plate spun round, the lines of force were intersected and induced currents generated, which produced their proper effect when carried from the plate to the galvanometer. 'When the plate was in the magnetic meridian, or in any other plane coinciding with the magnetic dip, then its rotation produced no effect upon the galvanometer.'

At the suggestion of a mind fruitful in suggestions of a profound and philosophic character—I mean that of Sir John Herschel—Mr. Barlow, of Woolwich, had experimented with a rotating iron shell. Mr. Christie had also performed an elaborate series of experiments on a rotating iron disk. Both of them had found that when in rotation the body exercised a peculiar action upon the magnetic needle, deflecting it in a manner which was not observed during quiescence; but neither of them was aware at the time of the agent which produced this extraordinary deflection. They ascribed it to some change in the magnetism of the iron shell and disk.

But Faraday at once saw that his induced currents must come into play here, and he immediately obtained them from an iron disk. With a hollow brass ball, moreover, he produced the effects obtained by Mr. Barlow. Iron was in no way necessary: the only condition of success was that the rotating body should be of a character to admit of the formation of currents in its substance: it must, in other words, be a conductor of electricity. The higher the conducting power the more copious were the currents. He now passes from his little brass globe to the globe of the earth. He plays like a magician with the earth's magnetism. He sees the invisible lines along which its magnetic action is exerted, and sweeping his wand across these lines evokes this new power. Placing a simple loop of wire round a magnetic needle he bends its upper portion to the west: the north pole of the needle immediately swerves to the east: he bends his loop to the east, and the north pole moves to the west. Suspending a common bar magnet in a vertical position, he causes it to spin round its own axis. Its pole being connected with one end of a galvanometer wire, and its equator with the other end, electricity rushes round the galvanometer from the rotating magnet. He remarks upon the 'singular independence' of the magnetism and the body of the magnet which carries it. The steel behaves as if it were isolated from its own magnetism.

And then his thoughts suddenly widen, and he asks himself whether the rotating earth does not generate induced currents as it turns round its axis from west to east. In his experiment with the twirling magnet the galvanometer wire remained at rest; one portion of the circuit was in motion relatively to another portion. But in the case of the twirling planet the galvanometer wire would necessarily be carried along with the earth; there would be no relative motion. What must be the consequence? Take the case of a telegraph wire with its two terminal plates dipped into the earth, and suppose the wire to lie in the magnetic meridian. The ground underneath the wire is influenced like the wire itself by the earth's rotation; if a current from south to north be generated in the wire, a similar current from south to north would be generated in the earth under the wire; these currents would run against the same terminal plate, and thus neutralise each other.

This inference appears inevitable, but his profound vision perceived its possible invalidity. He saw that it was at least possible that the difference of conducting power between the earth and the wire might give one an advantage over the other, and that thus a residual or differential current might be obtained. He combined wires of different materials, and caused them to act in opposition to each other, but found the combination ineffectual. The more copious flow in the better conductor was exactly counterbalanced by the resistance of the worse. Still, though experiment was thus emphatic, he would clear his mind of all discomfort by operating on the earth itself. He went to the round lake near Kensington Palace, and stretched 480 feet of copper wire, north and south, over the lake, causing plates soldered to the wire at its ends to dip into the water. The copper wire was severed at the middle, and the severed ends connected with a galvanometer. No effect whatever was observed. But though quiescent water gave no effect, moving water might. He therefore worked at London Bridge for three days during the ebb and flow of the tide, but without any satisfactory result. Still he urges, 'Theoretically it seems a necessary consequence, that where water is flowing there electric currents should be formed. If a line be imagined passing from Dover to Calais through the sea, and returning through the land, beneath the water, to Dover, it traces out a circuit of conducting matter one part of which, when the water moves up or down the channel, is cutting the magnetic curves of the earth, whilst the other is relatively at rest.... There is every reason to believe that currents do run in the general direction of the circuit described, either one way or the other, according as the passage of the waters is up or down the channel.' This was written before the submarine cable was thought of, and he once informed me that actual observation upon that cable had been found to be in accordance with his theoretic deduction.[1]

Three years subsequent to the publication of these researches—that is to say, on January 29, 1835—Faraday read before the Royal Society a paper 'On the influence by induction of an electric current upon itself.' A shock and spark of a peculiar character had been observed by a young man named William Jenkin, who must have been a youth of some scientific promise, but who, as Faraday once informed me, was dissuaded by his own father from having anything to do with science. The investigation of the fact noticed by Mr. Jenkin led Faraday to the discovery of the extra current, or the current induced in the primary wire itself at the moments of making and breaking contact, the phenomena of which he described and illustrated in the beautiful and exhaustive paper referred to.

Seven-and-thirty years have passed since the discovery of magneto-electricity; but, if we except the extra current, until quite recently nothing of moment was added to the subject. Faraday entertained the opinion that the discoverer of a great law or principle had a right to the 'spoils'—this was his term—arising from its illustration; and guided by the principle he had discovered, his wonderful mind, aided by his wonderful ten fingers, overran in a single autumn this vast domain, and hardly left behind him the shred of a fact to be gathered by his successors.

