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A History of Science, Volume 3(of 5)
by Henry Smith Williams
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This doctrine of interference of undulations was the absolutely novel part of Young's theory. The all-compassing genius of Robert Hooke had, indeed, very nearly apprehended it more than a century before, as Young himself points out, but no one else bad so much as vaguely conceived it; and even with the sagacious Hooke it was only a happy guess, never distinctly outlined in his own mind, and utterly ignored by all others. Young did not know of Hooke's guess until he himself had fully formulated the theory, but he hastened then to give his predecessor all the credit that could possibly be adjudged his due by the most disinterested observer. To Hooke's contemporary, Huygens, who was the originator of the general doctrine of undulation as the explanation of light, Young renders full justice also. For himself he claims only the merit of having demonstrated the theory which these and a few others of his predecessors had advocated without full proof.

The following year Dr. Young detailed before the Royal Society other experiments, which threw additional light on the doctrine of interference; and in 1803 he cited still others, which, he affirmed, brought the doctrine to complete demonstration. In applying this demonstration to the general theory of light, he made the striking suggestion that "the luminiferous ether pervades the substance of all material bodies with little or no resistance, as freely, perhaps, as the wind passes through a grove of trees." He asserted his belief also that the chemical rays which Ritter had discovered beyond the violet end of the visible spectrum are but still more rapid undulations of the same character as those which produce light. In his earlier lecture he had affirmed a like affinity between the light rays and the rays of radiant heat which Herschel detected below the red end of the spectrum, suggesting that "light differs from heat only in the frequency of its undulations or vibrations—those undulations which are within certain limits with respect to frequency affecting the optic nerve and constituting light, and those which are slower and probably stronger constituting heat only." From the very outset he had recognized the affinity between sound and light; indeed, it had been this affinity that led him on to an appreciation of the undulatory theory of light.

But while all these affinities seemed so clear to the great co-ordinating brain of Young, they made no such impression on the minds of his contemporaries. The immateriality of light had been substantially demonstrated, but practically no one save its author accepted the demonstration. Newton's doctrine of the emission of corpuscles was too firmly rooted to be readily dislodged, and Dr. Young had too many other interests to continue the assault unceasingly. He occasionally wrote something touching on his theory, mostly papers contributed to the Quarterly Review and similar periodicals, anonymously or under pseudonym, for he had conceived the notion that too great conspicuousness in fields outside of medicine would injure his practice as a physician. His views regarding light (including the original papers from the Philosophical Transactions of the Royal Society) were again given publicity in full in his celebrated volume on natural philosophy, consisting in part of his lectures before the Royal Institution, published in 1807; but even then they failed to bring conviction to the philosophic world. Indeed, they did not even arouse a controversial spirit, as his first papers had done.

ARAGO AND FRESNEL CHAMPION THE WAVE THEORY

So it chanced that when, in 1815, a young French military engineer, named Augustin Jean Fresnel, returning from the Napoleonic wars, became interested in the phenomena of light, and made some experiments concerning diffraction which seemed to him to controvert the accepted notions of the materiality of light, he was quite unaware that his experiments had been anticipated by a philosopher across the Channel. He communicated his experiments and results to the French Institute, supposing them to be absolutely novel. That body referred them to a committee, of which, as good fortune would have it, the dominating member was Dominique Francois Arago, a man as versatile as Young himself, and hardly less profound, if perhaps not quite so original. Arago at once recognized the merit of Fresnel's work, and soon became a convert to the theory. He told Fresnel that Young had anticipated him as regards the general theory, but that much remained to be done, and he offered to associate himself with Fresnel in prosecuting the investigation. Fresnel was not a little dashed to learn that his original ideas had been worked out by another while he was a lad, but he bowed gracefully to the situation and went ahead with unabated zeal.

The championship of Arago insured the undulatory theory a hearing before the French Institute, but by no means sufficed to bring about its general acceptance. On the contrary, a bitter feud ensued, in which Arago was opposed by the "Jupiter Olympus of the Academy," Laplace, by the only less famous Poisson, and by the younger but hardly less able Biot. So bitterly raged the feud that a life-long friendship between Arago and Biot was ruptured forever. The opposition managed to delay the publication of Fresnel's papers, but Arago continued to fight with his customary enthusiasm and pertinacity, and at last, in 1823, the Academy yielded, and voted Fresnel into its ranks, thus implicitly admitting the value of his work.

It is a humiliating thought that such controversies as this must mar the progress of scientific truth; but fortunately the story of the introduction of the undulatory theory has a more pleasant side. Three men, great both in character and in intellect, were concerned in pressing its claims—Young, Fresnel, and Arago—and the relations of these men form a picture unmarred by any of those petty jealousies that so often dim the lustre of great names. Fresnel freely acknowledged Young's priority so soon as his attention was called to it; and Young applauded the work of the Frenchman, and aided with his counsel in the application of the undulatory theory to the problems of polarization of light, which still demanded explanation, and which Fresnel's fertility of experimental resource and profundity of mathematical insight sufficed in the end to conquer.

After Fresnel's admission to the Institute in 1823 the opposition weakened, and gradually the philosophers came to realize the merits of a theory which Young had vainly called to their attention a full quarter-century before. Now, thanks largely to Arago, both Young and Fresnel received their full meed of appreciation. Fresnel was given the Rumford medal of the Royal Society of England in 1825, and chosen one of the foreign members of the society two years later, while Young in turn was elected one of the eight foreign members of the French Academy. As a fitting culmination of the chapter of felicities between the three friends, it fell to the lot of Young, as Foreign Secretary of the Royal Society, to notify Fresnel of the honors shown him by England's representative body of scientists; while Arago, as Perpetual Secretary of the French Institute, conveyed to Young in the same year the notification that he had been similarly honored by the savants of France.

A few months later Fresnel was dead, and Young survived him only two years. Both died prematurely, but their great work was done, and the world will remember always and link together these two names in connection with a theory which in its implications and importance ranks little below the theory of universal gravitation.



VII. THE MODERN DEVELOPMENT OF ELECTRICITY AND MAGNETISM

GALVANI AND VOLTA

The full importance of Young's studies of light might perhaps have gained earlier recognition had it not chanced that, at the time when they were made, the attention of the philosophic world was turned with the fixity and fascination of a hypnotic stare upon another field, which for a time brooked no rival. How could the old, familiar phenomenon, light, interest any one when the new agent, galvanism, was in view? As well ask one to fix attention on a star while a meteorite blazes across the sky.

Galvanism was so called precisely as the Roentgen ray was christened at a later day—as a safe means of begging the question as to the nature of the phenomena involved. The initial fact in galvanism was the discovery of Luigi Galvani (1737-1798), a physician of Bologna, in 1791, that by bringing metals in contact with the nerves of a frog's leg violent muscular contractions are produced. As this simple little experiment led eventually to the discovery of galvanic electricity and the invention of the galvanic battery, it may be regarded as the beginning of modern electricity.

The story is told that Galvani was led to his discovery while preparing frogs' legs to make a broth for his invalid wife. As the story runs, he had removed the skins from several frogs' legs, when, happening to touch the exposed muscles with a scalpel which had lain in close proximity to an electrical machine, violent muscular action was produced. Impressed with this phenomenon, he began a series of experiments which finally resulted in his great discovery. But be this story authentic or not, it is certain that Galvani experimented for several years upon frogs' legs suspended upon wires and hooks, until he finally constructed his arc of two different metals, which, when arranged so that one was placed in contact with a nerve and the other with a muscle, produced violent contractions.

These two pieces of metal form the basic principle of the modern galvanic battery, and led directly to Alessandro Volta's invention of his "voltaic pile," the immediate ancestor of the modern galvanic battery. Volta's experiments were carried on at the same time as those of Galvani, and his invention of his pile followed close upon Galvani's discovery of the new form of electricity. From these facts the new form of electricity was sometimes called "galvanic" and sometimes "voltaic" electricity, but in recent years the term "galvanism" and "galvanic current" have almost entirely supplanted the use of the term voltaic.

It was Volta who made the report of Galvani's wonderful discovery to the Royal Society of London, read on January 31, 1793. In this letter he describes Galvani's experiments in detail and refers to them in glowing terms of praise. He calls it one of the "most beautiful and important discoveries," and regarded it as the germ or foundation upon which other discoveries were to be made. The prediction proved entirely correct, Volta himself being the chief discoverer.

Working along lines suggested by Galvani's discovery, Volta constructed an apparatus made up of a number of disks of two different kinds of metal, such as tin and silver, arranged alternately, a piece of some moist, porous substance, like paper or felt, being interposed between each pair of disks. With this "pile," as it was called, electricity was generated, and by linking together several such piles an electric battery could be formed.

This invention took the world by storm. Nothing like the enthusiasm it created in the philosophic world had been known since the invention of the Leyden jar, more than half a century before. Within a few weeks after Volta's announcement, batteries made according to his plan were being experimented with in every important laboratory in Europe.