And here the question may arise in some minds, What is the use of it all? The answer is, that if man's intellectual nature thirsts for knowledge, then knowledge is useful because it satisfies this thirst. If you demand practical ends, you must, I think, expand your definition of the term practical, and make it include all that elevates and enlightens the intellect, as well as all that ministers to the bodily health and comfort of men. Still, if needed, an answer of another kind might be given to the question 'What is its use?' As far as electricity has been applied for medical purposes, it has been almost exclusively Faraday's electricity. You have noticed those lines of wire which cross the streets of London. It is Faraday's currents that speed from place to place through these wires. Approaching the point of Dungeness, the mariner sees an unusually brilliant light, and from the noble phares of La Heve the same light flashes across the sea. These are Faraday's sparks exalted by suitable machinery to sunlike splendour. At the present moment the Board of Trade and the Brethren of the Trinity House, as well as the Commissioners of Northern Lights, are contemplating the introduction of the Magneto-electric Light at numerous points upon our coasts; and future generations will be able to refer to those guiding stars in answer to the question. What has been the practical use of the labours of Faraday? But I would again emphatically say, that his work needs no such justification, and that if he had allowed his vision to be disturbed by considerations regarding the practical use of his discoveries, those discoveries would never have been made by him. 'I have rather,' he writes in 1831, 'been desirous of discovering new facts and new relations dependent on magneto-electric induction, than of exalting the force of those already obtained; being assured that the latter would find their full development hereafter.'

In 1817, when lecturing before a private society in London on the element chlorine, Faraday thus expressed himself with reference to this question of utility. 'Before leaving this subject, I will point out the history of this substance, as an answer to those who are in the habit of saying to every new fact. "What is its use?" Dr. Franklin says to such, "What is the use of an infant?" The answer of the experimentalist is, "Endeavour to make it useful." When Scheele discovered this substance, it appeared to have no use; it was in its infancy and useless state, but having grown up to maturity, witness its powers, and see what endeavours to make it useful have done.'

Footnote to Chapter 3

[1] I am indebted to a friend for the following exquisite morsel:—'A short time after the publication of Faraday's first researches in magneto-electricity, he attended the meeting of the British Association at Oxford, in 1832. On this occasion he was requested by some of the authorities to repeat the celebrated experiment of eliciting a spark from a magnet, employing for this purpose the large magnet in the Ashmolean Museum. To this he consented, and a large party assembled to witness the experiments, which, I need not say, were perfectly successful. Whilst he was repeating them a dignitary of the University entered the room, and addressing himself to Professor Daniell, who was standing near Faraday, inquired what was going on. The Professor explained to him as popularly as possible this striking result of Faraday's great discovery. The Dean listened with attention and looked earnestly at the brilliant spark, but a moment after he assumed a serious countenance and shook his head; "I am sorry for it," said he, as he walked away; in the middle of the room he stopped for a moment and repeated, "I am sorry for it:" then walking towards the door, when the handle was in his hand he turned round and said, "Indeed I am sorry for it; it is putting new arms into the hands of the incendiary." This occurred a short time after the papers had been filled with the doings of the hayrick burners. An erroneous statement of what fell from the Dean's mouth was printed at the time in one of the Oxford papers. He is there wrongly stated to have said, "It is putting new arms into the hands of the infidel."'



Chapter 4.

Points of Character.

A point highly illustrative of the character of Faraday now comes into view. He gave an account of his discovery of Magneto-electricity in a letter to his friend M. Hachette, of Paris, who communicated the letter to the Academy of Sciences. The letter was translated and published; and immediately afterwards two distinguished Italian philosophers took up the subject, made numerous experiments, and published their results before the complete memoirs of Faraday had met the public eye. This evidently irritated him. He reprinted the paper of the learned Italians in the 'Philosophical Magazine,' accompanied by sharp critical notes from himself. He also wrote a letter dated Dec. 1, 1832, to Gay Lussac, who was then one of the editors of the 'Annales de Chimie,' in which he analysed the results of the Italian philosophers, pointing out their errors, and defending himself from what he regarded as imputations on his character. The style of this letter is unexceptionable, for Faraday could not write otherwise than as a gentleman; but the letter shows that had he willed it he could have hit hard. We have heard much of Faraday's gentleness and sweetness and tenderness. It is all true, but it is very incomplete. You cannot resolve a powerful nature into these elements, and Faraday's character would have been less admirable than it was had it not embraced forces and tendencies to which the silky adjectives 'gentle' and 'tender' would by no means apply. Underneath his sweetness and gentleness was the heat of a volcano. He was a man of excitable and fiery nature; but through high self-discipline he had converted the fire into a central glow and motive power of life, instead of permitting it to waste itself in useless passion. 'He that is slow to anger,' saith the sage, 'is greater than the mighty, and he that ruleth his own spirit than he that taketh a city.' Faraday was not slow to anger, but he completely ruled his own spirit, and thus, though he took no cities, he captivated all hearts.

As already intimated, Faraday had contributed many of his minor papers—including his first analysis of caustic lime—to the 'Quarterly Journal of Science.' In 1832, he collected those papers and others together in a small octavo volume, labelled them, and prefaced them thus:—

'PAPERS, NOTES, NOTICES, &c., &c.,published in octavo, up to 1832. M. Faraday.'

'Papers of mine, published in octavo, in the "Quarterly Journal of Science," and elsewhere, since the time that Sir H. Davy encouraged me to write the analysis of caustic lime.

'Some, I think (at this date), are good; others moderate; and some bad. But I have put all into the volume, because of the utility they have been of to me—and none more than the bad—in pointing out to me in future, or rather, after times, the faults it became me to watch and to avoid.

'As I never looked over one of my papers a year after it was written without believing both in philosophy and manner it could have been much better done, I still hope the collection may be of great use to me.

'M. Faraday.

'Aug. 18, 1832.'

'None more than the bad!' This is a bit of Faraday's innermost nature; and as I read these words I am almost constrained to retract what I have said regarding the fire and excitability of his character. But is he not all the more admirable, through his ability to tone down and subdue that fire and that excitability, so as to render himself able to write thus as a little child? I once took the liberty of censuring the conclusion of a letter of his to the Dean of St. Paul's. He subscribed himself 'humbly yours,' and I objected to the adverb. 'Well, but, Tyndall,' he said, 'I am humble; and still it would be a great mistake to think that I am not also proud.' This duality ran through his character. A democrat in his defiance of all authority which unfairly limited his freedom of thought, and still ready to stoop in reverence to all that was really worthy of reverence, in the customs of the world or the characters of men.

And here, as well as elsewhere, may be introduced a letter which bears upon this question of self-control, written long years subsequent to the period at which we have now arrived. I had been at Glasgow in 1855, at a meeting of the British Association. On a certain day, I communicated a paper to the physical section, which was followed by a brisk discussion. Men of great distinction took part in it, the late Dr. Whewell among the number, and it waxed warm on both sides. I was by no means content with this discussion; and least of all, with my own part in it. This discontent affected me for some days, during which I wrote to Faraday, giving him no details, but expressing, in a general way, my dissatisfaction. I give the following extract from his reply:—

'Sydenham, Oct. 6, 1855.

'My Dear Tyndall,—These great meetings, of which I think very well altogether, advance science chiefly by bringing scientific men together and making them to know and be friends with each other; and I am sorry when that is not the effect in every part of their course. I know nothing except from what you tell me, for I have not yet looked at the reports of the proceedings; but let me, as an old man, who ought by this time to have profited by experience, say that when I was younger I found I often misinterpreted the intentions of people, and found they did not mean what at the time I supposed they meant; and, further, that as a general rule, it was better to be a little dull of apprehension where phrases seemed to imply pique, and quick in perception when, on the contrary, they seemed to imply kindly feeling. The real truth never fails ultimately to appear; and opposing parties, if wrong, are sooner convinced when replied to forbearingly, than when overwhelmed. All I mean to say is, that it is better to be blind to the results of partisanship, and quick to see good will. One has more happiness in oneself in endeavouring to follow the things that make for peace. You can hardly imagine how often I have been heated in private when opposed, as I have thought, unjustly and superciliously, and yet I have striven, and succeeded, I hope, in keeping down replies of the like kind. And I know I have never lost by it. I would not say all this to you did I not esteem you as a true philosopher and friend.[1]

'Yours, very truly,

'M. Faraday.'

Footnote to Chapter 4

[1] Faraday would have been rejoiced to learn that, during its last meeting at Dundee, the British Association illustrated in a striking manner the function which he here describes as its principal one. In my own case, a brotherly welcome was everywhere manifested. In fact, the differences of really honourable and sane men are never beyond healing.



Chapter 5.

Identity of electricities; first researches on electro-chemistry.

I have already once used the word 'discomfort' in reference to the occasional state of Faraday's mind when experimenting. It was to him a discomfort to reason upon data which admitted of doubt. He hated what he called 'doubtful knowledge,' and ever tended either to transfer it into the region of undoubtful knowledge, or of certain and definite ignorance. Pretence of all kinds, whether in life or in philosophy, was hateful to him. He wished to know the reality of our nescience as well as of our science. 'Be one thing or the other,' he seemed to say to an unproved hypothesis; 'come out as a solid truth, or disappear as a convicted lie.' After making the great discovery which I have attempted to describe, a doubt seemed to beset him as regards the identity of electricities. 'Is it right,' he seemed to ask, 'to call this agency which I have discovered electricity at all? Are there perfectly conclusive grounds for believing that the electricity of the machine, the pile, the gymnotus and torpedo, magneto-electricity and thermo-electricity, are merely different manifestations of one and the same agent?' To answer this question to his own satisfaction he formally reviewed the knowledge of that day. He added to it new experiments of his own, and finally decided in favour of the 'Identity of Electricities.' His paper upon this subject was read before the Royal Society on January 10 and 17, 1833.

After he had proved to his own satisfaction the identity of electricities, he tried to compare them quantitatively together. The terms quantity and intensity, which Faraday constantly used, need a word of explanation here. He might charge a single Leyden jar by twenty turns of his machine, or he might charge a battery of ten jars by the same number of turns. The quantity in both cases would be sensibly the same, but the intensity of the single jar would be the greatest, for here the electricity would be less diffused. Faraday first satisfied himself that the needle of his galvanometer was caused to swing through the same arc by the same quantity of machine electricity, whether it was condensed in a small battery or diffused over a large one. Thus the electricity developed by thirty turns of his machine produced, under very variable conditions of battery surface, the same deflection. Hence he inferred the possibility of comparing, as regards quantity, electricities which differ greatly from each other in intensity. His object now is to compare frictional with voltaic electricity. Moistening bibulous paper with the iodide of potassium—a favourite test of his—and subjecting it to the action of machine electricity, he decomposed the iodide, and formed a brown spot where the iodine was liberated. Then he immersed two wires, one of zinc, the other of platinum, each 1/13th of an inch in diameter, to a depth of 5/8ths of an inch in acidulated water during eight beats of his watch, or 3/20ths of a second; and found that the needle of his galvanometer swung through the same arc, and coloured his moistened paper to the same extent, as thirty turns of his large electrical machine. Twenty-eight turns of the machine produced an effect distinctly less than that produced by his two wires. Now, the quantity of water decomposed by the wires in this experiment totally eluded observation; it was immeasurably small; and still that amount of decomposition involved the development of a quantity of electric force which, if applied in a proper form, would kill a rat, and no man would like to bear it.