As the century closed, half the philosophic world was speculating as to whether "galvanic influence" were a new imponderable, or only a form of electricity; and the other half was eagerly seeking to discover what new marvels the battery might reveal. The least imaginative man could see that here was an invention that would be epoch-making, but the most visionary dreamer could not even vaguely adumbrate the real measure of its importance.

It was evident at once that almost any form of galvanic battery, despite imperfections, was a more satisfactory instrument for generating electricity than the frictional machine hitherto in use, the advantage lying in the fact that the current from the galvanic battery could be controlled practically at will, and that the apparatus itself was inexpensive and required comparatively little attention. These advantages were soon made apparent by the practical application of the electric current in several fields.

It will be recalled that despite the energetic endeavors of such philosophers as Watson, Franklin, Galvani, and many others, the field of practical application of electricity was very limited at the close of the eighteenth century. The lightning-rod had come into general use, to be sure, and its value as an invention can hardly be overestimated. But while it was the result of extensive electrical discoveries, and is a most practical instrument, it can hardly be called one that puts electricity to practical use, but simply acts as a means of warding off the evil effects of a natural manifestation of electricity. The invention, however, had all the effects of a mechanism which turned electricity to practical account. But with the advent of the new kind of electricity the age of practical application began.

DAVY AND ELECTRIC LIGHT

Volta's announcement of his pile was scarcely two months old when two Englishmen, Messrs. Nicholson and Carlisle, made the discovery that the current from the galvanic battery had a decided effect upon certain chemicals, among other things decomposing water into its elements, hydrogen and oxygen. On May 7, 1800, these investigators arranged the ends of two brass wires connected with the poles of a voltaic pile, composed of alternate silver and zinc plates, so that the current coming from the pile was discharged through a small quantity of "New River water." "A fine stream of minute bubbles immediately began to flow from the point of the lower wire in the tube which communicated with the silver," wrote Nicholson, "and the opposite point of the upper wire became tarnished, first deep orange and then black...." The product of gas during two hours and a half was two-thirtieths of a cubic inch. "It was then mixed with an equal quantity of common air," continues Nicholson, "and exploded by the application of a lighted waxen thread."

This demonstration was the beginning of the very important science of electro-chemistry.

The importance of this discovery was at once recognized by Sir Humphry Davy, who began experimenting immediately in this new field. He constructed a series of batteries in various combinations, with which he attacked the "fixed alkalies," the composition of which was then unknown. Very shortly he was able to decompose potash into bright metallic globules, resembling quicksilver. This new substance he named "potassium." Then in rapid succession the elementary substances sodium, calcium, strontium, and magnesium were isolated.

It was soon discovered, also, that the new electricity, like the old, possessed heating power under certain conditions, even to the fusing of pieces of wire. This observation was probably first made by Frommsdorff, but it was elaborated by Davy, who constructed a battery of two thousand cells with which he produced a bright light from points of carbon—the prototype of the modern arc lamp. He made this demonstration before the members of the Royal Institution in 1810. But the practical utility of such a light for illuminating purposes was still a thing of the future. The expense of constructing and maintaining such an elaborate battery, and the rapid internal destruction of its plates, together with the constant polarization, rendered its use in practical illumination out of the question. It was not until another method of generating electricity was discovered that Davy's demonstration could be turned to practical account.

In Davy's own account of his experiment he says:

"When pieces of charcoal about an inch long and one-sixth of an inch in diameter were brought near each other (within the thirtieth or fortieth of an inch), a bright spark was produced, and more than half the volume of the charcoal became ignited to whiteness; and, by withdrawing the points from each other, a constant discharge took place through the heated air, in a space equal to at least four inches, producing a most brilliant ascending arch of light, broad and conical in form in the middle. When any substance was introduced into this arch, it instantly became ignited; platina melted as readily in it as wax in a common candle; quartz, the sapphire, magnesia, lime, all entered into fusion; fragments of diamond and points of charcoal and plumbago seemed to evaporate in it, even when the connection was made in the receiver of an air-pump; but there was no evidence of their having previously undergone fusion. When the communication between the points positively and negatively electrified was made in the air rarefied in the receiver of the air-pump, the distance at which the discharge took place increased as the exhaustion was made; and when the atmosphere in the vessel supported only one-fourth of an inch of mercury in the barometrical gauge, the sparks passed through a space of nearly half an inch; and, by withdrawing the points from each other, the discharge was made through six or seven inches, producing a most brilliant coruscation of purple light; the charcoal became intensely ignited, and some platina wire attached to it fused with brilliant scintillations and fell in large globules upon the plate of the pump. All the phenomena of chemical decomposition were produced with intense rapidity by this combination."(1)

But this experiment demonstrated another thing besides the possibility of producing electric light and chemical decomposition, this being the heating power capable of being produced by the electric current. Thus Davy's experiment of fusing substances laid the foundation of the modern electric furnaces, which are of paramount importance in several great commercial industries.

While some of the results obtained with Davy's batteries were practically as satisfactory as could be obtained with modern cell batteries, the batteries themselves were anything but satisfactory. They were expensive, required constant care and attention, and, what was more important from an experimental standpoint at least, were not constant in their action except for a very limited period of time, the current soon "running down." Numerous experimenters, therefore, set about devising a satisfactory battery, and when, in 1836, John Frederick Daniell produced the cell that bears his name, his invention was epoch-making in the history of electrical progress. The Royal Society considered it of sufficient importance to bestow the Copley medal upon the inventor, whose device is the direct parent of all modern galvanic cells. From the time of the advent of the Daniell cell experiments in electricity were rendered comparatively easy. In the mean while, however, another great discovery was made.

ELECTRICITY AND MAGNETISM

For many years there had been a growing suspicion, amounting in many instances to belief in the close relationship existing between electricity and magnetism. Before the winter of 1815, however, it was a belief that was surmised but not demonstrated. But in that year it occurred to Jean Christian Oersted, of Denmark, to pass a current of electricity through a wire held parallel with, but not quite touching, a suspended magnetic needle. The needle was instantly deflected and swung out of its position.

"The first experiments in connection with the subject which I am undertaking to explain," wrote Oersted, "were made during the course of lectures which I held last winter on electricity and magnetism. From those experiments it appeared that the magnetic needle could be moved from its position by means of a galvanic battery—one with a closed galvanic circuit. Since, however, those experiments were made with an apparatus of small power, I undertook to repeat and increase them with a large galvanic battery.

"Let us suppose that the two opposite ends of the galvanic apparatus are joined by a metal wire. This I shall always call the conductor for the sake of brevity. Place a rectilinear piece of this conductor in a horizontal position over an ordinary magnetic needle so that it is parallel to it. The magnetic needle will be set in motion and will deviate towards the west under that part of the conductor which comes from the negative pole of the galvanic battery. If the wire is not more than four-fifths of an inch distant from the middle of this needle, this deviation will be about forty-five degrees. At a greater distance the angle of deviation becomes less. Moreover, the deviation varies according to the strength of the battery. The conductor can be moved towards the east or west, so long as it remains parallel to the needle, without producing any other result than to make the deviation smaller.

"The conductor can consist of several combined wires or metal coils. The nature of the metal does not alter the result except, perhaps, to make it greater or less. We have used wires of platinum, gold, silver, brass, and iron, and coils of lead, tin, and quicksilver with the same result. If the conductor is interrupted by water, all effect is not cut off, unless the stretch of water is several inches long.

"The conductor works on the magnetic needle through glass, metals, wood, water, and resin, through clay vessels and through stone, for when we placed a glass plate, a metal plate, or a board between the conductor and the needle the effect was not cut off; even the three together seemed hardly to weaken the effect, and the same was the case with an earthen vessel, even when it was full of water. Our experiments also demonstrated that the said effects were not altered when we used a magnetic needle which was in a brass case full of water.

"When the conductor is placed in a horizontal plane under the magnetic needle all the effects we have described take place in precisely the same way, but in the opposite direction to what took place when the conductor was in a horizontal plane above the needle.

"If the conductor is moved in a horizontal plane so that it gradually makes ever-increasing angles with the magnetic meridian, the deviation of the magnetic needle from the magnetic meridian is increased when the wire is turned towards the place of the needle; it decreases, on the other hand, when it is turned away from that place.

"A needle of brass which is hung in the same way as the magnetic needle is not set in motion by the influence of the conductor. A needle of glass or rubber likewise remains static under similar experiments. Hence the electrical conductor affects only the magnetic parts of a substance. That the electrical current is not confined to the conducting wire, but is comparatively widely diffused in the surrounding space, is sufficiently demonstrated from the foregoing observations."(2)

The effect of Oersted's demonstration is almost incomprehensible. By it was shown the close relationship between magnetism and electricity. It showed the way to the establishment of the science of electrodynamics; although it was by the French savant Andre Marie Ampere (1775-1836) that the science was actually created, and this within the space of one week after hearing of Oersted's experiment in deflecting the needle. Ampere first received the news of Oersted's experiment on September 11, 1820, and on the 18th of the same month he announced to the Academy the fundamental principles of the science of electro-dynamics—seven days of rapid progress perhaps unequalled in the history of science.