In his subsequent researches 'On the absolute Quantity of Electricity associated with the Particles or Atoms of matter,' he endeavours to give an idea of the amount of electrical force involved in the decomposition of a single grain of water. He is almost afraid to mention it, for he estimates it at 800,000 discharges of his large Leyden battery. This, if concentrated in a single discharge, would be equal to a very great flash of lightning; while the chemical action of a single grain of water on four grains of zinc would yield electricity equal in quantity to a powerful thunderstorm. Thus his mind rises from the minute to the vast, expanding involuntarily from the smallest laboratory fact till it embraces the largest and grandest natural phenomena.[1]

In reality, however, he is at this time only clearing his way, and he continues laboriously to clear it for some time afterwards. He is digging the shaft, guided by that instinct towards the mineral lode which was to him a rod of divination. 'Er riecht die Wahrheit,' said the lamented Kohlrausch, an eminent German, once in my hearing:—'He smells the truth.' His eyes are now steadily fixed on this wonderful voltaic current, and he must learn more of its mode of transmission.

On May 23, 1833, he read a paper before the Royal Society 'On a new Law of Electric Conduction.' He found that, though the current passed through water, it did not pass through ice:—why not, since they are one and the same substance? Some years subsequently he answered this question by saying that the liquid condition enables the molecule of water to turn round so as to place itself in the proper line of polarization, while the rigidity of the solid condition prevents this arrangement. This polar arrangement must precede decomposition, and decomposition is an accompaniment of conduction. He then passed on to other substances; to oxides and chlorides, and iodides, and salts, and sulphurets, and found them all insulators when solid, and conductors when fused. In all cases, moreover, except one—and this exception he thought might be apparent only—he found the passage of the current across the fused compound to be accompanied by its decomposition. Is then the act of decomposition essential to the act of conduction in these bodies? Even recently this question was warmly contested. Faraday was very cautious latterly in expressing himself upon this subject; but as a matter of fact he held that an infinitesimal quantity of electricity might pass through a compound liquid without producing its decomposition. De la Rive, who has been a great worker on the chemical phenomena of the pile, is very emphatic on the other side. Experiment, according to him and others, establishes in the most conclusive manner that no trace of electricity can pass through a liquid compound without producing its equivalent decomposition.[2]

Faraday has now got fairly entangled amid the chemical phenomena of the pile, and here his previous training under Davy must have been of the most important service to him. Why, he asks, should decomposition thus take place?—what force is it that wrenches the locked constituents of these compounds asunder? On the 20th of June, 1833, he read a paper before the Royal Society 'On Electro-chemical Decomposition,' in which he seeks to answer these questions. The notion had been entertained that the poles, as they are called, of the decomposing cell, or in other words the surfaces by which the current enters and quits the liquid, exercised electric attractions upon the constituents of the liquid and tore them asunder. Faraday combats this notion with extreme vigour. Litmus reveals, as you know, the action of an acid by turning red, turmeric reveals the action of an alkali by turning brown. Sulphate of soda, you know, is a salt compounded of the alkali soda and sulphuric acid. The voltaic current passing through a solution of this salt so decomposes it, that sulphuric acid appears at one pole of the decomposing cell and alkali at the other. Faraday steeped a piece of litmus paper and a piece of turmeric paper in a solution of sulphate of soda: placing each of them upon a separate plate of glass, he connected them together by means of a string moistened with the same solution. He then attached one of them to the positive conductor of an electric machine, and the other to the gas-pipes of this building. These he called his 'discharging train.' On turning the machine the electricity passed from paper to paper through the string, which might be varied in length from a few inches to seventy feet without changing the result. The first paper was reddened, declaring the presence of sulphuric acid; the second was browned, declaring the presence of the alkali soda. The dissolved salt, therefore, arranged in this fashion, was decomposed by the machine, exactly as it would have been by the voltaic current. When instead of using the positive conductor he used the negative, the positions of the acid and alkali were reversed. Thus he satisfied himself that chemical decomposition by the machine is obedient to the laws which rule decomposition by the pile.

And now he gradually abolishes those so-called poles, to the attraction of which electric decomposition had been ascribed. He connected a piece of turmeric paper moistened with the sulphate of soda with the positive conductor of his machine; then he placed a metallic point in connection with his discharging train opposite the moist paper, so that the electricity should discharge through the air towards the point. The turning of the machine caused the corners of the piece of turmeric paper opposite to the point to turn brown, thus declaring the presence of alkali. He changed the turmeric for litmus paper, and placed it, not in connection with his conductor, but with his discharging train, a metallic point connected with the conductor being fixed at a couple of inches from the paper; on turning the machine, acid was liberated at the edges and corners of the litmus. He then placed a series of pointed pieces of paper, each separate piece being composed of two halves, one of litmus and the other of turmeric paper, and all moistened with sulphate of soda, in the line of the current from the machine. The pieces of paper were separated from each other by spaces of air. The machine was turned; and it was always found that at the point where the electricity entered the paper, litmus was reddened, and at the point where it quitted the paper, turmeric was browned. 'Here,' he urges, 'the poles are entirely abandoned, but we have still electrochemical decomposition.' It is evident to him that instead of being attracted by the poles, the bodies separated are ejected by the current. The effects thus obtained with poles of air he also succeeded in obtaining with poles of water. The advance in Faraday's own ideas made at this time is indicated by the word 'ejected.' He afterwards reiterates this view: the evolved substances are expelled from the decomposing body, and 'not drawn out by an attraction.

Having abolished this idea of polar attraction, he proceeds to enunciate and develop a theory of his own. He refers to Davy's celebrated Bakerian Lecture, given in 1806, which he says 'is almost entirely occupied in the consideration of electrochemical decompositions.' The facts recorded in that lecture Faraday regards as of the utmost value. But 'the mode of action by which the effects take place is stated very generally; so generally, indeed, that probably a dozen precise schemes of electrochemical action might be drawn up, differing essentially from each other, yet all agreeing with the statement there given.'

It appears to me that these words might with justice be applied to Faraday's own researches at this time. They furnish us with results of permanent value; but little help can be found in the theory advanced to account for them. It would, perhaps, be more correct to say that the theory itself is hardly presentable in any tangible form to the intellect. Faraday looks, and rightly looks, into the heart of the decomposing body itself; he sees, and rightly sees, active within it the forces which produce the decomposition, and he rejects, and rightly rejects, the notion of external attraction; but beyond the hypothesis of decompositions and recompositions, enunciated and developed by Grothuss and Davy, he does not, I think, help us to any definite conception as to how the force reaches the decomposing mass and acts within it. Nor, indeed, can this be done, until we know the true physical process which underlies what we call an electric current.

Faraday conceives of that current as 'an axis of power having contrary forces exactly equal in amount in opposite directions'; but this definition, though much quoted and circulated, teaches us nothing regarding the current. An 'axis' here can only mean a direction; and what we want to be able to conceive of is, not the axis along which the power acts, but the nature and mode of action of the power itself. He objects to the vagueness of De la Rive; but the fact is, that both he and De la Rive labour under the same difficulty. Neither wishes to commit himself to the notion of a current compounded of two electricities flowing in two opposite directions: but the time had not come, nor is it yet come, for the displacement of this provisional fiction by the true mechanical conception. Still, however indistinct the theoretic notions of Faraday at this time may be, the facts which are rising before him and around him are leading him gradually, but surely, to results of incalculable importance in relation to the philosophy of the voltaic pile.

He had always some great object of research in view, but in the pursuit of it he frequently alighted on facts of collateral interest, to examine which he sometimes turned aside from his direct course. Thus we find the series of his researches on electrochemical decomposition interrupted by an inquiry into 'the power of metals and other solids, to induce the combination of gaseous bodies.' This inquiry, which was received by the Royal Society on Nov. 30, 1833, though not so important as those which precede and follow it, illustrates throughout his strength as an experimenter. The power of spongy platinum to cause the combination of oxygen and hydrogen had been discovered by Dobereiner in 1823, and had been applied by him in the construction of his well-known philosophic lamp. It was shown subsequently by Dulong and Thenard that even a platinum wire, when perfectly cleansed, may be raised to incandescence by its action on a jet of cold hydrogen.

In his experiments on the decomposition of water, Faraday found that the positive platinum plate of the decomposing cell possessed in an extraordinary degree the power of causing oxygen and hydrogen to combine. He traced the cause of this to the perfect cleanness of the positive plate. Against it was liberated oxygen, which, with the powerful affinity of the 'nascent state,' swept away all impurity from the surface against which it was liberated. The bubbles of gas liberated on one of the platinum plates or wires of a decomposing cell are always much smaller, and they rise in much more rapid succession than those from the other. Knowing that oxygen is sixteen times heavier than hydrogen, I have more than once concluded, and, I fear, led others into the error of concluding, that the smaller and more quickly rising bubbles must belong to the lighter gas. The thing appeared so obvious that I did not give myself the trouble of looking at the battery, which would at once have told me the nature of the gas. But Faraday would never have been satisfied with a deduction if he could have reduced it to a fact. And he has taught me that the fact here is the direct reverse of what I supposed it to be. The small bubbles are oxygen, and their smallness is due to the perfect cleanness of the surface on which they are liberated. The hydrogen adhering to the other electrode swells into large bubbles, which rise in much slower succession; but when the current is reversed, the hydrogen is liberated upon the cleansed wire, and then its bubbles also become small.

Footnotes to Chapter 5

[1] Buff finds the quantity of electricity associated with one milligramme of hydrogen in water to be equal to 45,480 charges of a Leyden jar, with a height of 480 millimetres, and a diameter of 160 millimetres. Weber and Kohlrausch have calculated that, if the quantity of electricity associated with one milligramme of hydrogen in water were diffused over a cloud at a height of 1000 metres above the earth, it would exert upon an equal quantity of the opposite electricity at the earth's surface an attractive force of 2,268,000 kilogrammes. (Electrolytische Maasbestimmungen, 1856, p. 262.)