Ampere's distinguished countryman, Arago, a few months later, gave the finishing touches to Oersted's and Ampere's discoveries, by demonstrating conclusively that electricity not only influenced a magnet, but actually produced magnetism under proper circumstances—a complemental fact most essential in practical mechanics.

Some four years after Arago's discovery, Sturgeon made the first "electro-magnet" by winding a soft iron core with wire through which a current of electricity was passed. This study of electro-magnets was taken up by Professor Joseph Henry, of Albany, New York, who succeeded in making magnets of enormous lifting power by winding the iron core with several coils of wire. One of these magnets, excited by a single galvanic cell of less than half a square foot of surface, and containing only half a pint of dilute acids, sustained a weight of six hundred and fifty pounds.

Thus by Oersted's great discovery of the intimate relationship of magnetism and electricity, with further elaborations and discoveries by Ampere, Volta, and Henry, and with the invention of Daniell's cell, the way was laid for putting electricity to practical use. Soon followed the invention and perfection of the electro-magnetic telegraph and a host of other but little less important devices.

FARADAY AND ELECTRO-MAGNETIC INDUCTION

With these great discoveries and inventions at hand, electricity became no longer a toy or a "plaything for philosophers," but of enormous and growing importance commercially. Still, electricity generated by chemical action, even in a very perfect cell, was both feeble and expensive, and, withal, only applicable in a comparatively limited field. Another important scientific discovery was necessary before such things as electric traction and electric lighting on a large scale were to become possible; but that discovery was soon made by Sir Michael Faraday.

Faraday, the son of a blacksmith and a bookbinder by trade, had interested Sir Humphry Davy by his admirable notes on four of Davy's lectures, which he had been able to attend. Although advised by the great scientist to "stick to his bookbinding" rather than enter the field of science, Faraday became, at twenty-two years of age, Davy's assistant in the Royal Institution. There, for several years, he devoted all his spare hours to scientific investigations and experiments, perfecting himself in scientific technique.

A few years later he became interested, like all the scientists of the time, in Arago's experiment of rotating a copper disk underneath a suspended compass-needle. When this disk was rotated rapidly, the needle was deflected, or even rotated about its axis, in a manner quite inexplicable. Faraday at once conceived the idea that the cause of this rotation was due to electricity, induced in the revolving disk—not only conceived it, but put his belief in writing. For several years, however, he was unable to demonstrate the truth of his assumption, although he made repeated experiments to prove it. But in 1831 he began a series of experiments that established forever the fact of electro-magnetic induction.

In his famous paper, read before the Royal Society in 1831, Faraday describes the method by which he first demonstrated electro-magnetic induction, and then explained the phenomenon of Arago's revolving disk.

"About twenty-six feet of copper wire, one-twentieth of an inch in diameter, were wound round a cylinder of wood as a helix," he said, "the different spires of which were prevented from touching by a thin interposed twine. This helix was covered with calico, and then a second wire applied in the same manner. In this way twelve helices were "superposed, each containing an average length of wire of twenty-seven feet, and all in the same direction. The first, third, fifth, seventh, ninth, and eleventh of these helices were connected at their extremities end to end so as to form one helix; the others were connected in a similar manner; and thus two principal helices were produced, closely interposed, having the same direction, not touching anywhere, and each containing one hundred and fifty-five feet in length of wire.

One of these helices was connected with a galvanometer, the other with a voltaic battery of ten pairs of plates four inches square, with double coppers and well charged; yet not the slightest sensible deflection of the galvanometer needle could be observed.

"A similar compound helix, consisting of six lengths of copper and six of soft iron wire, was constructed. The resulting iron helix contained two hundred and eight feet; but whether the current from the trough was passed through the copper or the iron helix, no effect upon the other could be perceived at the galvanometer.

"In these and many similar experiments no difference in action of any kind appeared between iron and other metals.

"Two hundred and three feet of copper wire in one length were passed round a large block of wood; other two hundred and three feet of similar wire were interposed as a spiral between the turns of the first, and metallic contact everywhere prevented by twine. One of these helices was connected with a galvanometer and the other with a battery of a hundred pairs of plates four inches square, with double coppers and well charged. When the contact was made, there was a sudden and very slight effect at the galvanometer, and there was also a similar slight effect when the contact with the battery was broken. But whilst the voltaic current was continuing to pass through the one helix, no galvanometrical appearances of any effect like induction upon the other helix could be perceived, although the active power of the battery was proved to be great by its heating the whole of its own helix, and by the brilliancy of the discharge when made through charcoal.

"Repetition of the experiments with a battery of one hundred and twenty pairs of plates produced no other effects; but it was ascertained, both at this and at the former time, that the slight deflection of the needle occurring at the moment of completing the connection was always in one direction, and that the equally slight deflection produced when the contact was broken was in the other direction; and, also, that these effects occurred when the first helices were used.

"The results which I had by this time obtained with magnets led me to believe that the battery current through one wire did, in reality, induce a similar current through the other wire, but that it continued for an instant only, and partook more of the nature of the electrical wave passed through from the shock of a common Leyden jar than of that from a voltaic battery, and, therefore, might magnetize a steel needle although it scarcely affected the galvanometer.

"This expectation was confirmed; for on substituting a small hollow helix, formed round a glass tube, for the galvanometer, introducing a steel needle, making contact as before between the battery and the inducing wire, and then removing the needle before the battery contact was broken, it was found magnetized.

"When the battery contact was first made, then an unmagnetized needle introduced, and lastly the battery contact broken, the needle was found magnetized to an equal degree apparently with the first; but the poles were of the contrary kinds."(3)

To Faraday these experiments explained the phenomenon of Arago's rotating disk, the disk inducing the current from the magnet, and, in reacting, deflecting the needle. To prove this, he constructed a disk that revolved between the poles of an electro-magnet, connecting the axis and the edge of the disk with a galvanometer. "... A disk of copper, twelve inches in diameter, fixed upon a brass axis," he says, "was mounted in frames so as to be revolved either vertically or horizontally, its edge being at the same time introduced more or less between the magnetic poles. The edge of the plate was well amalgamated for the purpose of obtaining good but movable contact; a part round the axis was also prepared in a similar manner.

"Conductors or collectors of copper and lead were constructed so as to come in contact with the edge of the copper disk, or with other forms of plates hereafter to be described. These conductors we're about four inches long, one-third of an inch wide, and one-fifth of an inch thick; one end of each was slightly grooved, to allow of more exact adaptation to the somewhat convex edge of the plates, and then amalgamated. Copper wires, one-sixteenth of an inch in thickness, attached in the ordinary manner by convolutions to the other ends of these conductors, passed away to the galvanometer.

"All these arrangements being made, the copper disk was adjusted, the small magnetic poles being about one-half an inch apart, and the edge of the plate inserted about half their width between them. One of the galvanometer wires was passed twice or thrice loosely round the brass axis of the plate, and the other attached to a conductor, which itself was retained by the hand in contact with the amalgamated edge of the disk at the part immediately between the magnetic poles. Under these circumstances all was quiescent, and the galvanometer exhibited no effect. But the instant the plate moved the galvanometer was influenced, and by revolving the plate quickly the needle could be deflected ninety degrees or more."(4)

This rotating disk was really a dynamo electric machine in miniature, the first ever constructed, but whose direct descendants are the ordinary dynamos. Modern dynamos range in power from little machines operating machinery requiring only fractions of a horsepower to great dynamos operating street-car lines and lighting cities; but all are built on the same principle as Faraday's rotating disk. By this discovery the use of electricity as a practical and economical motive power became possible.

STORAGE BATTERIES

When the discoveries of Faraday of electro-magnetic induction had made possible the means of easily generating electricity, the next natural step was to find a means of storing it or accumulating it. This, however, proved no easy matter, and as yet a practical storage or secondary battery that is neither too cumbersome, too fragile, nor too weak in its action has not been invented. If a satisfactory storage battery could be made, it is obvious that its revolutionary effects could scarcely be overestimated. In the single field of aeronautics, it would probably solve the question of aerial navigation. Little wonder, then, that inventors have sought so eagerly for the invention of satisfactory storage batteries. As early as 1803 Ritter had attempted to make such a secondary battery. In 1843 Grove also attempted it. But it was not until 1859, when Gaston Planche produced his invention, that anything like a reasonably satisfactory storage battery was made. Planche discovered that sheets of lead immersed in dilute sulphuric acid were very satisfactory for the production of polarization effects. He constructed a battery of sheets of lead immersed in sulphuric acid, and, after charging these for several hours from the cells of an ordinary Bunsen battery, was able to get currents of great strength and considerable duration. This battery, however, from its construction of lead, was necessarily heavy and cumbersome. Faure improved it somewhat by coating the lead plates with red-lead, thus increasing the capacity of the cell. Faure's invention gave a fresh impetus to inventors, and shortly after the market was filled with storage batteries of various kinds, most of them modifications of Planche's or Faure's. The ardor of enthusiastic inventors soon flagged, however, for all these storage batteries proved of little practical account in the end, as compared with other known methods of generating power.

Three methods of generating electricity are in general use: static or frictional electricity is generated by "plate" or "static" machines; galvanic, generated by batteries based on Volta's discovery; and induced, or faradic, generated either by chemical or mechanical action. There is still another kind, thermo-electricity, that may be generated in a most simple manner. In 1821 Seebecle, of Berlin, discovered that when a circuit was formed of two wires of different metals, if there be a difference in temperature at the juncture of these two metals an electrical current will be established. In this way heat may be transmitted directly into the energy of the current without the interposition of the steam-engine. Batteries constructed in this way are of low resistance, however, although by arranging several of them in "series," currents of considerable strength can be generated. As yet, however, they are of little practical importance.

About the middle of the century Clerk-Maxwell advanced the idea that light waves were really electro-magnetic waves. If this were true and light proved to be simply one form of electrical energy, then the same would be true of radiant heat. Maxwell advanced this theory, but failed to substantiate it by experimental confirmation. But Dr. Heinrich Hertz, a few years later, by a series of experiments, demonstrated the correctness of Maxwell's surmises. What are now called "Hertzian waves" are waves apparently identical with light waves, but of much lower pitch or period. In his experiments Hertz showed that, under proper conditions, electric sparks between polished balls were attended by ether waves of the same nature as those of light, but of a pitch of several millions of vibrations per second. These waves could be dealt with as if they were light waves—reflected, refracted, and polarized. These are the waves that are utilized in wireless telegraphy.

ROENTGEN RAYS, OR X-RAYS

In December of 1895 word came out of Germany of a scientific discovery that startled the world. It came first as a rumor, little credited; then as a pronounced report; at last as a demonstration. It told of a new manifestation of energy, in virtue of which the interior of opaque objects is made visible to human eyes. One had only to look into a tube containing a screen of a certain composition, and directed towards a peculiar electrical apparatus, to acquire clairvoyant vision more wonderful than the discredited second-sight of the medium. Coins within a purse, nails driven into wood, spectacles within a leather case, became clearly visible when subjected to the influence of this magic tube; and when a human hand was held before the tube, its bones stood revealed in weird simplicity, as if the living, palpitating flesh about them were but the shadowy substance of a ghost.

Not only could the human eye see these astounding revelations, but the impartial evidence of inanimate chemicals could be brought forward to prove that the mind harbored no illusion. The photographic film recorded the things that the eye might see, and ghostly pictures galore soon gave a quietus to the doubts of the most sceptical. Within a month of the announcement of Professor Roentgen's experiments comment upon the "X-ray" and the "new photography" had become a part of the current gossip of all Christendom.

It is hardly necessary to say that such a revolutionary thing as the discovery of a process whereby opaque objects became transparent, or translucent, was not achieved at a single bound with no intermediate discoveries. In 1859 the German physicist Julius Plucker (1801-1868) noticed that when there was an electrical discharge through an exhausted tube at a low pressure, on the surrounding walls of the tube near the negative pole, or cathode, appeared a greenish phosphorescence. This discovery was soon being investigated by a number of other scientists, among others Hittorf, Goldstein, and Professor (now Sir William) Crookes. The explanations given of this phenomenon by Professor Crookes concern us here more particularly, inasmuch as his views did not accord exactly with those held by the other two scientists, and as his researches were more directly concerned in the discovery of the Roentgen rays. He held that the heat and phosphorescence produced in a low-pressure tube were caused by streams of particles, projected from the cathode with great velocity, striking the sides of the glass tube. The composition of the glass seemed to enter into this phosphorescence also, for while lead glass produced blue phosphorescence, soda glass produced a yellowish green. The composition of the glass seemed to be changed by a long-continued pelting of these particles, the phosphorescence after a time losing its initial brilliancy, caused by the glass becoming "tired," as Professor Crookes said. Thus when some opaque substance, such as iron, is placed between the cathode and the sides of the glass tube so that it casts a shadow in a certain spot on the glass for some little time, it is found on removing the opaque substance or changing its position that the area of glass at first covered by the shadow now responded to the rays in a different manner from the surrounding glass.

The peculiar ray's, now known as the cathode rays, not only cast a shadow, but are deflected by a magnet, so that the position of the phosphorescence on the sides of the tube may be altered by the proximity of a powerful magnet. From this it would seem that the rays are composed of particles charged with negative electricity, and Professor J. J. Thomson has modified the experiment of Perrin to show that negative electricity is actually associated with the rays. There is reason for believing, therefore, that the cathode rays are rapidly moving charges of negative electricity. It is possible, also, to determine the velocity at which these particles are moving by measuring the deflection produced by the magnetic field.

From the fact that opaque substances cast a shadow in these rays it was thought at first that all solids were absolutely opaque to them. Hertz, however, discovered that a small amount of phosphorescence occurred on the glass even when such opaque substances as gold-leaf or aluminium foil were interposed between the cathode and the sides of the tube. Shortly afterwards Lenard discovered that the cathode rays can be made to pass from the inside of a discharge tube to the outside air. For convenience these rays outside the tube have since been known as "Lenard rays."

In the closing days of December, 1895, Professor Wilhelm Konrad Roentgen, of Wurzburg, announced that he had made the discovery of the remarkable effect arising from the cathode rays to which reference was made above. He found that if a plate covered with a phosphorescent substance is placed near a discharge tube exhausted so highly that the cathode rays produced a green phosphorescence, this plate is made to glow in a peculiar manner. The rays producing this glow were not the cathode rays, although apparently arising from them, and are what have since been called the Roentgen rays, or X-rays.

Roentgen found that a shadow is thrown upon the screen by substances held between it and the exhausted tube, the character of the shadow depending upon the density of the substance. Thus metals are almost completely opaque to the rays; such substances as bone much less so, and ordinary flesh hardly so at all. If a coin were held in the hand that had been interposed between the tube and the screen the picture formed showed the coin as a black shadow; and the bones of the hand, while casting a distinct shadow, showed distinctly lighter; while the soft tissues produced scarcely any shadow at all. The value of such a discovery was obvious from the first; and was still further enhanced by the discovery made shortly that, photographic plates are affected by the rays, thus making it possible to make permanent photographic records of pictures through what we know as opaque substances.

What adds materially to the practical value of Roentgen's discovery is the fact that the apparatus for producing the X-rays is now so simple and relatively inexpensive that it is within the reach even of amateur scientists. It consists essentially of an induction coil attached either to cells or a street-current plug for generating the electricity, a focus tube, and a phosphorescence screen. These focus tubes are made in various shapes, but perhaps the most popular are in the form of a glass globe, not unlike an ordinary small-sized water-bottle, this tube being closed and exhausted, and having the two poles (anode and cathode) sealed into the glass walls, but protruding at either end for attachment to the conducting wires from the induction coil. This tube may be mounted on a stand at a height convenient for manipulation. The phosphorescence screen is usually a plate covered with some platino-cyanide and mounted in the end of a box of convenient size, the opposite end of which is so shaped that it fits the contour of the face, shutting out the light and allowing the eyes of the observer to focalize on the screen at the end. For making observations the operator has simply to turn on the current of electricity and apply the screen to his eyes, pointing it towards the glowing tube, when the shadow of any substance interposed between the tube and the screen will appear upon the phosphorescence plate.

The wonderful shadow pictures produced on the phosphorescence screen, or the photographic plate, would seem to come from some peculiar form of light, but the exact nature of these rays is still an open question. Whether the Roentgen rays are really a form of light—that is, a form of "electro-magnetic disturbance propagated through ether," is not fully determined. Numerous experiments have been undertaken to determine this, but as yet no proof has been found that the rays are a form of light, although there appears to be nothing in their properties inconsistent with their being so. For the moment most investigators are content to admit that the term X-ray virtually begs the question as to the intimate nature of the form of energy involved.



VIII. THE CONSERVATION OF ENERGY

As we have seen, it was in 1831 that Faraday opened up the field of magneto-electricity. Reversing the experiments of his predecessors, who had found that electric currents may generate magnetism, he showed that magnets have power under certain circumstances to generate electricity; he proved, indeed, the interconvertibility of electricity and magnetism. Then he showed that all bodies are more or less subject to the influence of magnetism, and that even light may be affected by magnetism as to its phenomena of polarization. He satisfied himself completely of the true identity of all the various forms of electricity, and of the convertibility of electricity and chemical action. Thus he linked together light, chemical affinity, magnetism, and electricity. And, moreover, he knew full well that no one of these can be produced in indefinite supply from another. "Nowhere," he says, "is there a pure creation or production of power without a corresponding exhaustion of something to supply it."

When Faraday wrote those words in 1840 he was treading on the very heels of a greater generalization than any which he actually formulated; nay, he had it fairly within his reach. He saw a great truth without fully realizing its import; it was left for others, approaching the same truth along another path, to point out its full significance.

The great generalization which Faraday so narrowly missed is the truth which since then has become familiar as the doctrine of the conservation of energy—the law that in transforming energy from one condition to another we can never secure more than an equivalent quantity; that, in short, "to create or annihilate energy is as impossible as to create or annihilate matter; and that all the phenomena of the material universe consist in transformations of energy alone." Some philosophers think this the greatest generalization ever conceived by the mind of man. Be that as it may, it is surely one of the great intellectual landmarks of the nineteenth century. It stands apart, so stupendous and so far-reaching in its implications that the generation which first saw the law developed could little appreciate it; only now, through the vista of half a century, do we begin to see it in its true proportions.