[2] Faraday, sa Vie et ses Travaux, p. 20.



Chapter 6.

Laws of electro-chemical decomposition.

In our conceptions and reasonings regarding the forces of nature, we perpetually make use of symbols which, when they possess a high representative value, we dignify with the name of theories. Thus, prompted by certain analogies, we ascribe electrical phenomena to the action of a peculiar fluid, sometimes flowing, sometimes at rest. Such conceptions have their advantages and their disadvantages; they afford peaceful lodging to the intellect for a time, but they also circumscribe it, and by-and-by, when the mind has grown too large for its lodging, it often finds difficulty in breaking down the walls of what has become its prison instead of its home.[1]

No man ever felt this tyranny of symbols more deeply than Faraday, and no man was ever more assiduous than he to liberate himself from them, and the terms which suggested them. Calling Dr. Whewell to his aid in 1833, he endeavoured to displace by others all terms tainted by a foregone conclusion. His paper on Electro-chemical Decomposition, received by the Royal Society on January 9, 1834, opens with the proposal of a new terminology. He would avoid the word 'current' if he could.[2] He does abandon the word 'poles' as applied to the ends of a decomposing cell, because it suggests the idea of attraction, substituting for it the perfectly natural term Electrodes. He applied the term Electrolyte to every substance which can be decomposed by the current, and the act of decomposition he called Electrolysis. All these terms have become current in science. He called the positive electrode the Anode, and the negative one the Cathode, but these terms, though frequently used, have not enjoyed the same currency as the others. The terms Anion and Cation, which he applied to the constituents of the decomposed electrolyte, and the term Ion, which included both anions and cations, are still less frequently employed.

Faraday now passes from terminology to research; he sees the necessity of quantitative determinations, and seeks to supply himself with a measure of voltaic electricity. This he finds in the quantity of water decomposed by the current. He tests this measure in all possible ways, to assure himself that no error can arise from its employment. He places in the course of one and the same current a series of cells with electrodes of different sizes, some of them plates of platinum, others merely platinum wires, and collects the gas liberated on each distinct pair of electrodes. He finds the quantity of gas to be the same for all. Thus he concludes that when the same quantity of electricity is caused to pass through a series of cells containing acidulated water, the electro-chemical action is independent of the size of the electrodes.[3] He next proves that variations in intensity do not interfere with this equality of action. Whether his battery is charged with strong acid or with weak; whether it consists of five pairs or of fifty pairs; in short, whatever be its source, when the same current is sent through his series of cells the same amount of decomposition takes place in all. He next assures himself that the strength or weakness of his dilute acid does not interfere with this law. Sending the same current through a series of cells containing mixtures of sulphuric acid and water of different strengths, he finds, however the proportion of acid to water might vary, the same amount of gas to be collected in all the cells. A crowd of facts of this character forced upon Faraday's mind the conclusion that the amount of electro-chemical decomposition depends, not upon the size of the electrodes, not upon the intensity of the current, not upon the strength of the solution, but solely upon the quantity of electricity which passes through the cell. The quantity of electricity he concludes is proportional to the amount of chemical action. On this law Faraday based the construction of his celebrated Voltameter, or Measure of Voltaic electricity.

But before he can apply this measure he must clear his ground of numerous possible sources of error. The decomposition of his acidulated water is certainly a direct result of the current; but as the varied and important researches of MM. Becquerel, De la Rive, and others had shown, there are also secondary actions which may materially interfere with and complicate the pure action of the current. These actions may occur in two ways: either the liberated ion may seize upon the electrode against which it is set free, forming a chemical compound with that electrode; or it may seize upon the substance of the electrolyte itself, and thus introduce into the circuit chemical actions over and above those due to the current. Faraday subjected these secondary actions to an exhaustive examination. Instructed by his experiments, and rendered competent by them to distinguish between primary and secondary results, he proceeds to establish the doctrine of 'Definite Electro-chemical Decomposition.'

Into the same circuit he introduced his voltameter, which consisted of a graduated tube filled with acidulated water and provided with platinum plates for the decomposition of the water, and also a cell containing chloride of tin. Experiments already referred to had taught him that this substance, though an insulator when solid, is a conductor when fused, the passage of the current being always accompanied by the decomposition of the chloride. He wished to ascertain what relation this decomposition bore to that of the water in his voltameter.