A vast generalization such as this is never a mushroom growth, nor does it usually spring full grown from the mind of any single man. Always a number of minds are very near a truth before any one mind fully grasps it. Pre-eminently true is this of the doctrine of the conservation of energy. Not Faraday alone, but half a dozen different men had an inkling of it before it gained full expression; indeed, every man who advocated the undulatory theory of light and heat was verging towards the goal. The doctrine of Young and Fresnel was as a highway leading surely on to the wide plain of conservation. The phenomena of electro-magnetism furnished another such highway. But there was yet another road which led just as surely and even more readily to the same goal. This was the road furnished by the phenomena of heat, and the men who travelled it were destined to outstrip their fellow-workers; though, as we have seen, wayfarers on other roads were within hailing distance when the leaders passed the mark.

In order to do even approximate justice to the men who entered into the great achievement, we must recall that just at the close of the eighteenth century Count Rumford and Humphry Davy independently showed that labor may be transformed into heat; and correctly interpreted this fact as meaning the transformation of molar into molecular motion. We can hardly doubt that each of these men of genius realized—vaguely, at any rate—that there must be a close correspondence between the amount of the molar and the molecular motions; hence that each of them was in sight of the law of the mechanical equivalent of heat. But neither of them quite grasped or explicitly stated what each must vaguely have seen; and for just a quarter of a century no one else even came abreast their line of thought, let alone passing it.

But then, in 1824, a French philosopher, Sadi Carnot, caught step with the great Englishmen, and took a long leap ahead by explicitly stating his belief that a definite quantity of work could be transformed into a definite quantity of heat, no more, no less. Carnot did not, indeed, reach the clear view of his predecessors as to the nature of heat, for he still thought it a form of "imponderable" fluid; but he reasoned none the less clearly as to its mutual convertibility with mechanical work. But important as his conclusions seem now that we look back upon them with clearer vision, they made no impression whatever upon his contemporaries. Carnot's work in this line was an isolated phenomenon of historical interest, but it did not enter into the scheme of the completed narrative in any such way as did the work of Rumford and Davy.

The man who really took up the broken thread where Rumford and Davy had dropped it, and wove it into a completed texture, came upon the scene in 1840. His home was in Manchester, England; his occupation that of a manufacturer. He was a friend and pupil of the great Dr. Dalton. His name was James Prescott Joule. When posterity has done its final juggling with the names of the nineteenth century, it is not unlikely that the name of this Manchester philosopher will be a household word, like the names of Aristotle, Copernicus, and Newton.

For Joule's work it was, done in the fifth decade of the century, which demonstrated beyond all cavil that there is a precise and absolute equivalence between mechanical work and heat; that whatever the form of manifestation of molar motion, it can generate a definite and measurable amount of heat, and no more. Joule found, for example, that at the sea-level in Manchester a pound weight falling through seven hundred and seventy-two feet could generate enough heat to raise the temperature of a pound of water one degree Fahrenheit. There was nothing haphazard, nothing accidental, about this; it bore the stamp of unalterable law. And Joule himself saw, what others in time were made to see, that this truth is merely a particular case within a more general law. If heat cannot be in any sense created, but only made manifest as a transformation of another kind of motion, then must not the same thing be true of all those other forms of "force"—light, electricity, magnetism—which had been shown to be so closely associated, so mutually convertible, with heat? All analogy seemed to urge the truth of this inference; all experiment tended to confirm it. The law of the mechanical equivalent of heat then became the main corner-stone of the greater law of the conservation of energy.

But while this citation is fresh in mind, we must turn our attention with all haste to a country across the Channel—to Denmark, in short—and learn that even as Joule experimented with the transformation of heat, a philosopher of Copenhagen, Colding by name, had hit upon the same idea, and carried it far towards a demonstration. And then, without pausing, we must shift yet again, this time to Germany, and consider the work of three other men, who independently were on the track of the same truth, and two of whom, it must be admitted, reached it earlier than either Joule or Colding, if neither brought it to quite so clear a demonstration. The names of these three Germans are Mohr, Mayer, and Helmholtz. Their share in establishing the great doctrine of conservation must now claim our attention.

As to Karl Friedrich Mohr, it may be said that his statement of the doctrine preceded that of any of his fellows, yet that otherwise it was perhaps least important. In 1837 this thoughtful German had grasped the main truth, and given it expression in an article published in the Zeitschrift fur Physik, etc. But the article attracted no attention whatever, even from Mohr's own countrymen. Still, Mohr's title to rank as one who independently conceived the great truth, and perhaps conceived it before any other man in the world saw it as clearly, even though he did not demonstrate its validity, is not to be disputed.

It was just five years later, in 1842, that Dr. Julius Robert Mayer, practising physician in the little German town of Heilbronn, published a paper in Liebig's Annalen on "The Forces of Inorganic Nature," in which not merely the mechanical theory of heat, but the entire doctrine of the conservation of energy, is explicitly if briefly stated. Two years earlier Dr. Mayer, while surgeon to a Dutch India vessel cruising in the tropics, had observed that the venous blood of a patient seemed redder than venous blood usually is observed to be in temperate climates. He pondered over this seemingly insignificant fact, and at last reached the conclusion that the cause must be the lesser amount of oxidation required to keep up the body temperature in the tropics. Led by this reflection to consider the body as a machine dependent on outside forces for its capacity to act, he passed on into a novel realm of thought, which brought him at last to independent discovery of the mechanical theory of heat, and to the first full and comprehensive appreciation of the great law of conservation. Blood-letting, the modern physician holds, was a practice of very doubtful benefit, as a rule, to the subject; but once, at least, it led to marvellous results. No straw is go small that it may not point the receptive mind of genius to new and wonderful truths.

MAYER'S PAPER OF 1842

The paper in which Mayer first gave expression to his revolutionary ideas bore the title of "The Forces of Inorganic Nature," and was published in 1842. It is one of the gems of scientific literature, and fortunately it is not too long to be quoted in its entirety. Seldom if ever was a great revolutionary doctrine expounded in briefer compass:

"What are we to understand by 'forces'? and how are different forces related to each other? The term force conveys for the most part the idea of something unknown, unsearchable, and hypothetical; while the term matter, on the other hand, implies the possession, by the object in question, of such definite properties as weight and extension. An attempt, therefore, to render the idea of force equally exact with that of matter is one which should be welcomed by all those who desire to have their views of nature clear and unencumbered by hypothesis.

"Forces are causes; and accordingly we may make full application in relation to them of the principle causa aequat effectum. If the cause c has the effect e, then c = e; if, in its turn, e is the cause of a second effect of f, we have e = f, and so on: c = e = f... = c. In a series of causes and effects, a term or a part of a term can never, as is apparent from the nature of an equation, become equal to nothing. This first property of all causes we call their indestructibility.

"If the given cause c has produced an effect e equal to itself, it has in that very act ceased to be—c has become e. If, after the production of e, c still remained in the whole or in part, there must be still further effects corresponding to this remaining cause: the total effect of c would thus be > e, which would be contrary to the supposition c = e. Accordingly, since c becomes e, and e becomes f, etc., we must regard these various magnitudes as different forms under which one and the same object makes its appearance. This capability of assuming various forms is the second essential property of all causes. Taking both properties together, we may say, causes an INDESTRUCTIBLE quantitatively, and quantitatively CONVERTIBLE objects.

"There occur in nature two causes which apparently never pass one into the other," said Mayer. "The first class consists of such causes as possess the properties of weight and impenetrability. These are kinds of matter. The other class is composed of causes which are wanting in the properties just mentioned—namely, forces, called also imponderables, from the negative property that has been indicated. Forces are therefore INDESTRUCTIBLE, CONVERTIBLE, IMPONDERABLE OBJECTS.

"As an example of causes and effects, take matter: explosive gas, H + O, and water, HO, are related to each other as cause and effect; therefore H + O = HO. But if H + O becomes HO, heat, cal., makes its appearance as well as water; this heat must likewise have a cause, x, and we have therefore H + O + X = HO + cal. It might be asked, however, whether H + O is really = HO, and x = cal., and not perhaps H + O = cal., and x = HO, whence the above equation could equally be deduced; and so in many other cases. The phlogistic chemists recognized the equation between cal. and x, or phlogiston as they called it, and in so doing made a great step in advance; but they involved themselves again in a system of mistakes by putting x in place of O. In this way they obtained H = HO + x.

"Chemistry teaches us that matter, as a cause, has matter for its effect; but we may say with equal justification that to force as a cause corresponds force as effect. Since c = e, and e = c, it is natural to call one term of an equation a force, and the other an effect of force, or phenomenon, and to attach different notions to the expression force and phenomenon. In brief, then, if the cause is matter, the effect is matter; if the cause is a force, the effect is also a force.