Completing his circuit, he permitted the current to continue until 'a reasonable quantity of gas' was collected in the voltameter. The circuit was then broken, and the quantity of tin liberated compared with the quantity of gas. The weight of the former was 3.2 grains, that of the latter 0.49742 of a grain. Oxygen, as you know, unites with hydrogen in the proportion of 8 to 1, to form water. Calling the equivalent, or as it is sometimes called, the atomic weight of hydrogen 1, that of oxygen is 8; that of water is consequently 8 + 1 or 9. Now if the quantity of water decomposed in Faraday's experiment be represented by the number 9, or in other words by the equivalent of water, then the quantity of tin liberated from the fused chloride is found by an easy calculation to be 57.9, which is almost exactly the chemical equivalent of tin. Thus both the water and the chloride were broken up in proportions expressed by their respective equivalents. The amount of electric force which wrenched asunder the constituents of the molecule of water was competent, and neither more nor less than competent, to wrench asunder the constituents of the molecules of the chloride of tin. The fact is typical. With the indications of his voltameter he compared the decompositions of other substances, both singly and in series. He submitted his conclusions to numberless tests. He purposely introduced secondary actions. He endeavoured to hamper the fulfilment of those laws which it was the intense desire of his mind to see established. But from all these difficulties emerged the golden truth, that under every variety of circumstances the decompositions of the voltaic current are as definite in their character as those chemical combinations which gave birth to the atomic theory. This law of Electro-chemical Decomposition ranks, in point of importance, with that of Definite Combining Proportions in chemistry.

Footnotes to Chapter 6

[1] I copy these words from the printed abstract of a Friday evening lecture, given by myself, because they remind me of Faraday's voice, responding to the utterance by an emphatic 'hear! hear!'—Proceedings of the Royal Institution, vol. ii. p. 132.

[2] In 1838 he expresses himself thus:—'The word current is so expressive in common language that when applied in the consideration of electrical phenomena, we can hardly divest it sufficiently of its meaning, or prevent our minds from being prejudiced by it.'—Exp. Resear., vol. i. p. 515. ($ 1617.)

[3] This conclusion needs qualification. Faraday overlooked the part played by ozone.



Chapter 7.

Origin of power in the voltaic pile.

In one of the public areas of the town of Como stands a statue with no inscription on its pedestal, save that of a single name, 'Volta.' The bearer of that name occupies a place for ever memorable in the history of science. To him we owe the discovery of the voltaic pile, to which for a brief interval we must now turn our attention.

The objects of scientific thought being the passionless laws and phenomena of external nature, one might suppose that their investigation and discussion would be completely withdrawn from the region of the feelings, and pursued by the cold dry light of the intellect alone. This, however, is not always the case. Man carries his heart with him into all his works. You cannot separate the moral and emotional from the intellectual; and thus it is that the discussion of a point of science may rise to the heat of a battle-field. The fight between the rival optical theories of Emission and Undulation was of this fierce character; and scarcely less fierce for many years was the contest as to the origin and maintenance of the power of the voltaic pile. Volta himself supposed it to reside in the Contact of different metals. Here was exerted his 'Electro-motive force,' which tore the combined electricities asunder and drove them as currents in opposite directions. To render the circulation of the current possible, it was necessary to connect the metals by a moist conductor; for when any two metals were connected by a third, their relation to each other was such that a complete neutralisation of the electric motion was the result. Volta's theory of metallic contact was so clear, so beautiful, and apparently so complete, that the best intellects of Europe accepted it as the expression of natural law.

Volta himself knew nothing of the chemical phenomena of the pile; but as soon as these became known, suggestions and intimations appeared that chemical action, and not metallic contact, might be the real source of voltaic electricity. This idea was expressed by Fabroni in Italy, and by Wollaston in England. It was developed and maintained by those 'admirable electricians,' Becquerel, of Paris, and De la Rive, of Geneva. The Contact Theory, on the other hand, received its chief development and illustration in Germany. It was long the scientific creed of the great chemists and natural philosophers of that country, and to the present hour there may be some of them unable to liberate themselves from the fascination of their first-love.

After the researches which I have endeavoured to place before you, it was impossible for Faraday to avoid taking a side in this controversy. He did so in a paper 'On the Electricity of the Voltaic Pile,' received by the Royal Society on the 7th of April, 1834. His position in the controversy might have been predicted. He saw chemical effects going hand in hand with electrical effects, the one being proportional to the other; and, in the paper now before us, he proved that when the former was excluded, the latter were sought for in vain. He produced a current without metallic contact; he discovered liquids which, though competent to transmit the feeblest currents—competent therefore to allow the electricity of contact to flow through them if it were able to form a current—were absolutely powerless when chemically inactive.

One of the very few experimental mistakes of Faraday occurred in this investigation. He thought that with a single voltaic cell he had obtained the spark before the metals touched, but he subsequently discovered his error. To enable the voltaic spark to pass through air before the terminals of the battery were united, it was necessary to exalt the electro-motive force of the battery by multiplying its elements; but all the elements Faraday possessed were unequal to the task of urging the spark across the shortest measurable space of air. Nor, indeed, could the action of the battery, the different metals of which were in contact with each other, decide the point in question. Still, as regards the identity of electricities from various sources, it was at that day of great importance to determine whether or not the voltaic current could jump, as a spark, across an interval before contact. Faraday's friend, Mr. Gassiot, solved this problem. He erected a battery of 4000 cells, and with it urged a stream of sparks from terminal to terminal, when separated from each other by a measurable space of air.

The memoir on the 'Electricity of the Voltaic Pile,' published in 1834, appears to have produced but little impression upon the supporters of the contact theory. These indeed were men of too great intellectual weight and insight lightly to take up, or lightly to abandon a theory. Faraday therefore resumed the attack in a paper, communicated to the Royal Society on the 6th of February, 1840. In this paper he hampered his antagonists by a crowd of adverse experiments. He hung difficulty after difficulty about the neck of the contact theory, until in its efforts to escape from his assaults it so changed its character as to become a thing totally different from the theory proposed by Volta. The more persistently it was defended, however, the more clearly did it show itself to be a congeries of devices, bearing the stamp of dialectic skill rather than of natural truth.