"The cause that brings about the raising of a weight is a force. The effect of the raised weight is, therefore, also a force; or, expressed in a more general form, SEPARATION IN SPACE OF PONDERABLE OBJECTS IS A FORCE; and since this force causes the fall of bodies, we call it FALLING FORCE. Falling force and fall, or, still more generally, falling force and motion, are forces related to each other as cause and effect—forces convertible into each other—two different forms of one and the same object. For example, a weight resting on the ground is not a force: it is neither the cause of motion nor of the lifting of another weight. It becomes so, however, in proportion as it is raised above the ground. The cause—that is, the distance between a weight and the earth, and the effect, or the quantity of motion produced, bear to each other, as shown by mechanics, a constant relation.

"Gravity being regarded as the cause of the falling of bodies, a gravitating force is spoken of; and thus the ideas of PROPERTY and of FORCE are confounded with each other. Precisely that which is the essential attribute of every force—that is, the UNION of indestructibility with convertibility—is wanting in every property: between a property and a force, between gravity and motion, it is therefore impossible to establish the equation required for a rightly conceived causal relation. If gravity be called a force, a cause is supposed which produces effects without itself diminishing, and incorrect conceptions of the causal connections of things are thereby fostered. In order that a body may fall, it is just as necessary that it be lifted up as that it should be heavy or possess gravity. The fall of bodies, therefore, ought not to be ascribed to their gravity alone. The problem of mechanics is to develop the equations which subsist between falling force and motion, motion and falling force, and between different motions. Here is a case in point: The magnitude of the falling force v is directly proportional (the earth's radius being assumed—oo) to the magnitude of the mass m, and the height d, to which it is raised—that is, v = md. If the height d = l, to which the mass m is raised, is transformed into the final velocity c = l of this mass, we have also v = mc; but from the known relations existing between d and c, it results that, for other values of d or of c, the measure of the force v is mc squared; accordingly v = md = mcsquared. The law of the conservation of vis viva is thus found to be based on the general law of the indestructibility of causes.

"In many cases we see motion cease without having caused another motion or the lifting of a weight. But a force once in existence cannot be annihilated—it can only change its form. And the question therefore arises, what other forms is force, which we have become acquainted with as falling force and motion, capable of assuming? Experience alone can lead us to a conclusion on this point. That we may experiment to advantage, we must select implements which, besides causing a real cessation of motion, are as little as possible altered by the objects to be examined. For example, if we rub together two metal plates, we see motion disappear, and heat, on the other hand, make its appearance, and there remains to be determined only whether MOTION is the cause of heat. In order to reach a decision on this point, we must discuss the question whether, in the numberless cases in which the expenditure of motion is accompanied by the appearance of heat, the motion has not some other effect than the production of heat, and the heat some other cause than the motion.

"A serious attempt to ascertain the effects of ceasing motion has never been made. Without wishing to exclude a priori the hypothesis which it may be possible to establish, therefore, we observe only that, as a rule, this effect cannot be supposed to be an alteration in the state of aggregation of the moved (that is, rubbing, etc.) bodies. If we assume that a certain quantity of motion v is expended in the conversion of a rubbing substance m into n, we must then have m + v - n, and n = m + v; and when n is reconverted into m, v must appear again in some form or other.

"By the friction of two metallic plates continued for a very long time, we can gradually cause the cessation of an immense quantity of movement; but would it ever occur to us to look for even the smallest trace of the force which has disappeared in the metallic dust that we could collect, and to try to regain it thence? We repeat, the motion cannot have been annihilated; and contrary, or positive and negative, motions cannot be regarded as = o any more than contrary motions can come out of nothing, or a weight can raise itself.

"Without the recognition of a causal relation between motion and heat, it is just as difficult to explain the production of heat as it is to give any account of the motion that disappears. The heat cannot be derived from the diminution of the volume of the rubbing substances. It is well known that two pieces of ice may be melted by rubbing them together in vacuo; but let any one try to convert ice into water by pressure, however enormous. The author has found that water undergoes a rise of temperature when shaken violently. The water so heated (from twelve to thirteen degrees centigrade) has a greater bulk after being shaken than it had before. Whence now comes this quantity of heat, which by repeated shaking may be called into existence in the same apparatus as often as we please? The vibratory hypothesis of heat is an approach towards the doctrine of heat being the effect of motion, but it does not favor the admission of this causal relation in its full generality. It rather lays the chief stress on restless oscillations.

"If it be considered as now established that in many cases no other effect of motion can be traced except heat, and that no other cause than motion can be found for the heat that is produced, we prefer the assumption that heat proceeds from motion to the assumption of a cause without effect and of an effect without a cause. Just as the chemist, instead of allowing oxygen and hydrogen to disappear without further investigation, and water to be produced in some inexplicable manner, establishes a connection between oxygen and hydrogen on the one hand, and water on the other.

"We may conceive the natural connection existing between falling force, motion, and heat as follows: We know that heat makes its appearance when the separate particles of a body approach nearer to each other; condensation produces heat. And what applies to the smallest particles of matter, and the smallest intervals between them, must also apply to large masses and to measurable distances. The falling of a weight is a diminution of the bulk of the earth, and must therefore without doubt be related to the quantity of heat thereby developed; this quantity of heat must be proportional to the greatness of the weight and its distance from the ground. From this point of view we are easily led to the equations between falling force, motion, and heat that have already been discussed.

"But just as little as the connection between falling force and motion authorizes the conclusion that the essence of falling force is motion, can such a conclusion be adopted in the case of heat. We are, on the contrary, rather inclined to infer that, before it can become heat, motion must cease to exist as motion, whether simple, or vibratory, as in the case of light and radiant heat, etc.

"If falling force and motion are equivalent to heat, heat must also naturally be equivalent to motion and falling force. Just as heat appears as an EFFECT of the diminution of bulk and of the cessation of motion, so also does heat disappear as a CAUSE when its effects are produced in the shape of motion, expansion, or raising of weight.

"In water-mills the continual diminution in bulk which the earth undergoes, owing to the fall of the water, gives rise to motion, which afterwards disappears again, calling forth unceasingly a great quantity of heat; and, inversely, the steam-engine serves to decompose heat again into motion or the raising of weights. A locomotive with its train may be compared to a distilling apparatus; the heat applied under the boiler passes off as motion, and this is deposited again as heat at the axles of the wheels."

Mayer then closes his paper with the following deduction: "The solution of the equations subsisting between falling force and motion requires that the space fallen through in a given time—e. g., the first second—should be experimentally determined. In like manner, the solution of the equations subsisting between falling force and motion on the one hand and heat on the other requires an answer to the question, How great is the quantity of heat which corresponds to a given quantity of motion or falling force? For instance, we must ascertain how high a given weight requires to be raised above the ground in order that its falling force maybe equivalent to the raising of the temperature of an equal weight of water from 0 degrees to 1 degrees centigrade. The attempt to show that such an equation is the expression of a physical truth may be regarded as the substance of the foregoing remarks.

"By applying the principles that have been set forth to the relations subsisting between the temperature and the volume of gases, we find that the sinking of a mercury column by which a gas is compressed is equivalent to the quantity of heat set free by the compression; and hence it follows, the ratio between the capacity for heat of air under constant pressure and its capacity under constant volume being taken as = 1.421, that the warming of a given weight of water from 0 degrees to equal weight from the height of about three hundred and sixty-five metres. If we compare with this result the working of our best steam-engines, we see how small a part only of the heat applied under the boiler is really transformed into motion or the raising of weights; and this may serve as justification for the attempts at the profitable production of motion by some other method than the expenditure of the chemical difference between carbon and oxygen—more particularly by the transformation into motion of electricity obtained by chemical means."(1)

MAYER AND HELMHOLTZ

Here, then, was this obscure German physician, leading the humdrum life of a village practitioner, yet seeing such visions as no human being in the world had ever seen before.

The great principle he had discovered became the dominating thought of his life, and filled all his leisure hours. He applied it far and wide, amid all the phenomena of the inorganic and organic worlds. It taught him that both vegetables and animals are machines, bound by the same laws that hold sway over inorganic matter, transforming energy, but creating nothing. Then his mind reached out into space and met a universe made up of questions. Each star that blinked down at him as he rode in answer to a night-call seemed an interrogation-point asking, How do I exist? Why have I not long since burned out if your theory of conservation be true? No one had hitherto even tried to answer that question; few had so much as realized that it demanded an answer. But the Heilbronn physician understood the question and found an answer. His meteoric hypothesis, published in 1848, gave for the first time a tenable explanation of the persistent light and heat of our sun and the myriad other suns—an explanation to which we shall recur in another connection.

All this time our isolated philosopher, his brain aflame with the glow of creative thought, was quite unaware that any one else in the world was working along the same lines. And the outside world was equally heedless of the work of the Heilbronn physician. There was no friend to inspire enthusiasm and give courage, no kindred spirit to react on this masterful but lonely mind. And this is the more remarkable because there are few other cases where a master-originator in science has come upon the scene except as the pupil or friend of some other master-originator. Of the men we have noticed in the present connection, Young was the friend and confrere of Davy; Davy, the protege of Rumford; Faraday, the pupil of Davy; Fresnel, the co-worker with Arago; Colding, the confrere of Oersted; Joule, the pupil of Dalton. But Mayer is an isolated phenomenon—one of the lone mountain-peak intellects of the century. That estimate may be exaggerated which has called him the Galileo of the nineteenth century, but surely no lukewarm praise can do him justice.

Yet for a long time his work attracted no attention whatever. In 1847, when another German physician, Hermann von Helmholtz, one of the most massive and towering intellects of any age, had been independently led to comprehension of the doctrine of the conservation of energy and published his treatise on the subject, he had hardly heard of his countryman Mayer. When he did hear of him, however, he hastened to renounce all claim to the doctrine of conservation, though the world at large gives him credit of independent even though subsequent discovery.

JOULE'S PAPER OF 1843

Meantime, in England, Joule was going on from one experimental demonstration to another, oblivious of his German competitors and almost as little noticed by his own countrymen. He read his first paper before the chemical section of the British Association for the Advancement of Science in 1843, and no one heeded it in the least. It is well worth our while, however, to consider it at length. It bears the title, "On the Calorific Effects of Magneto-Electricity, and the Mechanical Value of Heat." The full text, as published in the Report of the British Association, is as follows:

"Although it has been long known that fine platinum wire can be ignited by magneto-electricity, it still remained a matter of doubt whether heat was evolved by the COILS in which the magneto-electricity was generated; and it seemed indeed not unreasonable to suppose that COLD was produced there in order to make up for the heat evolved by the other part of the circuit. The author therefore has endeavored to clear up this uncertainty by experiment. His apparatus consisted of a small compound electro-magnet, immersed in water, revolving between the poles of a powerful stationary magnet. The magneto-electricity developed in the coils of the revolving electro-magnet was measured by an accurate galvanometer; and the temperature of the water was taken before and after each experiment by a very delicate thermometer. The influence of the temperature of the surrounding atmospheric air was guarded against by covering the revolving tube with flannel, etc., and by the adoption of a system of interpolation. By an extensive series of experiments with the above apparatus the author succeeded in proving that heat is evolved by the coils of the magneto-electrical machine, as well as by any other part of the circuit, in proportion to the resistance to conduction of the wire and the square of the current; the magneto having, under comparable circumstances, the same calorific power as the voltaic electricity.

"Professor Jacobi, of St. Petersburg, bad shown that the motion of an electro-magnetic machine generates magneto-electricity in opposition to the voltaic current of the battery. The author had observed the same phenomenon on arranging his apparatus as an electro-magnetic machine; but had found that no additional heat was evolved on account of the conflict of forces in the coil of the electro-magnet, and that the heat evolved by the coil remained, as before, proportional to the square of the current. Again, by turning the machine contrary to the direction of the attractive forces, so as to increase the intensity of the voltaic current by the assistance of the magneto-electricity, he found that the evolution of heat was still proportional to the square of the current. The author discovered, therefore, that the heat evolved by the voltaic current is invariably proportional to the square of the current, however the intensity of the current may be varied by magnetic induction. But Dr. Faraday has shown that the chemical effects of the current are simply as its quantity. Therefore he concluded that in the electro-magnetic engine a part of the heat due to the chemical actions of the battery is lost by the circuit, and converted into mechanical power; and that when the electro-magnetic engine is turned CONTRARY to the direction of the attractive forces, a greater quantity of heat is evolved by the circuit than is due to the chemical reactions of the battery, the over-plus quantity being produced by the conversion of the mechanical force exerted in turning the machine. By a dynamometrical apparatus attached to his machine, the author has ascertained that, in all the above cases, a quantity of heat, capable of increasing the temperature of a pound of water by one degree of Fahrenheit's scale, is equal to the mechanical force capable of raising a weight of about eight hundred and thirty pounds to the height of one foot."(2)

JOULE OR MAYER?

Two years later Joule wished to read another paper, but the chairman hinted that time was limited, and asked him to confine himself to a brief verbal synopsis of the results of his experiments. Had the chairman but known it, he was curtailing a paper vastly more important than all the other papers of the meeting put together. However, the synopsis was given, and one man was there to hear it who had the genius to appreciate its importance. This was William Thomson, the present Lord Kelvin, now known to all the world as among the greatest of natural philosophers, but then only a novitiate in science. He came to Joule's aid, started rolling the ball of controversy, and subsequently associated himself with the Manchester experimenter in pursuing his investigations.

But meantime the acknowledged leaders of British science viewed the new doctrine askance. Faraday, Brewster, Herschel—those were the great names in physics at that day, and no one of them could quite accept the new views regarding energy. For several years no older physicist, speaking with recognized authority, came forward in support of the doctrine of conservation. This culminating thought of the first half of the nineteenth century came silently into the world, unheralded and unopposed. The fifth decade of the century had seen it elaborated and substantially demonstrated in at least three different countries, yet even the leaders of thought did not so much as know of its existence. In 1853 Whewell, the historian of the inductive sciences, published a second edition of his history, and, as Huxley has pointed out, he did not so much as refer to the revolutionizing thought which even then was a full decade old.

By this time, however, the battle was brewing. The rising generation saw the importance of a law which their elders could not appreciate, and soon it was noised abroad that there were more than one claimant to the honor of discovery. Chiefly through the efforts of Professor Tyndall, the work of Mayer became known to the British public, and a most regrettable controversy ensued between the partisans of Mayer and those of Joule—a bitter controversy, in which Davy's contention that science knows no country was not always regarded, and which left its scars upon the hearts and minds of the great men whose personal interests were involved.

And so to this day the question who is the chief discoverer of the law of the conservation of energy is not susceptible of a categorical answer that would satisfy all philosophers. It is generally held that the first choice lies between Joule and Mayer. Professor Tyndall has expressed the belief that in future each of these men will be equally remembered in connection with this work. But history gives us no warrant for such a hope. Posterity in the long run demands always that its heroes shall stand alone. Who remembers now that Robert Hooke contested with Newton the discovery of the doctrine of universal gravitation? The judgment of posterity is unjust, but it is inexorable. And so we can little doubt that a century from now one name will be mentioned as that of the originator of the great doctrine of the conservation of energy. The man whose name is thus remembered will perhaps be spoken of as the Galileo, the Newton, of the nineteenth century; but whether the name thus dignified by the final verdict of history will be that of Colding, Mohr, Mayer, Helmholtz, or Joule, is not as, yet decided.

LORD KELVIN AND THE DISSIPATION OF ENERGY

The gradual permeation of the field by the great doctrine of conservation simply repeated the history of the introduction of every novel and revolutionary thought. Necessarily the elder generation, to whom all forms of energy were imponderable fluids, must pass away before the new conception could claim the field. Even the word energy, though Young had introduced it in 1807, did not come into general use till some time after the middle of the century. To the generality of philosophers (the word physicist was even less in favor at this time) the various forms of energy were still subtile fluids, and never was idea relinquished with greater unwillingness than this. The experiments of Young and Fresnel had convinced a large number of philosophers that light is a vibration and not a substance; but so great an authority as Biot clung to the old emission idea to the end of his life, in 1862, and held a following.

Meantime, however, the company of brilliant young men who had just served their apprenticeship when the doctrine of conservation came upon the scene had grown into authoritative positions, and were battling actively for the new ideas. Confirmatory evidence that energy is a molecular motion and not an "imponderable" form of matter accumulated day by day. The experiments of two Frenchmen, Hippolyte L. Fizeau and Leon Foucault, served finally to convince the last lingering sceptics that light is an undulation; and by implication brought heat into the same category, since James David Forbes, the Scotch physicist, had shown in 1837 that radiant heat conforms to the same laws of polarization and double refraction that govern light. But, for that matter, the experiments that had established the mechanical equivalent of heat hardly left room for doubt as to the immateriality of this "imponderable." Doubters had indeed, expressed scepticism as to the validity of Joule's experiments, but the further researches, experimental and mathematical, of such workers as Thomson (Lord Kelvin), Rankine, and Tyndall in Great Britain, of Helmholtz and Clausius in Germany, and of Regnault in France, dealing with various manifestations of heat, placed the evidence beyond the reach of criticism.

Out of these studies, just at the middle of the century, to which the experiments of Mayer and Joule had led, grew the new science of thermo-dynamics. Out of them also grew in the mind of one of the investigators a new generalization, only second in importance to the doctrine of conservation itself. Professor William Thomson (Lord Kelvin) in his studies in thermodynamics was early impressed with the fact that whereas all the molar motion developed through labor or gravity could be converted into heat, the process is not fully reversible. Heat can, indeed, be converted into molar motion or work, but in the process a certain amount of the heat is radiated into space and lost. The same thing happens whenever any other form of energy is converted into molar motion. Indeed, every transmutation of energy, of whatever character, seems complicated by a tendency to develop heat, part of which is lost. This observation led Professor Thomson to his doctrine of the dissipation of energy, which he formulated before the Royal Society of Edinburgh in 1852, and published also in the Philosophical Magazine the same year, the title borne being, "On a Universal Tendency in Nature to the Dissipation of Mechanical Energy."