In conclusion, Faraday brought to bear upon it an argument which, had its full weight and purport been understood at the time, would have instantly decided the controversy. 'The contact theory,' he urged, 'assumed that a force which is able to overcome powerful resistance, as for instance that of the conductors, good or bad, through which the current passes, and that again of the electrolytic action where bodies are decomposed by it, can arise out of nothing; that, without any change in the acting matter, or the consumption of any generating force, a current shall be produced which shall go on for ever against a constant resistance, or only be stopped, as in the voltaic trough, by the ruins which its exertion has heaped up in its own course. This would indeed be a creation of power, and is like no other force in nature. We have many processes by which the form of the power may be so changed, that an apparent conversion of one into the other takes place. So we can change chemical force into the electric current, or the current into chemical force. The beautiful experiments of Seebeck and Peltier show the convertibility of heat and electricity; and others by Oersted and myself show the convertibility of electricity and magnetism. But in no case, not even in those of the Gymnotus and Torpedo, is there a pure creation or a production of power without a corresponding exhaustion of something to supply it.'

These words were published more than two years before either Mayer printed his brief but celebrated essay on the Forces of Inorganic Nature, or Mr. Joule published his first famous experiments on the Mechanical Value of Heat. They illustrate the fact that before any great scientific principle receives distinct enunciation by individuals, it dwells more or less clearly in the general scientific mind. The intellectual plateau is already high, and our discoverers are those who, like peaks above the plateau, rise a little above the general level of thought at the time.

But many years prior even to the foregoing utterance of Faraday, a similar argument had been employed. I quote here with equal pleasure and admiration the following passage written by Dr. Roget so far back as 1829. Speaking of the contact theory, he says:—'If there could exist a power having the property ascribed to it by the hypothesis, namely, that of giving continual impulse to a fluid in one constant direction, without being exhausted by its own action, it would differ essentially from all the known powers in nature. All the powers and sources of motion with the operation of which we are acquainted, when producing these peculiar effects, are expended in the same proportion as those effects are produced; and hence arises the impossibility of obtaining by their agency a perpetual effect; or in other words a perpetual motion. But the electro-motive force, ascribed by Volta to the metals, when in contact, is a force which, as long as a free course is allowed to the electricity it sets in motion, is never expended, and continues to be excited with undiminished power in the production of a never-ceasing effect. Against the truth of such a supposition the probabilities are all but infinite.' When this argument, which he employed independently, had clearly fixed itself in his mind, Faraday never cared to experiment further on the source of electricity in the voltaic pile. The argument appeared to him 'to remove the foundation itself of the contact theory,' and he afterwards let it crumble down in peace.[1]

Footnote to Chapter 7

[1] To account for the electric current, which was really the core of the whole discussion, Faraday demonstrated the impotence of the Contact Theory as then enunciated and defended. Still, it is certain that two different metals, when brought into contact, charge themselves, the one with positive and the other with negative electricity. I had the pleasure of going over this ground with Kohlrausch in 1849, and his experiments left no doubt upon my mind that the contact electricity of Volta was a reality, though it could produce no current. With one of the beautiful instruments devised by himself, Sir William Thomson has rendered this point capable of sure and easy demonstration; and he and others now hold what may be called a contact theory, which, while it takes into account the action of the metals, also embraces the chemical phenomena of the circuit. Helmholtz, I believe, was the first to give the contact theory this new form, in his celebrated essay, Ueber die Erhaltung der Kraft, p. 45.



Chapter 8.

Researches on frictional electricity: induction: conduction: specific inductive capacity: theory of contiguous particles.

The burst of power which had filled the four preceding years with an amount of experimental work unparalleled in the history of science partially subsided in 1835, and the only scientific paper contributed by Faraday in that year was a comparatively unimportant one, 'On an improved Form of the Voltaic Battery.' He brooded for a time: his experiments on electrolysis had long filled his mind; he looked, as already stated, into the very heart of the electrolyte, endeavouring to render the play of its atoms visible to his mental eye. He had no doubt that in this case what is called 'the electric current' was propagated from particle to particle of the electrolyte; he accepted the doctrine of decomposition and recomposition which, according to Grothuss and Davy, ran from electrode to electrode. And the thought impressed him more and more that ordinary electric induction was also transmitted and sustained by the action of 'contiguous particles.'

His first great paper on frictional electricity was sent to the Royal Society on November 30, 1837. We here find him face to face with an idea which beset his mind throughout his whole subsequent life,—the idea of action at a distance. It perplexed and bewildered him. In his attempts to get rid of this perplexity, he was often unconsciously rebelling against the limitations of the intellect itself. He loved to quote Newton upon this point; over and over again he introduces his memorable words, 'That gravity should be innate, inherent, and essential to matter, so that one body may act upon another at a distance through a vacuum and without the mediation of anything else, by and through which this action and force may be conveyed from one to another, is to me so great an absurdity, that I believe no man who has in philosophical matters a competent faculty of thinking, can ever fall into it. Gravity must be caused by an agent acting constantly according to certain laws; but whether this agent be material or immaterial, I have left to the consideration of my readers.'[1]