From the principle here expressed Professor Thomson drew the startling conclusion that, "since any restoration of this mechanical energy without more than an equivalent dissipation is impossible," the universe, as known to us, must be in the condition of a machine gradually running down; and in particular that the world we live on has been within a finite time unfit for human habitation, and must again become so within a finite future. This thought seems such a commonplace to-day that it is difficult to realize how startling it appeared half a century ago. A generation trained, as ours has been, in the doctrines of the conservation and dissipation of energy as the very alphabet of physical science can but ill appreciate the mental attitude of a generation which for the most part had not even thought it problematical whether the sun could continue to give out heat and light forever. But those advance thinkers who had grasped the import of the doctrine of conservation could at once appreciate the force of Thomson's doctrine of dissipation, and realize the complementary character of the two conceptions.

Here and there a thinker like Rankine did, indeed, attempt to fancy conditions under which the energy lost through dissipation might be restored to availability, but no such effort has met with success, and in time Professor Thomson's generalization and his conclusions as to the consequences of the law involved came to be universally accepted.

The introduction of the new views regarding the nature of energy followed, as I have said, the course of every other growth of new ideas. Young and imaginative men could accept the new point of view; older philosophers, their minds channelled by preconceptions, could not get into the new groove. So strikingly true is this in the particular case now before us that it is worth while to note the ages at the time of the revolutionary experiments of the men whose work has been mentioned as entering into the scheme of evolution of the idea that energy is merely a manifestation of matter in motion. Such a list will tell the story better than a volume of commentary.

Observe, then, that Davy made his epochal experiment of melting ice by friction when he was a youth of twenty. Young was no older when he made his first communication to the Royal Society, and was in his twenty-seventh year when he first actively espoused the undulatory theory. Fresnel was twenty-six when he made his first important discoveries in the same field; and Arago, who at once became his champion, was then but two years his senior, though for a decade he had been so famous that one involuntarily thinks of him as belonging to an elder generation.

Forbes was under thirty when he discovered the polarization of heat, which pointed the way to Mohr, then thirty-one, to the mechanical equivalent. Joule was twenty-two in 1840, when his great work was begun; and Mayer, whose discoveries date from the same year, was then twenty-six, which was also the age of Helmholtz when he published his independent discovery of the same law. William Thomson was a youth just past his majority when he came to the aid of Joule before the British Society, and but seven years older when he formulated his own doctrine of the dissipation of energy. And Clausius and Rankine, who are usually mentioned with Thomson as the great developers of thermo-dynamics, were both far advanced with their novel studies before they were thirty. With such a list in mind, we may well agree with the father of inductive science that "the man who is young in years may be old in hours."

Yet we must not forget that the shield has a reverse side. For was not the greatest of observing astronomers, Herschel, past thirty-five before he ever saw a telescope, and past fifty before he discovered the heat rays of the spectrum? And had not Faraday reached middle life before he turned his attention especially to electricity? Clearly, then, to make this phrase complete, Bacon should have added that "the man who is old in years may be young in imagination." Here, however, even more appropriate than in the other case—more's the pity—would have been the application of his qualifying clause: "but that happeneth rarely."

THE FINAL UNIFICATION

There are only a few great generalizations as yet thought out in any single field of science. Naturally, then, after a great generalization has found definitive expression, there is a period of lull before another forward move. In the case of the doctrines of energy, the lull has lasted half a century. Throughout this period, it is true, a multitude of workers have been delving in the field, and to the casual observer it might seem as if their activity had been boundless, while the practical applications of their ideas—as exemplified, for example, in the telephone, phonograph, electric light, and so on—have been little less than revolutionary. Yet the most competent of living authorities, Lord Kelvin, could assert in 1895 that in fifty years he had learned nothing new regarding the nature of energy.

This, however, must not be interpreted as meaning that the world has stood still during these two generations. It means rather that the rank and file have been moving forward along the road the leaders had already travelled. Only a few men in the world had the range of thought regarding the new doctrine of energy that Lord Kelvin had at the middle of the century. The few leaders then saw clearly enough that if one form of energy is in reality merely an undulation or vibration among the particles of "ponderable" matter or of ether, all other manifestations of energy must be of the same nature. But the rank and file were not even within sight of this truth for a long time after they had partly grasped the meaning of the doctrine of conservation. When, late in the fifties, that marvellous young Scotchman, James Clerk-Maxwell, formulating in other words an idea of Faraday's, expressed his belief that electricity and magnetism are but manifestations of various conditions of stress and motion in the ethereal medium (electricity a displacement of strain, magnetism a whirl in the ether), the idea met with no immediate popularity. And even less cordial was the reception given the same thinker's theory, put forward in 1863, that the ethereal undulations producing the phenomenon we call light differ in no respect except in their wave-length from the pulsations of electro-magnetism.

At about the same time Helmholtz formulated a somewhat similar electro-magnetic theory of light; but even the weight of this combined authority could not give the doctrine vogue until very recently, when the experiments of Heinrich Hertz, the pupil of Helmholtz, have shown that a condition of electrical strain may be developed into a wave system by recurrent interruptions of the electric state in the generator, and that such waves travel through the ether with the rapidity of light. Since then the electro-magnetic theory of light has been enthusiastically referred to as the greatest generalization of the century; but the sober thinker must see that it is really only what Hertz himself called it—one pier beneath the great arch of conservation. It is an interesting detail of the architecture, but the part cannot equal the size of the whole.

More than that, this particular pier is as yet by no means a very firm one. It has, indeed, been demonstrated that waves of electro-magnetism pass through space with the speed of light, but as yet no one has developed electric waves even remotely approximating the shortness of the visual rays. The most that can positively be asserted, therefore, is that all the known forms of radiant energy-heat, light, electro-magnetism—travel through space at the same rate of speed, and consist of traverse vibrations—"lateral quivers," as Fresnel said of light—known to differ in length, and not positively known to differ otherwise. It has, indeed, been suggested that the newest form of radiant energy, the famous X-ray of Professor Roentgen's discovery, is a longitudinal vibration, but this is a mere surmise. Be that as it may, there is no one now to question that all forms of radiant energy, whatever their exact affinities, consist essentially of undulatory motions of one uniform medium.

A full century of experiment, calculation, and controversy has thus sufficed to correlate the "imponderable fluids" of our forebears, and reduce them all to manifestations of motion among particles of matter. At first glimpse that seems an enormous change of view. And yet, when closely considered, that change in thought is not so radical as the change in phrase might seem to imply. For the nineteenth-century physicist, in displacing the "imponderable fluids" of many kinds—one each for light, heat, electricity, magnetism—has been obliged to substitute for them one all-pervading fluid, whose various quivers, waves, ripples, whirls or strains produce the manifestations which in popular parlance are termed forms of force. This all-pervading fluid the physicist terms the ether, and he thinks of it as having no weight. In effect, then, the physicist has dispossessed the many imponderables in favor of a single imponderable—though the word imponderable has been banished from his vocabulary. In this view the ether—which, considered as a recognized scientific verity, is essentially a nineteenth-century discovery—is about the most interesting thing in the universe. Something more as to its properties, real or assumed, we shall have occasion to examine as we turn to the obverse side of physics, which demands our attention in the next chapter.



IX. THE ETHER AND PONDERABLE MATTER

"Whatever difficulties we may have in forming a consistent idea of the constitution of the ether, there can be no doubt that the interplanetary and interstellar spaces are not empty, but are occupied by a material substance or body which is certainly the largest and probably the most uniform body of which we have any knowledge."

Such was the verdict pronounced some thirty years ago by James Clerk-Maxwell, one of the very greatest of nineteenth-century physicists, regarding the existence of an all-pervading plenum in the universe, in which every particle of tangible matter is immersed. And this verdict may be said to express the attitude of the entire philosophical world of our day. Without exception, the authoritative physicists of our time accept this plenum as a verity, and reason about it with something of the same confidence they manifest in speaking of "ponderable" matter or of, energy. It is true there are those among them who are disposed to deny that this all-pervading plenum merits the name of matter. But that it is a something, and a vastly important something at that, all are agreed. Without it, they allege, we should know nothing of light, of radiant heat, of electricity or magnetism; without it there would probably be no such thing as gravitation; nay, they even hint that without this strange something, ether, there would be no such thing as matter in the universe. If these contentions of the modern physicist are justified, then this intangible ether is incomparably the most important as well as the "largest and most uniform substance or body" in the universe. Its discovery may well be looked upon as one of the most important feats of the nineteenth century.

For a discovery of that century it surely is, in the sense that all the known evidences of its existence were gathered in that epoch. True dreamers of all ages have, for metaphysical reasons, imagined the existence of intangible fluids in space—they had, indeed, peopled space several times over with different kinds of ethers, as Maxwell remarks—but such vague dreamings no more constituted the discovery of the modern ether than the dream of some pre-Columbian visionary that land might lie beyond the unknown waters constituted the discovery of America. In justice it must be admitted that Huyghens, the seventeenth-century originator of the undulatory theory of light, caught a glimpse of the true ether; but his contemporaries and some eight generations of his successors were utterly deaf to his claims; so he bears practically the same relation to the nineteenth-century discoverers of ether that the Norseman bears to Columbus.

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